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Untitled - Kelly Walsh High School

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94 CHEMISTRY FOR THE UTTERLY CONFUSED<br />

theory and investigated certain equations describing the properties of real<br />

gases. You learned that you could use the van der Waals equation in those cases<br />

where there was significant deviation from ideal gas behavior. And finally, you<br />

hopefully learned that in order to learn to work gas law problems it will take<br />

Practice, Practice, Practice.<br />

1. Write the expression for Dalton’s law.<br />

2. Write the expression for the combined gas equation.<br />

3. Write the expression for the ideal gas equation.<br />

4. List the pressure units introduced in this chapter, and show the relationships<br />

between these units.<br />

5. Write the rearranged expression of the ideal gas equation where you are<br />

solving for moles.<br />

6. Write the rearranged expression of the combined gas equation where you<br />

are solving for T 2.<br />

7. Fill in the blank in each of the columns below with either I (increases), or D<br />

(decreases), or C (constant). The potential changes apply to a sample of gas:<br />

a. b. c. d. e.<br />

Volume constant ___ constant constant increases<br />

Pressure increases constant increases ___ ___<br />

Temperature constant decreases ___ increases constant<br />

Moles ___ constant constant constant constant<br />

8. A sample of a gas occupies 15.55 L at a temperature of 27C. What temperature,<br />

in C, is necessary to adjust the volume of the gas to 10.00 L?<br />

9. The initial pressure on a sample of oxygen gas was 795.0 torr. At this pressure,<br />

the sample occupied 1250.0 mL at 0C. What was the final pressure, in<br />

atm, of this sample of oxygen gas if the final volume was 1.000 L and the<br />

final temperature was 25C?<br />

10. A sample of xenon gas was collected in a 5.000 L container at a pressure of<br />

225.0 mmHg, and a temperature of 27.0C. Later the pressure had changed<br />

to 1.000 atm, and the temperature was 0.0C. What was the new volume, in<br />

liters, of the gas?<br />

11. The molecular weight of an unknown gas was to be determined through an<br />

effusion experiment. The unknown gas effused at a rate of 0.1516 mL/s. Under<br />

the same conditions, a sample of oxygen effused at a rate of 0.3238 mL/s.<br />

Determine the molecular weight of the unknown gas.<br />

12. The decomposition of NaN3 will generate N2 gas. A 8.25 L sample of gas was<br />

collected over water at 25C and at a total pressure of 875 torr. How many<br />

grams of NaN3 reacted? The vapor pressure of water, at 25C, is 24 torr.<br />

2 NaN3(s) l 2 Na(s) 3 N2(g)

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