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Untitled - Kelly Walsh High School

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Mass, Moles, and Equations 43<br />

the balanced chemical equation. (This is one place where, if we did not balance<br />

the equation, we would be in trouble.)<br />

I 2 0.295508 mol I 2<br />

1<br />

F 2 0.66423 mol F 2<br />

5<br />

The quantity (mole-to-coefficient ratio) of F 2 is smaller than that of I 2; therefore,<br />

fluorine in the limiting reactant (reagent). Once we know the limiting<br />

reactant, all remaining calculations will depend on the limiting reactant.<br />

Now we can find the maximum number of moles of IF 5 that can be produced<br />

(theoretical yield). We will begin with our limiting reactant rather than using<br />

the 45.2 g of IF 5 given (actual yield). Remember, the limiting reagent is our key,<br />

and we don’t want to lose our key once we have found it.<br />

To find the moles of IF 5 from the limiting reagent, we need to use a mole ratio<br />

derived from information in the balanced chemical equation. (This is another<br />

place where, if we had not balanced the equation, we would be in trouble.)<br />

We will not actually calculate the moles of IF 5 yet; we will simply save this setup.<br />

The problem asks for the percent yield. Recall the definition of percent yield:<br />

%yield <br />

0.295508 (unrounded)<br />

0.132846 (unrounded) (limiting reactant)<br />

mol IF5 (0.66423 mol F2 )a 2 mol IF5 b<br />

5 mol F2 actual yield<br />

theoretical yield<br />

In this problem, the actual yield is the amount of product found by the scientist<br />

(45.2 g IF 5); therefore, we need the theoretical yield to finish the problem.<br />

Since our actual yield has the units “g IF 5,” our theoretical yield must have<br />

identical units. To determine the grams of IF 5 from the moles of limiting reactant,<br />

we need the molar mass of IF 5 [126.9 g I/mol I 5 (19.00 g F/mol F) <br />

221.9 g IF 5/mol].<br />

Mass IF 5 (0.66423 mol F 2 )a 2 mol IF 5<br />

5 mol F 2<br />

100 %<br />

58.957 g IF 5 (unrounded)<br />

ba 221.9 g IF5 b<br />

1 mol IF5

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