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Untitled - Kelly Walsh High School

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Chemistry: First Steps 5<br />

exact normally by definition. There are exactly 12 items in a dozen, 36 inches in<br />

a yard, and so forth. Measured values, like the ones you will be dealing with in<br />

lab, have uncertainty associated with them because of the limitations of our<br />

measuring instruments. When those measured values appear in calculations,<br />

the answer must reflect that combined uncertainty by the number of significant<br />

figures that you report in the final answer. The more significant numbers reported,<br />

the greater the certainty in the answer.<br />

The measurements that you use in calculations may contain varying numbers of<br />

significant figures, so carry as many as possible until the end and then round off<br />

the final answer. The least precise measurement will determine the significant<br />

figures reported in the final answer. Determine the number of significant figures<br />

in each measured value (not the exact ones) and then, depending on the mathematical<br />

operations involved, round off the final answer to the correct number<br />

of significant figures. Here are the rules for determining the number of significant<br />

figures in a measured value:<br />

1. All nonzero digits (1, 2, 3, 4, and so on.) are significant.<br />

2. Zeroes between nonzero digits are significant.<br />

3. Zeroes to the left of the first nonzero digit are not significant.<br />

4. Zeroes to the right of the last nonzero digit are significant if there is a decimal<br />

point present, but not significant if, there is no decimal point.<br />

Rule 4 is a convention that we will be using, but some teachers or books may<br />

use alternative methods, so check with your instructor for the convention she or<br />

he would like you to use.<br />

By these rules, 0.320400 would contain six significant figures but 320,400 would<br />

only contain four.<br />

Another way to determine the number of significant figures in a number is to<br />

express it in scientific (exponential) notation. The number of digits shown is the<br />

number of significant figures. For example, 2.305 10 5 would contain four significant<br />

figures.<br />

In determining the number of significant figures you will express in the final<br />

answer, the following rules apply:<br />

1. For addition and subtraction problems, round the answer off to the same<br />

number of decimal points as the measurement with the fewest decimal places.<br />

18.256 cm 7.25 cm 2.7 cm 28.206 cm 28.2 cm (rounded to the<br />

tenths place)

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