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Untitled - Kelly Walsh High School

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Molecular Geometry and Hybridization 153<br />

Don’t Forget!<br />

Don’t Forget!<br />

simplicity, the 1s orbitals of each oxygen and MOs have not been shown here,<br />

just the valence electron orbitals.<br />

The bond order for O 2 would be (10 6)/2 2.<br />

To count the bonding and antibonding electrons at energy level 1.<br />

When adding electrons to MOs, add them to the lowest energy orbital first. If the<br />

orbitals have equal energies remember to half-fill the orbitals and then pair-up<br />

the electrons.<br />

10-4 Utterly Confused About<br />

Molecular Geometry<br />

We will examine the geometries of the two Lewis structures derived in Section 9-7.<br />

Η Ο<br />

N O F<br />

F<br />

Xe F<br />

In order to predict the molecular geometries, you must have a correct Lewis<br />

structure. We will begin with the structure of nitrous acid. There are two central<br />

atoms in this structure: the nitrogen and the oxygen atom with the hydrogen<br />

attached. We will begin with the nitrogen atom. This atom has an octet of<br />

electrons surrounding it. It has a lone pair and three bonding pairs distributed<br />

between a single and two double bonds. To predict the electron-group geometry,<br />

we count one for the lone pair, one for the single bond, and one for the<br />

F

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