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Untitled - Kelly Walsh High School

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210 CHEMISTRY FOR THE UTTERLY CONFUSED<br />

Careful!<br />

Quick Tip<br />

A container has the following equilibrium established at 700°C:<br />

N 2(g) 3 H 2(g) K 2 NH 3(g)<br />

The equilibrium mixture had an ammonia concentration of 0.120 M, a nitrogen<br />

concentration of 1.03 M, and a hydrogen concentration of 1.62 M. Determine the<br />

value of the equilibrium constant, K c.<br />

Temperatures often appear in equilibria problems, but most problems will not<br />

require you to use the temperature.<br />

The first step in this, and most equilibria problems, should begin by writing the<br />

equilibrium constant expression. In this case, the expression is:<br />

K c [NH 3 ]2<br />

[N 2 ][H 2 ] 3<br />

This step will, in most cases, get you some partial credit.<br />

The problem gives us: [NH 3] 0.120 M, [N 2] 1.03 M, and [H 2] 1.62 M. The<br />

next step is to enter the given values into the equilibrium constant expression<br />

and enter the values into your calculator.<br />

Kc 3.288367 103 3.29 103 [0.120] 2<br />

[1.03] [1.62] 3<br />

[NH3 ] 2<br />

[N2 ][H2 ] 3<br />

The equilibrium value for the following equilibrium is 2.42 10 3 at a certain<br />

temperature. N 2(g) 3 H 2(g) K 2 NH 3(g) Determine the ammonia concentration<br />

at equilibrium with 2.00 M nitrogen and 3.00 M hydrogen.

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