School of Engineering and Science - Jacobs University

Appendix 1 continued. Data in mg/kg.
JDo-1 JMn-1 BHVO-2
Garbe- Govindaraju Imai Dulski Yamamoto
this
this
Terashima Imai Dulski
this
Plumlee Huang Willbold Shafer Schramm Ryder Polat
this
Schönberg (1994) et al. (2001) (2004)
study
study
et al. et al. (2001)
study
(1998) and Frey and et al. et al. (2006) et al.
study
(1993)
(1996)
HF-HClO4 carbonate 4
(1995) (1999)
(2003) Jochum (2005) (2005)
(2006)
(2005)
method 1 ICPMS compiled compiled ICPMS ICPMS ref. avg. 2 %RSD JUB avg. 3 %RSD JUB avg. 3 %RSD ICPMS compiled ICPMS ref. avg. %RSD JUB avg. %RSD compiled ICPMS ICPMS ICPMS ICPMS ICPMS ICPMS ref. avg. %RSD JUB avg. %RSD
HF-HClO4
(n=5)
(n=7)
(n=4)
(n=7)
Sc 0.5 0.14 0.136 0.259 66.0 0.195 23.7 0.265 6.8 13 13 10.1 12.7 32 38 30.1 32 33.0 9.0 30.9 7.4
Ti 7.97 7.97 8.80 10.1 2.10 8.9 6360 6360 5160 10.5 16300 16300 12700 15.3
Co 0.3 0.168 0.234 28.2 1.46* 29.6 0.689* 16.9 1692 1732 1712 1.2 1080 5.9 45 56.2 41 45.7 42 46.0 11.8 44.3 6.0
Ni 2.9 2.9 2.9 0.0 11.1* 2.8 3.04 5.9 12552 12632 12592 0.3 7770 12.1 119 137 107 115 115 119 8.4 124 19.3
Rb 1.5 0.14 0.82 82.9 0.0940 9.1 0.0434 25.0 11.04 10.9 11.6 11.18 2.7 9.99 3.1 9.8 9.48 8.56 10.1 8.71 9.77 8.69 9.30 6.3 9.42 5.6
Sr 108 119 116 117 115 3.6 117 5.7 113 2.6 737 792 800 776 3.6 653 5.5 389 399 394 407 389 396 368 392 2.9 379 4.3
Y 8.9 11.2 10.3 10.4 10.2 8.1 10.6 3.3 11.0 3.0 106.49 111 114 110.50 2.8 95.1 2.5 26 28.3 29 25.8 23.2 28 23 26.2 8.5 24.3 2.6
Zr 0.4 6.21 0.56 2.39 113.1 0.567 1.4 0.237 12.8 350 344 392 362 5.9 318 2.9 172 178 172 174 168 181 158 172 4.0 168 4.9
Nb 0.2 0.2 0.253 40.6 0.0072 12.5 27.42 22.3 24.86 10.3 24.1 10.2 18 19 18.9 19.2 16.6 15.8 15 17.5 9.0 17.5 4.5
Mo 0.4 0.4 0.4 0.0 0.291 7.5 0.282 34.3 316 318 317 0.3 268 2.0 4 3.94 3.97 0.8 4.58 14.9
Cs 0.019 0.019 0.0072 8.8 0.0030 19.8 0.41 0.604 0.37 0.461 22.2 0.324 3.8 0.1 0.11 0.09 0.11 0.09 0.10 8.9 0.0954 4.6
Ba 24 6.14 7 12.4 66.4 6.26 19.1 5.54 2.5 1702 1714 1511 1642 5.7 1450 2.9 130 135 131 142 129 133 125 132 3.8 128 3.4
La 7.1 7.87 7.93 7.7 7.56 7.63 3.9 7.75 3.7 7.84 2.8 124.88 122 121 122.63 1.3 109 2.6 15 15.2 15.3 15.5 14.5 15.3 14.23 15.00 2.9 14.8 2.8
Ce 1.85 2.54 2.49 2.02 2.06 2.19 12.5 2.07 3.4 2.12 2.3 286 277 271 278 2.2 274 19.4 38 38.4 37.6 38.4 35.3 37.5 35.73 37.28 3.1 36.8 3.1
Pr 0.97 0.9 0.956 1.05 0.986 0.972 5.0 1.01 3.9 1.02 2.5 29.72 31.4 32 31.04 3.1 28.3 3.7 5.35 5.57 5.31 5.72 5.1 5.39 4.96 5.34 4.5 5.18 2.9
Nd 4 5.33 5.25 4.09 4.21 4.58 12.8 4.18 3.6 4.25 2.4 127.88 137 123 129.29 4.5 118 3.1 25 24.9 24.5 24.8 23.4 24.6 22.8 24.3 3.2 24.0 3.6
Sm 0.73 0.84 0.788 0.68 0.686 0.745 8.2 0.708 2.9 0.712 2.7 29.25 30.2 27 28.82 4.7 26.7 3.6 6.2 6.16 6.04 5.99 5.9 6.12 5.69 6.01 2.7 5.96 3.1
Eu 0.15 0.19 0.176 0.162 0.154 0.166 8.9 0.159 4.0 0.161 3.0 7.26 7.58 7.53 7.46 1.9 6.60 2.0 2.07 2.03 2.05 2.07 1.96 2.07 1.96 2.03 2.3 2.03 3.2
