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Examination of Firearms Review: 2007 to 2010 - Interpol

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In the context <strong>of</strong> standardization <strong>of</strong> the fingermark sampling pro<strong>to</strong>cols, the study<br />

proposed by Crox<strong>to</strong>n et al. showed that lipids are logically over represented in<br />

“groomed” fingermarks (i.e., when the donors are asked <strong>to</strong> rub their fingers on their<br />

face or hair prior the deposition <strong>of</strong> fingermarks) compared <strong>to</strong> natural marks (202).<br />

Eighteen donors were asked <strong>to</strong> leave “natural” fingermarks and sebum-rich ones on<br />

a non-porous substrate. All the fingermarks were immediately analysed using gas<br />

chroma<strong>to</strong>graphy coupled with a mass spectrometer (GC-MS). On average, fatty acid<br />

content could be over represented by a ratio <strong>of</strong> 4:1, squalene by a ratio <strong>of</strong> 16:1, and<br />

the <strong>to</strong>tal sebaceous mass by a ratio <strong>of</strong> 6:1, compared <strong>to</strong> natural marks. This over<br />

representation in lipids could seriously compromise the validity <strong>of</strong> some published<br />

results. It should be noted that the amino acid composition remained significantly<br />

similar between the two kinds <strong>of</strong> fingermarks. Moreover, the relative abundance <strong>of</strong><br />

amino acids was consistent with previously published studies (212), with serine as<br />

the most abundant amino acid followed by glycine, alanine and aspartic acid. Finally,<br />

no correlation between the <strong>to</strong>tal amount <strong>of</strong> fatty acids and <strong>of</strong> amino acids was<br />

observed in both kinds <strong>of</strong> fingermarks. This result seems logical since these<br />

chemicals are secreted by different glands.<br />

Soltyszewski et al. studied the effect <strong>of</strong> water on the recovery <strong>of</strong> fingermarks and<br />

DNA pr<strong>of</strong>iling (209). For this study, 456 sebum-rich fingermarks were left by eight<br />

donors, on glass (10 seconds <strong>of</strong> contact time, medium pressure). Additionally, four<br />

different kinds <strong>of</strong> water (i.e., river, sea, tap, and distilled), two temperature conditions<br />

(i.e., 5 and 20°C), and six immersion times (from one day <strong>to</strong> 42 days) were<br />

considered. The samples were then dried, processed by three fingermark detection<br />

techniques (i.e., aluminium and ferromagnetic powders, and cyanoacrylate), then<br />

swabbed for DNA pr<strong>of</strong>iling. Fingermarks were successfully retrieved for items being<br />

submerged in water for up <strong>to</strong> six weeks, with high success rates for one <strong>to</strong> seven<br />

days <strong>of</strong> immersion. Ferromagnetic powder and cyanoacrylate fuming showed <strong>to</strong> be<br />

more effective than aluminium powder. The quality <strong>of</strong> the fingermarks nevertheless<br />

decreased as the immersion times increased, and as the water temperature rose<br />

from 5°C <strong>to</strong> 20°C. Finally, no DNA pr<strong>of</strong>ile could be obtained regardless <strong>of</strong> the tested<br />

conditions.<br />

Kerr et al. investigated the effect <strong>of</strong> water immersion on the efficiency <strong>of</strong> the<br />

commonly used fingermark detection techniques (208). For this study, non-enriched<br />

fingermarks were left on glass before being immersed in different water baths (i.e.,<br />

cold, 50°C, or soapy) for varying times (i.e., five seconds and one minute). It should<br />

be noted that the fingermark aging time (i.e., the time left between the deposition <strong>of</strong><br />

the marks and their wetting) has not been specified by the authors. We assume that<br />

the freshly deposited marks were immediately rinsed after their deposition. Nine<br />

fingermark detection techniques were compared (i.e., aluminium and gold powders,<br />

small particle reagent – SPR, eosin blue, erythrosine B, physical developer - PD,<br />

gentian violet, sudan black, and cyanoacrylate fuming) according <strong>to</strong> their ability <strong>to</strong><br />

reproduce ridge details. As a conclusion, the authors recommend <strong>to</strong> first air dry<br />

wetted glass samples vertically, before processing them with either aluminium or gold<br />

powder. If vertical drying is impossible, they recommend using SPR while the<br />

samples are still wet. It should be noted that cyanoacrylate fuming gave poor results<br />

on the dried samples, which is in contradiction with the above-described study (209).<br />

246

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