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Untitled - Kelly Walsh High School

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184 CHEMISTRY FOR THE UTTERLY CONFUSED<br />

Don’t Forget!<br />

To calculate the boiling point of the solution we use the relationship:<br />

Tb iKbm We already have the van’t Hoff factor, K b, and solution molality so we can simply<br />

substitute:<br />

Tb iKb molality (3) (0.52°C/m) (0.545620951 m)<br />

0.85116868°C (unrounded)<br />

Tb (100.00 0.85116868)°C 100.85°C<br />

The most common error made in colligative property problems is to forget to separate<br />

the ions of an electrolyte. The van’t Hoff factor, even when not needed, is<br />

a useful reminder.<br />

In this chapter, you learned about solutions. A solution is a homogeneous mixture<br />

composed of a solvent and one or more solutes. Solutions may be unsaturated,<br />

saturated, or supersaturated. Solution concentration units include percentage,<br />

molarity, molality, and mole fraction. The solubility of solids in liquids<br />

normally increases with increasing temperature, but the reverse is true of gases<br />

dissolving in liquids. The solubility of gases in liquids increases with increasing<br />

pressure.<br />

Colligative properties are those properties of solutions that depend on the number<br />

of solute particles present and not their identity. Colligative properties<br />

include vapor pressure lowering, freezing point depression, boiling point elevation,<br />

and osmotic pressure. Colloids are homogeneous mixtures, in which the<br />

solute particles are intermediate in size between suspensions and true solutions.<br />

We can distinguish colloids from true solutions by the Tyndall effect.<br />

1. What phrase applies to a situation where a polar solvent dissolves a polar<br />

solute?<br />

2. A solution containing the maximum amount of solute per given amount of<br />

solvent at a given temperature is said to be<br />

a. concentrated b. dilute c. unsaturated<br />

d. saturated e. supersaturated

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