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Untitled - Kelly Walsh High School

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300 CHEMISTRY FOR THE UTTERLY CONFUSED<br />

use of magnetic fields (“magnetic bottles”) to contain the nuclei at this temperature.<br />

If they can overcome these obstacles, fusion may well provide a limitless<br />

energy source for our world. The production of neutrons by this process is a<br />

problem. It is difficult to keep a neutron in a magnetic bottle. Escaping neutrons<br />

will convert some of the material in the fusion plant into radioactive wastes.<br />

20-6 Utterly Confused About<br />

Nuclear Decay<br />

Nuclear decay problems normally use one or both of the following equations:<br />

(1) ln (N t/N 0) kt and (2) t 1/2 (ln 2)/k or t 1/2 0.693/k<br />

The terms N t and N 0 may have many different units. The only restriction on the<br />

units is that these two terms have the same units. If they do not have the same<br />

units, you will need to convert one of the units. Both t and t 1/2 will have units of<br />

time. Any time unit may be present. The rate constant (decay constant), k, will<br />

have units of time 1 . Any time unit may be present. The time units for t, t 1/2, and<br />

k must agree. If the units do not agree, you will need to make a conversion.<br />

Let’s look at some sample questions.<br />

Determine the decay constant for iron-55. The half-life of iron-55 is 2.7 years.<br />

You should begin a problem of this type by recopying and labeling each of the<br />

known and unknown variables:<br />

k ? t 1/2 2.7 y<br />

These two variables appear in the equation t 1/2 (ln 2)/k. We can rearrange this<br />

equation to find k, and enter the value for the half-life:<br />

k (ln 2)/t 1/2 (ln 2)/2.7 y 0.693/2.7 y 0.256667 0.26 y 1<br />

What is the half-life for argon-41? The decay constant for argon-41 is 6.33 <br />

10 3 min 1 .<br />

We can recopy and label the variables to get:<br />

k 6.33 10 3 min 1 t 1/2 ?<br />

These two variables appear in the equation t 1/2 (ln 2)/k. We do not need to<br />

rearrange this equation. We only need to enter the value for the decay constant.

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