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LECTURE PHYSICAL CHEMISTRY 3rd EDITION ROBERT G. MORTIMER

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The partial molar enthalpy of an ideal gas does not<br />

depend on pressure.<br />

According to Dalton’s law of partial pressures, each<br />

gas in a mixture of ideal gases behaves as though it<br />

were alone in the container. Equation (4.5-23) applies<br />

to any substance in an ideal gas mixture:<br />

where µ ◦ i is the chemical potential of substance i in the<br />

standard state at pressure P ◦ and P i is its partial<br />

pressure. All of the other equations for one-component<br />

ideal gases apply as well.<br />

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