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Untitled - Kelly Walsh High School

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Thermochemistry 99<br />

Quick Tip<br />

Don’t Forget!<br />

or released during the chemical or physical change is q, and is proportional to<br />

the change in temperature of the system. This system has a heat capacity, which<br />

is the quantity of heat needed to change the temperature 1 K. It has the form:<br />

Heat capacity q/T<br />

The heat capacity most commonly has units of J/K. The specific heat capacity<br />

(or specific heat) (c), is the quantity of heat needed to raise the temperature of<br />

1 g of the substance 1 K:<br />

c q/(mass)(T) or q (c)(mass)(T)<br />

The specific heat capacity commonly has units of J/gK. The specific heat capacity<br />

of water is 4.18 J/gK. If we have the specific heat capacity, the mass, and the<br />

change of temperature, it is possible to determine the amount of energy<br />

absorbed or released (q).<br />

The specific heat capacity of water is necessary to solve many problems.<br />

However, when reading the problem, it is often not apparent that you must use<br />

this value. If the problem mentions water, its specific heat capacity will often be<br />

part of the solution to the problem.<br />

Don’t mix energy units, J and cal; always use appropriate conversions.<br />

Another related quantity is the molar heat capacity (C), the amount of heat<br />

needed to change the temperature of 1 mol of a substance 1 K.<br />

Calorimetry involves the use of a laboratory instrument called a calorimeter.<br />

Two types of calorimeters are commonly used, a simple coffee-cup calorimeter<br />

and a more sophisticated bomb calorimeter. In both, we carry out a reaction<br />

with known amounts of reactants and the change in temperature is measured.<br />

Check your textbook for pictures of one or both of these.

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