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VGB POWERTECH 7 (2020) - International Journal for Generation and Storage of Electricity and Heat

VGB PowerTech - International Journal for Generation and Storage of Electricity and Heat. Issue 7 (2020). Technical Journal of the VGB PowerTech Association. Energy is us! Maintenance. Thermal waste utilisation

VGB PowerTech - International Journal for Generation and Storage of Electricity and Heat. Issue 7 (2020).
Technical Journal of the VGB PowerTech Association. Energy is us!
Maintenance. Thermal waste utilisation

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<strong>VGB</strong> PowerTech 7 l <strong>2020</strong> The Bi<strong>of</strong>ficiency Project | Part 1<br />

Tab. 1. Classification <strong>of</strong> different sources <strong>of</strong> biomass <strong>for</strong> energy <strong>and</strong> investigated feedstock in Bi<strong>of</strong>ficiency. Adapted from<br />

Main sector Sub sector Examples Investigated in Bi<strong>of</strong>ficiency<br />

Agriculture<br />

Forestry<br />

Organic waste<br />

Dedicated<br />

cultivation<br />

By-products<br />

<strong>and</strong> residues<br />

Crops <strong>for</strong> bi<strong>of</strong>uels (corn, sugarcane, rapeseed, oil palm, cassava etc.), energy grasses<br />

(miscanthus, switchgrass), short rotation <strong>for</strong>ests, others<br />

Herbaceous by-products: Straw from cereals, rice, corn, bagasse, empty fruit bunch from oil<br />

palm, prunings from stover, empty corn cobs, etc.<br />

Woody biomass: regeneration orchards, vineyards, olive <strong>and</strong> oil palm plantations<br />

Other <strong>for</strong>ms: Processing residues such as kernels, sunflower shells, rice husks, animal manure,<br />

foliage<br />

Miscanthus<br />

Wheat straw, empty fruit<br />

bunches<br />

Sun flower husk, digestate<br />

Main product Stems, wood fuel from <strong>for</strong>ests or trees outside <strong>for</strong>ests, woody biomass from l<strong>and</strong>scape cleaning Wood pellets<br />

By-products<br />

<strong>and</strong> residues<br />

Residues <strong>of</strong> <strong>for</strong>est harvest (branches, tops, stumps), residues <strong>of</strong> wood industry (bark, sawdust,<br />

other wood pieces, black liquor, tall oil, recycled wood)<br />

Municipal solid waste (MSW), food waste from stores, restaurants <strong>and</strong> households, used kitchen<br />

oil, waste from the food industries (from dairy, sugar, beer, wine, fruit juice industry, olive<br />

oil filter cake, from slaughterhouses), sewage sludge<br />

Spruce bark, fir brushwood<br />

Manure, sewage sludge, olive<br />

pomace, urban leave litter,<br />

road side grass, tomato foliage<br />

to meet strict limits <strong>for</strong> fine particles, nitrogen<br />

oxide <strong>and</strong> sulphur oxide emissions.<br />

The project addressed current bottlenecks<br />

in solid biomass combustion, namely increase<br />

deposit <strong>for</strong>mation, corrosion <strong>and</strong><br />

ash utilisation by a variety <strong>of</strong> new, promising<br />

approaches. The goal was to deepen<br />

the underst<strong>and</strong>ing <strong>of</strong> biomass combustion,<br />

to improve biomass pre-treatment technologies,<br />

as well as to contribute to the field <strong>of</strong><br />

biomass ash utilisation. The following<br />

main objectives <strong>and</strong> goals were defined in<br />

order to develop the next generation, biomass-fired<br />

CHP plant:<br />

––<br />

Increase efficiency <strong>of</strong> CHP plants by elevated<br />

steam temperatures through solving<br />

<strong>and</strong> underst<strong>and</strong>ing <strong>of</strong> ash-related<br />

problems – slagging, fouling <strong>and</strong> corrosion.<br />

––<br />

Reduce emissions – i.e. CO 2 , particulates,<br />

CO, NO x , <strong>and</strong> SO 2 – by efficiency gain,<br />

reduction <strong>of</strong> impurities <strong>and</strong> by tailored<br />

plant design.<br />

––<br />

Widen the feedstock <strong>for</strong> pulverised fuel<br />

(PF) <strong>and</strong> fluidised bed (FB) power plants<br />

using pre-treatment methods with focus<br />

on the reduction <strong>of</strong> harmful components<br />

in the biomass (torrefaction, hydrothermal<br />

carbonisation <strong>and</strong> steam explosion).<br />

––<br />

Optimise the use <strong>of</strong> additives in the combustion<br />

<strong>of</strong> solid biomass.<br />

––<br />

Widen ash utilisation <strong>and</strong> nutrient recirculation,<br />

study new concepts <strong>and</strong> explore<br />

possible utilisation options based<br />

on in-depth ash characterisation.<br />

The main results <strong>of</strong> the project are presented<br />

in a series <strong>of</strong> two technical papers in<br />

<strong>VGB</strong> Power Tech, whereby in this first part<br />

the focus lies on h<strong>and</strong>ling ash-related issues<br />

in biomass boilers <strong>and</strong> accessing difficult<br />

biomass feedstock <strong>for</strong> energetic use via<br />

pre-treatment.<br />

2. Accessing difficult biomass<br />

feedstock via pre-treatment<br />

2.1 Available bioenergy carriers<br />

Biomass is organic material that originates<br />

from plants <strong>and</strong> animals <strong>and</strong> can be used as<br />

