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Untitled - Kelly Walsh High School

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70 CHEMISTRY FOR THE UTTERLY CONFUSED<br />

Mg(s) 2 HC 2H 3O 2(aq) l Mg 2 (aq) H 2(g)<br />

Al 2(SO 4) 3(aq) Fe(s) l NR<br />

2 Li(s) 2 H 2O(aq) l 2 Li (aq) H 2(g)<br />

Completing the reactants requires the addition of the following ions: reaction 1,<br />

2 Cl ; reaction 2, 2 Br ; reaction 3, 2 C 2H 3O 2 ; reaction 4, no ions; reaction 5, 2<br />

OH . To balance the reactions we add these ions to the other side of the reaction<br />

arrow and combine with the cations present on the other side. This gives<br />

the molecular equations.<br />

Ni(s) 2 HCl(aq) l NiCl 2(aq) H 2(g)<br />

Zn(s) CuBr 2(aq) l ZnBr 2(aq) Cu(s)<br />

Mg(s) 2 HC 2H 3O 2(aq) l Mg(C 2H 3O 2) 2(aq) H 2(g)<br />

Al 2(SO 4) 3(aq) Fe(s) l NR<br />

2 Li(s) 2 H 2O(aq) l 2 LiOH(aq) H 2(g)<br />

We can now follow the steps used previously to convert each of these to a total<br />

ionic equation:<br />

Ni(s) 2 H (aq) 2 Cl (aq) l Ni 2 (aq) 2 Cl (aq) H 2(g)<br />

Zn(s) Cu 2 (aq) 2 Br (aq) l Zn 2 (aq) 2 Br (aq) Cu(s)<br />

Mg(s) 2 HC 2H 3O 2(aq) l Mg 2 (aq) 2 C 2H 3O 2 (aq) H2(g)<br />

Al 2(SO 4) 3(aq) Fe(s) l NR<br />

2 Li(s) 2 H 2O(aq) l 2 Li (aq) 2 OH (aq) H 2(g)<br />

Finally, we eliminate the spectator ions to obtain the net ionic equations:<br />

Ni(s) 2 H (aq) l Ni 2 (aq) H 2(g)<br />

Zn(s) Cu 2 (aq) l Zn 2 (aq) Cu(s)<br />

Mg(s) 2 HC 2H 3O 2(aq) l Mg 2 (aq) 2 C 2H 3O 2 (aq) H2(g)<br />

Al 2(SO 4) 3(aq) Fe(s) l NR<br />

2 Li(s) 2 H 2O(aq) l 2 Li (aq) 2 OH (aq) H 2(g)<br />

4-6 Utterly Confused About Titrations<br />

A common laboratory application of acid-base reactions is titration. A titration<br />

is a laboratory procedure in which we use a solution of known concentration to<br />

determine some information (such as concentration and mass) about an<br />

unknown substance. A titration may involve any type of reaction—acid-base,<br />

redox, and so on. In this section, we will only consider acid-base titrations. The

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