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Examination of Firearms Review: 2007 to 2010 - Interpol

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normally exposed images subsequently processed with standard digital<br />

modifications.<br />

When speaking about fingermarks (or about reference fingerprints), the image quality<br />

is <strong>of</strong> a first importance if it is defined as the apparent visibility <strong>of</strong> the existing ridges<br />

and ridge details. This subject is discussed by Smith in an article whose aim is <strong>to</strong><br />

encourage the readers <strong>to</strong> think about such issues (347).<br />

A tu<strong>to</strong>rial was dedicated <strong>to</strong> the use <strong>of</strong> a function named “Black & White adjustment”<br />

(B&W), included in the Adobe Pho<strong>to</strong>shop CS3 s<strong>of</strong>tware (and later), <strong>to</strong> enhance<br />

images <strong>of</strong> fingermarks left on multicoloured substrates (345). The B&W option<br />

provides the ability <strong>to</strong> work on a monochromatic representation <strong>of</strong> an image while still<br />

having the full access <strong>to</strong> the individual colour channels. Compared <strong>to</strong> the “channel<br />

mixer” function, which works on three colour channels (i.e., red, green, blue), the<br />

B&W option allows <strong>to</strong> work on six colour channels (i.e., red, green, blue, cyan,<br />

magenta, yellow), providing fine image tuning capabilities such as multicoloured<br />

background removal.<br />

2.3.3 Chemical imaging using Fourier transform infrared (FTIR) and Raman<br />

FTIR<br />

Vibrational spectroscopic techniques, such as Fourier transform infrared<br />

(FTIR) or Raman, represent a non-invasive way <strong>to</strong> investigate the<br />

chemical composition <strong>of</strong> latent fingermarks left on non-porous (348, 349)<br />

or on difficult substrates (350, 351), as well as <strong>to</strong> moni<strong>to</strong>r the presence <strong>of</strong><br />

exogenous substances, such as cosmetics (352), drugs (352-356) or<br />

explosives (320-322, 353, 357). But they could also be used <strong>to</strong> image<br />

superimposed fingermarks (357). Nevertheless, the sensitivity <strong>of</strong> these<br />

spectroscopy-based methods (<strong>to</strong> image fingermarks or <strong>to</strong> identify<br />

contaminants) strongly depends on the differentiation between the<br />

spectrum <strong>of</strong> the material from the spectral response <strong>of</strong> the substrate and<br />

<strong>of</strong> the secretion. Moreover, the issues related <strong>to</strong> the size <strong>of</strong> the imaged<br />

area, the difficulty <strong>to</strong> localize a mark on an entire item prior <strong>to</strong> any imaging<br />

attempt, and <strong>to</strong> the scanning time still constitute limiting aspects that are<br />

not always sufficiently emphasized in the contributions.<br />

The conjunction <strong>of</strong> attenuated <strong>to</strong>tal reflection microscopy with Fourier transform<br />

infrared spectroscopy (ATR-FTIR) provided the possibility <strong>to</strong> image gelatine-lifted<br />

(untreated) fingermarks <strong>to</strong> study the chemical composition <strong>of</strong> various components<br />

contained in adult fingermarks (348, 349). The advantage <strong>of</strong> ATR-FTIR, compared <strong>to</strong><br />

conventional FTIR, mainly lies in the possibility <strong>to</strong> reduce the interference <strong>of</strong> the<br />

substrate (the gel lifter in this case) that could cover and hinder the spectral features<br />

<strong>of</strong> the latent secretions. In a first study, sebum-rich fingermarks were left on various<br />

substrates (e.g., door handle, mug handle, curved glass surface, computer screen)<br />

before being lifted using two commercial gel lifters (i.e., BVDA Gelatine Lifter and<br />

Dycem Gel Print Lifter) and analysed by ATR-FTIR. Imaging <strong>of</strong> sebaceous-rich<br />

regions <strong>of</strong> the lifted-fingermarks showed that the gels could spectrally dominate and<br />

hinder the latent secretion spectra, making difficult the investigation <strong>of</strong> the chemical<br />

composition <strong>of</strong> the fingermarks. By changing the angle <strong>of</strong> incidence, the interference<br />

281

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