a source <strong>of</strong> renewable energy. Traditionally,<br />

biomass has always been utilised as fuel<br />

<strong>for</strong> domestic applications such as heating<br />

<strong>and</strong> or cooking. Nowadays modern technologies<br />

are available <strong>for</strong> the energetic utilisation<br />

<strong>of</strong> biomass. For example, when biomass<br />

is burnt, it releases heat that can be<br />

used in subsequent combined heat <strong>and</strong><br />

power generation. Biomass accounts <strong>for</strong><br />

roughly two thirds <strong>of</strong> renewable energy in<br />

the European Union [2]. It plays the most<br />

crucial role in the heating sector, where<br />

biomass is responsible <strong>for</strong> over 90 % <strong>of</strong> all<br />

renewable heat generated.<br />

Ta b l e 1 provides a classification <strong>of</strong> the<br />

different potential sources <strong>of</strong> biomass <strong>for</strong><br />

energetic utilisation. In Bi<strong>of</strong>ficiency, biomass<br />

feedstock from almost all these sectors<br />

have been investigated. The selection<br />

was based on availability, cost <strong>and</strong> potential.<br />

All biomass feedstocks selected in the<br />

Bi<strong>of</strong>ficiency project were characterised<br />

thoroughly. The data is available on the<br />

open source database Phyllis II <strong>of</strong> project<br />

partner TNO.<br />

Due to the transition <strong>of</strong> the European energy<br />

system towards higher shares <strong>of</strong> renewable<br />

resources <strong>and</strong> energy carriers,<br />

there is an increasing dem<strong>and</strong> <strong>for</strong> biomass<br />

to be used <strong>for</strong> energy. Hence it competes<br />

with the existing use <strong>for</strong> production <strong>of</strong> e.g.<br />

construction materials, pulp <strong>and</strong> paper,<br />

<strong>and</strong> even <strong>for</strong> more novel uses such as chemicals.<br />

There<strong>for</strong>e, an important question is<br />

how much sustainable biomass will be<br />

available <strong>for</strong> bioenergy in Europe in the future.<br />

F i g u r e 1 gives an overview <strong>of</strong> the<br />

technical <strong>and</strong> sustainable potentials <strong>of</strong> the<br />

above-mentioned biomass classes in the EU<br />

by <strong>2020</strong> [3].<br />

Technical potential is the available biomass<br />

<strong>for</strong> all uses under current framework<br />

conditions with the current technological<br />

possibilities including existing harvesting<br />

techniques, infrastructure <strong>and</strong> accessibility<br />

<strong>and</strong> processing techniques.<br />

Potential <strong>for</strong> energy use is a proportion <strong>of</strong><br />

the technical potential after satisfying other<br />

existing <strong>and</strong> projected competing uses <strong>of</strong><br />

the same biomass feedstock.<br />

Sustainable potential constricts energy potential<br />

based on the sustainability criteria.<br />

As seen in F i g u r e 1 , agricultural <strong>and</strong> <strong>for</strong>estry<br />

residues represent a large portion <strong>of</strong><br />

the available biomass feedstock. Consequently,<br />

these feedstocks are <strong>of</strong> increasing<br />

interest in the energy sector, due to the<br />

lower associated fuel costs as well as higher<br />

local availability.<br />

Mtoe<br />

500<br />

450<br />

400<br />

350<br />

300<br />

250<br />

200<br />

150<br />

100<br />

50<br />

0<br />

Technical<br />

potential<br />

Potential <strong>for</strong><br />

energy use<br />

Manure, Sewage, other waste<br />

Forest residues, wood residues<br />

Forest stemwood<br />

Agricultural waste<br />

Energy crops<br />

Sustainable<br />

potential<br />

Fig. 1. Technical potential, potential <strong>for</strong> energy<br />

use <strong>and</strong> sustainable potential (Mtoe) <strong>of</strong><br />

fuels <strong>for</strong> bioenergy in the EU <strong>2020</strong>.<br />

Adapted from [3].<br />

However, most <strong>of</strong> these biomass feedstock<br />

suffer from low bulk density, high moisture<br />

content, low calorific value <strong>and</strong> their high<br />

hydrophilic nature [4, 5]. With these properties,<br />

multiple problems arise [5]. Firstly,<br />

hydrophilic biomass is subjected to biological<br />

deterioration, limiting the practical<br />

time <strong>for</strong> storage, a challenge <strong>for</strong> seasonally<br />

available agricultural residues. Further,<br />

the fibrous nature <strong>of</strong> biomass materials<br />

brings milling <strong>and</strong> fuel h<strong>and</strong>ling difficulties.<br />

Compared to fossil fuels, biomass <strong>of</strong>ten<br />

contains higher amounts <strong>of</strong> alkali metals<br />

<strong>and</strong> chlorine, which are responsible <strong>for</strong><br />

many undesirable reactions leading to operational<br />

problems in combustion furnaces<br />

<strong>and</strong> boilers.<br />

63

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