LECTURE PHYSICAL CHEMISTRY 3rd EDITION ROBERT G. MORTIMER

More documents

Recommendations

Info

www.daykemquynhon.ucoz.com If one component and three phases are present, f = 0 and there is no choice about the temperature, the pressure, or any other intensive variable. This three-phase state is represented by a triple point at which three coexistence curves intersect. The solid– liquid–vapor triple point of water occurs at a temperature of 273.16K and a pressure of 4.562 torr. p(mmHg) 218(atm) 4,562 D A B 0,01 lỏng https://plus.google.com/+DạyKèmQuyNhơn rắn O hơi C 374 t( 0 C) Collected by Nguyen Thanh Tu Teacher MailBox : nguyenthanhtuteacher@hotmail.com
www.daykemquynhon.ucoz.com The Clapeyron Equation In a one-component system the chemical potential is equal to the molar Gibbs energy, so that if phases I and II of a single substance are at equilibrium From Eq. (4.2-19): Nonrigorously “dividing” this equation by dT , we obtain the Clapeyron equation: https://plus.google.com/+DạyKèmQuyNhơn Collected by Nguyen Thanh Tu Teacher MailBox : nguyenthanhtuteacher@hotmail.com
Page 2 and 3:
Part 1 Thermodynamics and the Macro
Page 4 and 5:
Chapter 5. Phase Equilibrium 5.1 Th
Page 6 and 7:
www.daykemquynhon.ucoz.com Chapter
Page 8 and 9:
www.daykemquynhon.ucoz.com 1.1. Int
Page 10 and 11:
www.daykemquynhon.ucoz.com Systems
Page 12 and 13:
www.daykemquynhon.ucoz.com Mathemat
Page 14 and 15:
www.daykemquynhon.ucoz.com A force
Page 16 and 17:
www.daykemquynhon.ucoz.com https://
Page 18 and 19:
www.daykemquynhon.ucoz.com PROBLEMS
Page 20 and 21:
www.daykemquynhon.ucoz.com 1.4 A li
Page 22 and 23:
www.daykemquynhon.ucoz.com 1.6 Maki
Page 24 and 25:
www.daykemquynhon.ucoz.com 1.10 Acc
Page 26 and 27:
www.daykemquynhon.ucoz.com 1.2. Sys
Page 28 and 29:
www.daykemquynhon.ucoz.com We must
Page 30 and 31:
www.daykemquynhon.ucoz.com - Extens
Page 32 and 33:
www.daykemquynhon.ucoz.com where
Page 34 and 35:
www.daykemquynhon.ucoz.com The coef
Page 36 and 37:
Page 38 and 39:
www.daykemquynhon.ucoz.com 1.3. Rea
Page 40 and 41:
Page 42 and 43:
www.daykemquynhon.ucoz.com 1.4. The
Page 44 and 45:
Page 46 and 47:
www.daykemquynhon.ucoz.com where dw
Page 48 and 49:
www.daykemquynhon.ucoz.com For a fi
Page 50 and 51:
www.daykemquynhon.ucoz.com The Work
Page 52 and 53:
www.daykemquynhon.ucoz.com For an i
Page 54 and 55:
www.daykemquynhon.ucoz.com Work Don
Page 56 and 57:
Page 58 and 59:
www.daykemquynhon.ucoz.com Constant
Page 60 and 61:
www.daykemquynhon.ucoz.com Expansio
Page 62 and 63:
www.daykemquynhon.ucoz.com Compress
Page 64 and 65:
www.daykemquynhon.ucoz.com 2.2. Hea
Page 66 and 67:
www.daykemquynhon.ucoz.com where m
Page 68 and 69:
www.daykemquynhon.ucoz.com If the h
Page 70 and 71:
www.daykemquynhon.ucoz.com The heat
Page 72 and 73:
Page 74 and 75:
www.daykemquynhon.ucoz.com Since th
Page 76 and 77:
www.daykemquynhon.ucoz.com where C
Page 78 and 79:
www.daykemquynhon.ucoz.com To an ex
Page 80 and 81:
www.daykemquynhon.ucoz.com Since U
Page 82 and 83:
Page 84 and 85:
www.daykemquynhon.ucoz.com Joule wa
Page 86 and 87:
www.daykemquynhon.ucoz.com Reversib
Page 88 and 89:
www.daykemquynhon.ucoz.com Equation
Page 90 and 91:
www.daykemquynhon.ucoz.com Irrevers
Page 92 and 93:
www.daykemquynhon.ucoz.com 2.5. Ent
Page 94 and 95:
www.daykemquynhon.ucoz.com The heat
Page 96 and 97:
www.daykemquynhon.ucoz.com the rela
Page 98 and 99:
www.daykemquynhon.ucoz.com The rati
Page 100 and 101:
www.daykemquynhon.ucoz.com The Joul
Page 102 and 103:
Page 104 and 105:
Page 106 and 107:
Page 108 and 109:
Page 110 and 111:
Page 112 and 113:
www.daykemquynhon.ucoz.com Physical
Page 114 and 115:
www.daykemquynhon.ucoz.com If all s
Page 116 and 117:
www.daykemquynhon.ucoz.com For 1 mo
Page 118 and 119:
www.daykemquynhon.ucoz.com This equ
Page 120 and 121:
www.daykemquynhon.ucoz.com Enthalpy
Page 122 and 123:
www.daykemquynhon.ucoz.com Accordin
Page 124 and 125:
www.daykemquynhon.ucoz.com ∆C P i
Page 126 and 127:
