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Examination of Firearms Review: 2007 to 2010 - Interpol

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In the particular field <strong>of</strong> Handwriting, we note the emergence <strong>of</strong> some s<strong>of</strong>tware<br />

dedicated <strong>to</strong> help the examiners in his writing report. One <strong>of</strong> the most distributed at this<br />

time is WriteOn 2.<br />

3.2 The composition <strong>of</strong> inks: review <strong>of</strong> the analytical methods<br />

The expert in documents is brought <strong>to</strong> examine, in the majority <strong>of</strong> the cases, three major<br />

classes <strong>of</strong> ink:<br />

• Inks <strong>of</strong> pen ([66] <strong>to</strong> [102]).<br />

• Toner ([103] <strong>to</strong> [111]).<br />

• Ink <strong>of</strong> inkjet printer ([112] <strong>to</strong> [119]).<br />

Whilst there are many publications on the forensic analysis <strong>of</strong> inks <strong>of</strong> pen inks (37<br />

papers, posters or presentations found), fewer have been written on the analysis <strong>of</strong><br />

inkjet inks (8 papers, posters or presentations found) and <strong>to</strong>ner inks (7 papers, posters<br />

or presentations found). However, it seems that <strong>to</strong>day, it is this kind <strong>of</strong> inks that are<br />

regularly asked <strong>to</strong> be analysed by magistrates or investiga<strong>to</strong>rs more than pen inks.<br />

To allow further analysis, the document examiners are <strong>of</strong>ten compelled <strong>to</strong> preserve the<br />

sample he has <strong>to</strong> analyse.<br />

Today, Raman spectroscopy ([72], [93], [108], [109], [122], [125], [128], [146], [148]),<br />

remains the reference process but we can see some emergent techniques able <strong>to</strong> make<br />

non destructive analysis applicable <strong>to</strong> inks.<br />

As said below, it is extremely hard <strong>to</strong> give an exhaustive list <strong>of</strong> analytical techniques that<br />

can be used for ink analysis. Listed below are the references appearing in the review<br />

grouped according <strong>to</strong> technique, the relative popularities <strong>of</strong> which are likely <strong>to</strong> be due <strong>to</strong><br />

their availability in the university or lab undertaking the tests.<br />

3.2.1 Liquid Chroma<strong>to</strong>graphy:<br />

• TLC (Thin Layer Chroma<strong>to</strong>graphy) [74], [78], [80], [81], [85], [95], [97], [98], [119],<br />

[129], [140]<br />

• HPTLC (High Performance Thin Layer Chroma<strong>to</strong>graphy) [80], [81], [91]<br />

• HPLC (High Performance Liquid Chroma<strong>to</strong>graphy) [91], [104], [119], [134], [140],<br />

[141]<br />

3.3.2 Spectroscopy:<br />

• FTIR spectroscopy (Fourier Transform Infra Red) [76], [85], [89], [108], [119],<br />

[126], [127], [129], [144], [147], [156]<br />

• µFTIR [104], [128]<br />

• Raman spectroscopy [72], [93], [108], [109], [122], [125], [128], [146], [148]<br />

352

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