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Examination of Firearms Review: 2007 to 2010 - Interpol

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supported a conclusion that the red paint on the shoes and the red paint applied<br />

<strong>to</strong> one <strong>of</strong> the buildings for the purposes <strong>of</strong> defacing its surface contained the<br />

same observed and measured characteristics.<br />

Two articles were published by Zadora and coauthors that described ongoing<br />

efforts <strong>to</strong> determine the significance <strong>of</strong> paint transfer evidence using likelihood<br />

ratios. One study utilized data generated by FTIR analysis and the other<br />

employed Py-GC/MS results. [142;143] Stable iso<strong>to</strong>pe analysis <strong>of</strong> white paints<br />

was another application <strong>of</strong> likelihood ratios described by Farmer et al. In this<br />

study, iso<strong>to</strong>pe ratio mass spectrometry (IRMS) was used <strong>to</strong> analyze 13 C, 18 O, and<br />

2 H iso<strong>to</strong>pic compositions originating from paint binders.[144]<br />

Further discussion <strong>of</strong> significance assessments were reported in Science and<br />

Justice in <strong>2010</strong> as abstracts <strong>of</strong> presentations given at the 5 th Triennial<br />

Conference <strong>of</strong> the European Academy <strong>of</strong> Forensic Science held in Glasgow,<br />

Scotland in September 2009.[145] A number <strong>of</strong> presentations addressed the<br />

need <strong>to</strong> provide context <strong>to</strong> report conclusions. Use <strong>of</strong> Bayesian statistics,<br />

likelihood ratios, and development <strong>of</strong> a unified ordinal scale <strong>to</strong> describe levels <strong>of</strong><br />

conclusions were presented.<br />

As a final note <strong>to</strong> the discussion <strong>of</strong> significance, paint examiners routinely review<br />

trade journals and consult with experts from the coatings industry in order <strong>to</strong><br />

guide critical thinking as <strong>to</strong> the probative value <strong>of</strong> an examination request or the<br />

appropriate interpretation <strong>of</strong> analytical findings. In this regard, educating the<br />

paint and coatings industry about forensic paint examinations can be as critical<br />

as the reverse. To that end, Mike Eyring, formerly <strong>of</strong> the Arizona Department <strong>of</strong><br />

Public Safety, wrote a review <strong>of</strong> several forensic paint cases that highlight how<br />

forensic paint examinations are conducted and how they can be used within the<br />

context <strong>of</strong> criminal investigations.[146]<br />

9. Studies regarding au<strong>to</strong>motive finishes and refinishes<br />

Research on the performance <strong>of</strong> coated galvanized steel was reported on by<br />

San<strong>to</strong>s et al. in which waterborne and solvent borne basecoats were compared<br />

on primed and pre-primed steel sheets in order <strong>to</strong> study effects on<br />

adhesion.[147] In general, the waterborne finishes showed better adhesion<br />

results over the solvent borne coatings. Not surprisingly, the use <strong>of</strong> primers also<br />

promoted better adhesion. Other results included comparison <strong>of</strong> the differences<br />

noted between electrogalvanized, hot dip galvanized, and galvannealed steel for<br />

these adhesion tests.<br />

Three papers were published during this review period that discussed analysis or<br />

development <strong>of</strong> systems used in au<strong>to</strong>motive refinishes. In the first, au<strong>to</strong>motive<br />

body fillers were characterized in order <strong>to</strong> better assess discrimination <strong>of</strong> these<br />

materials in casework.[148] Thirty-three samples <strong>of</strong> body filler and spot putties<br />

were analyzed using light microscopy, FTIR, SEM/EDS, and Py-GC. Overall, 19<br />

135

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