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56 Substance <strong>flow</strong> <strong>analysis</strong> <strong>of</strong> <strong>the</strong> <strong>recycling</strong> <strong>of</strong> <strong>small</strong> WEEE<br />

between equipment types with different functions, but also between single appliances within<br />

one equipment type.<br />

If no data on <strong>the</strong> average concentration <strong>of</strong> precious metals in <strong>the</strong> equipment groups was<br />

directly available, quantifying <strong>the</strong> concentration <strong>of</strong> precious metals in <strong>the</strong> different equipment<br />

groups in 2007 requires data at <strong>the</strong> following information levels (see hierarchy illustrated in<br />

Figure 11):<br />

(1) The types <strong>of</strong> equipment contained in <strong>the</strong> equipment groups (mass-based breakdown),<br />

(2) The average material composition <strong>of</strong> <strong>the</strong> equipment types and<br />

(3) The average precious metals concentration in <strong>the</strong> different equipment types.<br />

The average concentration <strong>of</strong> precious metals in <strong>the</strong> devices was calculated by assuming<br />

that <strong>the</strong> precious metals in sWEEE can only be found in printed circuit boards. Precious<br />

metals may be contained in o<strong>the</strong>r parts like connectors, contacts, cables and solders<br />

(Gmünder 2007; Hagelüken 2006a), but no quantitative data are available regarding <strong>the</strong><br />

precious metals contained in <strong>the</strong>se components.<br />

The following formula was used:<br />

c<br />

PM,G<br />

<br />

n<br />

<br />

T1<br />

c<br />

PM,PCB,T<br />

M<br />

G<br />

M<br />

With:<br />

c PM,G : mean concentration <strong>of</strong> precious metal in <strong>the</strong> equipment group G<br />

c PM,PCB,T : mean concentration <strong>of</strong> precious metal in <strong>the</strong> printed circuit boards <strong>of</strong> equipment type T<br />

M T : mass <strong>of</strong> devices <strong>of</strong> equipment type T (belonging to equipment group G) generated in 2007<br />

M G : total mass <strong>of</strong> devices <strong>of</strong> equipment group G generated in 2007<br />

T<br />

The estimation <strong>of</strong> <strong>the</strong> mean concentrations <strong>of</strong> precious metals does not take into<br />

consideration <strong>the</strong> temporal and spatial variations <strong>of</strong> <strong>the</strong> characteristics <strong>of</strong> sWEEE. These<br />

variations are originated by technological changes (for example implementation <strong>of</strong> new<br />

nanotechnologies in EEE), market changes or legislative requirements, like experienced<br />

since 2006 in <strong>the</strong> European Union through <strong>the</strong> implementation <strong>of</strong> <strong>the</strong> Restriction <strong>of</strong><br />

Hazardous Substances Directive, which restricts <strong>the</strong> use <strong>of</strong> six hazardous materials in <strong>the</strong><br />

manufacture <strong>of</strong> various types <strong>of</strong> EEE. Since not enough data is available on <strong>the</strong><br />

characteristics <strong>of</strong> WEEE in 2007 and in <strong>the</strong> investigated regions (Germany and USA), <strong>the</strong><br />

results <strong>of</strong> characterisation studies conducted in o<strong>the</strong>r periods and at o<strong>the</strong>r locations had to be<br />

considered.

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