Gd 0.87 0.87 0.9 0.872 0.878 1.4 0.910 4.1 0.904 3.5 26.05 29.8 32.1 29.32 8.5 27.8 0.5 6.3 6.13 6.23 6.48 5.9 6.32 6.13 6.21 2.7 6.11 2.1
Tb 0.12 0.12 0.116 0.12 0.113 0.118 2.4 0.121 3.9 0.121 3.3 4.42 4.81 4.92 4.72 4.5 4.27 1.6 0.9 0.963 0.933 0.9 0.9 0.959 0.89 0.921 3.1 0.908 2.9
Dy 0.71 1 0.814 0.75 0.747 0.804 12.9 0.754 3.6 0.755 3.4 25.65 28.3 28.6 27.52 4.8 25.3 2.1 5.31 5.3 5.29 5.25 5.2 5.34 5.07 5.25 1.6 5.18 3.0
Ho 0.17 0.2 0.164 0.167 0.164 0.173 7.9 0.168 3.9 0.168 3.6 5.49 5.76 5.58 5.61 2.0 4.93 2.4 1.04 1.01 0.964 1.03 0.95 1.01 0.93 0.991 4.0 0.960 2.5
Er 0.44 0.44 0.46 0.462 0.451 2.3 0.466 3.0 0.465 3.2 13.26 14.6 15.6 14.49 6.6 13.8 1.8 2.54 2.5 2.49 2.49 2.4 2.53 2.39 2.48 2.2 2.49 2.6
Tm 0.06 0.06 0.058 0.056 0.055 0.058 3.5 0.0550 3.8 0.0550 3.9 2.04 2.14 2.21 2.13 3.3 1.94 2.1 0.33 0.35 0.321 0.34 0.32 0.34 0.31 0.330 3.9 0.316 3.0
Yb 0.29 0.36 0.323 0.305 0.303 0.316 7.7 0.301 3.3 0.297 3.5 12.86 13.8 14.4 13.69 4.6 12.5 2.4 2 2.05 1.95 2.01 1.91 2.03 1.84 1.97 3.5 1.90 2.7
Lu 0.05 0.05 0.0494 0.043 0.042 0.0469 7.7 0.0426 4.2 0.0427 3.9 2.06 2.07 2.16 2.10 2.1 1.91 3.1 0.28 0.286 0.269 0.28 0.26 0.278 0.25 0.272 4.4 0.272 3.1
Hf 0.12 0.1 0.0897 0.1032 12.2 0.0148 5.9 0.0053 16.7 6.1 6.23 6.4 6.24 2.0 5.59 4.3 4.1 4.42 4.2 4.58 4.4 4.38 4.35 3.6 4.27 4.7
Ta 0.009 0.009 0.0137 75.1 0.0010 0.0 0.68 0.635 0.658 3.4 0.485 10.6 1.4 1.22 1.08 1.23 1.09 0.686 0.92 1.089 19.8 1.06 6.7
W 0.26 0.26 0.276 13.5 0.248 17.5 37.49 45.3 41.40 9.4 34.7 7.5 0.21 0.29 0.25 16.0 0.228 6.7
Pb 0.5 1 0.19 0.77 0.62 49.2 0.450 4.4 0.352 23.7 444 430 434 436 1.4 360 4.3 1.6 1.53 1.8 1.22 1.58 2.89 1.58 1.74 28.4 1.63 9.2
Th 0.04 0.0429 0.0415 3.5 0.0556 3.3 0.0521 6.1 11.93 11.7 13 12.21 4.6 10.2 3.9 1.2 1.3 1.13 1.32 1.2 1.22 1.53 1.27 9.5 1.23 4.7
U 0.8 0.858 0.88 0.846 4.0 1.03 3.9 0.987 6.1 4.81 5.01 5.3 5.04 4.0 4.32 3.2 0.403 0.446 0.403 0.45 0.42 0.425 0.4 0.421 4.6 0.430 3.4
1 data sources, whether compiled from studies or from single analytical method, and arranged in chronologically.
2 reference average reported to number of significant digits observed in most precisely measured data from literature sources.
3 JUB average calculated from number of sample decompositions reported in Table 1 and reported to three significant digits only for illustrative purposes (see Section 5 regarding analytical precision), with exception of some elements for JDo-1 carbonate decomposition method.
4 data for JDo-1 includes measured concentrations as determined using both the HF-HClO 4 and carbonate (HNO 3 ) sample decomposition methods (see Fig. 1). Note that Ni data for carbonate decomposition solely determined from the 62 Ni isotope.
* values greater than reference average considered to include significant contributions from interfering molecular species, arising from high major element contents (Mg, Al, Ca, Mn, Fe).
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