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Examination of Firearms Review: 2007 to 2010 - Interpol

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the contaminated fingertips on an aluminium-coated microscope slide. The imaging<br />

was performed by comparing the spectra obtained from the scanned fingermarks<br />

with the reference spectra <strong>of</strong> the targeted explosives, using Pearson's crosscorrelation.<br />

In this preliminary study, it was possible <strong>to</strong> locate and identify explosives<br />

from contaminated fingermarks. The consideration <strong>of</strong> realistic surfaces and the effect<br />

<strong>of</strong> fingermark detection techniques (such as cyanoacrylate) on the subsequent<br />

identification <strong>of</strong> explosives have <strong>to</strong> be investigated in further experiments.<br />

Attenuated <strong>to</strong>tal reflection – Fourier transform infrared (ATR-FTIR) was used <strong>to</strong><br />

locate and identify explosive particles in latent fingermarks (321). Fingertips were first<br />

contaminated with explosives (i.e., TNT, trinitrobenzene, or ammonium nitrate) by<br />

<strong>to</strong>uching a glass slide on which explosive powder was spread. Excessive powder<br />

was brushed away, until no more powder was visible by the naked eye, and the<br />

fingers were pressed on stainless steel (this substrate is transparent in the infrared<br />

region) as well as on a more realistic substrate (i.e., metal lid from a jar). The<br />

procedure consisted in locating (explosive) particles (as small as 20 µm) and<br />

comparing their FTIR spectrum with an infrared spectral library. It should be noted<br />

that sweat residue could interfere with the resulting FTIR spectrum. Similarly <strong>to</strong> this<br />

work, the use <strong>of</strong> RDX-containing solution were used <strong>to</strong> contaminate fingertips before<br />

they were pressed on aluminium coated slides, and further analyzed using ordinary<br />

FTIR (322).<br />

The use <strong>of</strong> a reflective ultraviolet imaging system (RUVIS) is reported <strong>to</strong> locate<br />

fingermarks on post-blast material (324). The author stated that people generally look<br />

for fingermarks on tape and batteries (used <strong>to</strong> set up the explosive device), but not<br />

necessarily on the device itself, assuming that the heat <strong>of</strong> explosion had a strong<br />

detrimental effect on fingermarks. In this experiment, explosive devices were<br />

designed using C4, nitromethane and gasoline, a bag and plastic bottles. Following<br />

the blast in open air, pieces <strong>of</strong> the explosive device were collected and observed<br />

using a RUVIS. A single fingermark – further identified <strong>to</strong> the designer <strong>of</strong> the<br />

explosive devices - was found on a non-porous surface (a remaining piece <strong>of</strong> a<br />

plastic bottle). The advantage <strong>of</strong> RUVIS is that the resulting contrast is not dependent<br />

on the colour <strong>of</strong> the substrate. Moreover, this technique can be used on-site if<br />

explosive devices have <strong>to</strong> be destroyed in place, without a subsequent labora<strong>to</strong>ry<br />

examination capability (e.g., Irak).<br />

2.2.15 Detection and lifting <strong>of</strong> fingermarks on skin<br />

The detection <strong>of</strong> marks on skin has been investigated through different<br />

environmental parameters (325) and by comparing several fingermark<br />

detection techniques (237, 325). Swedish Black, Magnetic Jet Black<br />

powder, or RTX spraying are recommended for use in this context (237).<br />

The lifting <strong>of</strong> unprocessed marks from skin should be done by using<br />

Transparent Instant lifter (237), whereas powdered marks should be lifted<br />

by using silicone casting material (325) or white gelatin lifter (326).<br />

Four fingerprint powders (i.e., Magnetic Jet Black, Magnetic Silver, Silver Special,<br />

and Swedish Black) and two chemical methods (i.e., cyanoacrylate fuming and<br />

ruthenium tetroxyde - RTX) were compared <strong>to</strong> assess their ability <strong>to</strong> detect<br />

fingermarks on skin (237). The marks were either processed directly on skin, or lifted<br />

274

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