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A Self-Learning Manual - Institution of Engineers Mauritius

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A <strong>Self</strong>-<strong>Learning</strong> <strong>Manual</strong><br />

Mastering Different Fields <strong>of</strong> Civil Engineering Works (VC-Q&A Method) Vincent T. H. CHU<br />

Wet-mix method involves the pumping <strong>of</strong> ready mixed concrete to the<br />

nozzle. Compressed air is introduced at the nozzle to impel the mixture<br />

onto the receiving surface. The wet-mix method is more favorable for large<br />

volume placements. Rebound is less than in the dry-mix method. The<br />

nozzleman does not need to be concerned with the control on water<br />

addition.<br />

18. What is the difference between carbonation and carbon dioxide<br />

attack? (D1)<br />

For carbon dioxide attack, carbon dioxide dissolves in water to form a weak<br />

acid called carbonic acid. It would dissolve the cement matrix. However,<br />

the amount <strong>of</strong> carbon dioxide from the atmosphere is usually not sufficient<br />

to cause harm to concrete structures until additional source <strong>of</strong> carbon<br />

dioxide is available (e.g. decaying vegetable matter).<br />

Carbonation is the process <strong>of</strong> converting alkaline hydroxides in concrete to<br />

carbonates by reaction with carbon dioxide. The significance <strong>of</strong><br />

carbonation lies in the reduction <strong>of</strong> pH <strong>of</strong> pore water in concrete structure<br />

from 12-13 to 8-9 so that it drops the protection to steel reinforcement. The<br />

process takes place at concrete surface and spreads inwards. The passive<br />

nature play an important role in steel corrosion as it prevents corrosion<br />

even in the presence <strong>of</strong> water and oxygen. This passive nature is derived<br />

from a stable and thin layer <strong>of</strong> iron oxide formed at the surface <strong>of</strong> steel<br />

reinforcement. However, if the pH <strong>of</strong> concrete is dropped, this passive<br />

oxide layer becomes unstable and corrosion may start once water and<br />

oxygen supply is available.<br />

Stress would be generated owing to the occurrence <strong>of</strong> shrinkage. For<br />

instance, concrete at surface tends to dry more rapidly than the interior,<br />

leading to differential shrinkage. This results in the formation <strong>of</strong> internal<br />

balancing forces in which there is tension on concrete surface with<br />

compression in the interior concrete. About 90% <strong>of</strong> ultimate concrete strain<br />

occurs in the first year.<br />

When the water is allowed to absorb water, only part <strong>of</strong> shrinkage is<br />

reversible. Water loss from gel pore with C-S-H and capillary pres can be<br />

readily replenished. However, water loss from the space between C-S-H<br />

layers cannot be easily replaced with water. Once water is lost from the<br />

space between C-S-H layers at the first place, the bond between the layers<br />

becomes stronger and the layers would get closer together, thus making it<br />

72

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