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SUbstance flow analysis of the recycling of small waste electrical ...

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80 Substance <strong>flow</strong> <strong>analysis</strong> <strong>of</strong> <strong>the</strong> <strong>recycling</strong> <strong>of</strong> <strong>small</strong> WEEE<br />

processed in a facility <strong>of</strong> type ‘mechanical 2’, whereas <strong>the</strong> remaining 24% is pre-processed<br />

manually. 26% <strong>of</strong> collection group 5 is pre-processed manually, 25% in facilities <strong>of</strong> type<br />

‘mechanical 1’ and 49% in facilities <strong>of</strong> type ‘mechanical 2’. Table 28 presents <strong>the</strong> assumed<br />

distribution <strong>of</strong> <strong>the</strong> sWEEE over <strong>the</strong> four kinds <strong>of</strong> pre-processing facilities in 2007, as well as<br />

assumptions on <strong>the</strong> recovery rates for precious metals achieved by <strong>the</strong> three types <strong>of</strong> preprocessing<br />

facilities. The assumptions are based on <strong>the</strong> results <strong>of</strong> experimental substance<br />

<strong>flow</strong> analyses conducted in pre-processing facilities for sWEEE.<br />

Chancerel & Rotter (2008b) investigated a manual dismantling process and estimated that<br />

around 82% <strong>of</strong> <strong>the</strong> gold contained in sWEEE <strong>of</strong> collection group 3 is sent directly to a<br />

precious-metals recovery process. The remaining gold is ei<strong>the</strong>r sent to fur<strong>the</strong>r mechanical<br />

pre-processing or sent to plastic <strong>recycling</strong> and lost. It is assumed that in total, pre-processing<br />

through manual dismantling allows <strong>the</strong> recovery <strong>of</strong> 90% <strong>of</strong> <strong>the</strong> gold and palladium. The<br />

results have <strong>the</strong> same order <strong>of</strong> magnitude as <strong>the</strong> results <strong>of</strong> Meskers et al. (2009), who<br />

investigated only personal computers. Van Schaik & Reuter (2009) mentioned recovery rates<br />

<strong>of</strong> 15% for gold in a shredding facility that can be assumed to be <strong>of</strong> type ‘mechanical 1’. The<br />

results presented in Paper 2 showed that around 24% <strong>of</strong> gold and palladium are recovered in<br />

a German facility <strong>of</strong> type ‘mechanical 2’. Meskers et al. (2009) conducted similar<br />

experimental investigations in ano<strong>the</strong>r facility using ano<strong>the</strong>r type <strong>of</strong> technology, and<br />

considering only personal computers. Much higher recovery rates (70%) were determined by<br />

Meskers et al. (2009) compared to <strong>the</strong> results <strong>of</strong> Paper 2, probably due to <strong>the</strong> use <strong>of</strong> ano<strong>the</strong>r<br />

liberation technology and <strong>the</strong> homogeneity <strong>of</strong> <strong>the</strong> input material (only PCs) compared to <strong>the</strong><br />

input mix considered in Paper 2.<br />

All <strong>the</strong>se investigations are restricted to a certain facility at a certain time for a certain input<br />

material. The limitations regarding representativeness <strong>of</strong> <strong>the</strong> studies cause high uncertainties<br />

by <strong>the</strong> extrapolation <strong>of</strong> <strong>the</strong> data to <strong>the</strong> whole subsystem ‘pre-processing <strong>of</strong> sWEEE’ in<br />

Germany. However, <strong>the</strong>se experimental results are <strong>the</strong> only available data.<br />

Because personal computers are sometimes dismantled manually in ‘mechanical 2’ facilities,<br />

an average recovery rate <strong>of</strong> 50% was assumed. Regarding CRT monitors, observations<br />

showed that in Germany <strong>the</strong> printed circuit boards are usually removed manually (Bolland<br />

2009). Afterwards, <strong>the</strong>y are usually treated mechanically to separate <strong>the</strong> iron and <strong>the</strong><br />

aluminium from <strong>the</strong> precious metals and <strong>the</strong> copper-rich materials. This mechanical<br />

treatment leads to losses <strong>of</strong> precious metals that have, so far, not been quantified by<br />

experimental investigations. An overall recovery rate for gold from CRT monitors <strong>of</strong> 60% was<br />

assumed.

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