www.daykemquynhon.ucoz.com Adiabati
Page 128 and 129:
www.daykemquynhon.ucoz.com Process
Page 130 and 131:
www.daykemquynhon.ucoz.com 2.8. Cal
Page 132 and 133:
www.daykemquynhon.ucoz.com If the p
Page 134 and 135:
Page 136 and 137:
Page 138 and 139:
Page 140 and 141:
www.daykemquynhon.ucoz.com 7. The t
Page 142 and 143:
www.daykemquynhon.ucoz.com -The Cla
Page 144 and 145:
www.daykemquynhon.ucoz.com Figure 3
Page 146 and 147:
www.daykemquynhon.ucoz.com The effi
Page 148 and 149:
www.daykemquynhon.ucoz.com The valu
Page 150 and 151:
www.daykemquynhon.ucoz.com These tw
Page 152 and 153:
www.daykemquynhon.ucoz.com 3.2. The
Page 154 and 155:
Page 156 and 157:
www.daykemquynhon.ucoz.com Entropy
Page 158 and 159:
Page 160 and 161:
www.daykemquynhon.ucoz.com This mea
Page 162 and 163:
www.daykemquynhon.ucoz.com For isot
Page 164 and 165:
Page 166 and 167:
Page 168 and 169:
Page 170 and 171:
www.daykemquynhon.ucoz.com For temp
Page 172 and 173:
Page 174 and 175:
Page 176 and 177:
Page 178 and 179:
www.daykemquynhon.ucoz.com If the o
Page 180 and 181:
Page 182 and 183:
Page 184 and 185:
www.daykemquynhon.ucoz.com The entr
Page 186 and 187:
Page 188 and 189:
www.daykemquynhon.ucoz.com where k
Page 190 and 191:
www.daykemquynhon.ucoz.com In 1923
Page 192 and 193:
www.daykemquynhon.ucoz.com where S(
Page 194 and 195:
Page 196 and 197:
www.daykemquynhon.ucoz.com 4.1. Cri
Page 198 and 199:
www.daykemquynhon.ucoz.com Since T
Page 200 and 201:
www.daykemquynhon.ucoz.com The diff
Page 202 and 203:
www.daykemquynhon.ucoz.com for a si
Page 204 and 205:
www.daykemquynhon.ucoz.com We can i
Page 206 and 207:
www.daykemquynhon.ucoz.com We summa
Page 208 and 209:
www.daykemquynhon.ucoz.com An infin
Page 210 and 211:
www.daykemquynhon.ucoz.com At const
Page 212 and 213:
www.daykemquynhon.ucoz.com In the c
Page 214 and 215:
www.daykemquynhon.ucoz.com Equilibr
Page 216 and 217:
www.daykemquynhon.ucoz.com 4.2. Fun
Page 218 and 219:
www.daykemquynhon.ucoz.com We take
Page 220 and 221:
Page 222 and 223:
Page 224 and 225:
www.daykemquynhon.ucoz.com Equation
Page 226 and 227:
www.daykemquynhon.ucoz.com We can n
Page 228 and 229:
Page 230 and 231:
www.daykemquynhon.ucoz.com We can a
Page 232 and 233:
Page 234 and 235:
www.daykemquynhon.ucoz.com We apply
Page 236 and 237:
www.daykemquynhon.ucoz.com The part
Page 238 and 239:
www.daykemquynhon.ucoz.com An equat
Page 240 and 241: www.daykemquynhon.ucoz.com We can n
Page 242 and 243: www.daykemquynhon.ucoz.com The Gibb
Page 244 and 245: www.daykemquynhon.ucoz.com https://
Page 246 and 247: www.daykemquynhon.ucoz.com We can o
Page 248 and 249: www.daykemquynhon.ucoz.com The left
Page 252 and 253: www.daykemquynhon.ucoz.com The Temp
Page 254 and 255: www.daykemquynhon.ucoz.com If ∆S
Page 256 and 257: www.daykemquynhon.ucoz.com 4.5. Mul
Page 258 and 259: www.daykemquynhon.ucoz.com we can w
Page 260 and 261: www.daykemquynhon.ucoz.com The natu
Page 262 and 263: www.daykemquynhon.ucoz.com If the l
Page 264 and 265: www.daykemquynhon.ucoz.com The Part
Page 266 and 267: www.daykemquynhon.ucoz.com Partial
Page 268 and 269: www.daykemquynhon.ucoz.com The part
Page 270 and 271: www.daykemquynhon.ucoz.com 4.6. Eul
Page 272 and 273: www.daykemquynhon.ucoz.com Let Y st
Page 276 and 277: www.daykemquynhon.ucoz.com In a two
Page 280 and 281: www.daykemquynhon.ucoz.com 5.1. The
Page 282 and 283: www.daykemquynhon.ucoz.com Since th
Page 284 and 285: www.daykemquynhon.ucoz.com We write
Page 286 and 287: www.daykemquynhon.ucoz.com The two
Page 292 and 293: www.daykemquynhon.ucoz.com For a re
Page 298 and 299: www.daykemquynhon.ucoz.com The same
Page 300 and 301: www.daykemquynhon.ucoz.com If the e
Page 302 and 303: www.daykemquynhon.ucoz.com The Crit
Page 304 and 305: www.daykemquynhon.ucoz.com A useful
show all

LECTURE PHYSICAL CHEMISTRY 3rd EDITION ROBERT G. MORTIMER

You also want an ePaper? Increase the reach of your titles

Delete template?

Save as template?