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Examination of Firearms Review: 2007 to 2010 - Interpol

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the nature <strong>of</strong> the garment in question being drawn. The need for caution in its<br />

application and an appreciation <strong>of</strong> the fac<strong>to</strong>rs affecting the technology are<br />

emphasised in intelligence led casework.<br />

7. Analysis<br />

Due <strong>to</strong> the prevailing economic climate, now more than ever purchase <strong>of</strong> new<br />

instrumentation and adoption <strong>of</strong> new methods <strong>of</strong> analysis are dependent upon<br />

demonstrable improvements in time, resources and/ or increased<br />

discrimination before uptake is justified in terms <strong>of</strong> cost. Nevertheless, over<br />

the past three years research in this area has continued.<br />

Biermann [34] carried out a study <strong>to</strong> determine the variation in blue and red<br />

cot<strong>to</strong>n fibres using light and fluorescence microscopy, UV/Vis<br />

microspectropho<strong>to</strong>metry with particular attention being paid <strong>to</strong> the recurrence<br />

<strong>of</strong> certain spectral patterns. The importance <strong>of</strong> spectral information in the UV<br />

range is re-emphasised, as is the importance <strong>of</strong> colour in the forensic<br />

comparison <strong>of</strong> cot<strong>to</strong>n fibres. The author demonstrated that the combination <strong>of</strong><br />

tests employed can give a high power <strong>of</strong> discrimination, (DP c. 0.98)<br />

enhancing the evidential value <strong>of</strong> red and blue cot<strong>to</strong>n fibres in fibre transfer<br />

cases.<br />

Similar results were obtained in a study <strong>of</strong> non-denim blue cot<strong>to</strong>n fibres by<br />

Palmer et al [35] <strong>to</strong> determine the degree <strong>of</strong> discrimination obtained between<br />

non-denim blue cot<strong>to</strong>n fibres using visible-UV range MSP alone. The<br />

discriminating power <strong>of</strong> visible range MSP was calculated <strong>to</strong> be 0.89 for 'midblue'<br />

garments and 0.87 for 'dark blue' garments. Extending MSP in<strong>to</strong> the UV<br />

range increased discrimination by 7%, giving a discriminating power <strong>of</strong> 0.96<br />

for both mid and dark blue cot<strong>to</strong>n fibres, which was similar <strong>to</strong> that reported by<br />

Biermann [34]. The implications <strong>of</strong> this study for casework are discussed and<br />

a revised analytical pathway for the comparison <strong>of</strong> this fibre type/colour<br />

combination using MSP as a primary screening <strong>to</strong>ol is proposed.<br />

Research in<strong>to</strong> the application <strong>of</strong> Raman spectroscopy <strong>to</strong> the forensic<br />

examination <strong>of</strong> textile fibres has continued since the last review, with<br />

members <strong>of</strong> the European Fibre Group being the most active in this area [36-<br />

38]. Despite this research, adoption <strong>of</strong> this technique in<strong>to</strong> the majority <strong>of</strong><br />

operational labora<strong>to</strong>ries is still poor, possibly because it has still <strong>to</strong><br />

demonstrate substantial advantages over the combination <strong>of</strong> existing<br />

techniques and in many respects has been shown <strong>to</strong> be complimentary;<br />

Massonett and Buzzini [36] compared Raman spectroscopy against<br />

microscopy, UV-Vis MSP and TLC in the discrimination <strong>of</strong> acrylic, cot<strong>to</strong>n and<br />

wool fibres. The results <strong>of</strong> their study showed that in the majority <strong>of</strong> cases<br />

microscopy and UV Vis MSP provided the greatest discrimination and that the<br />

optimal analytical sequence varies with the fibre type/ colour combination<br />

(according <strong>to</strong> the discrimination power).<br />

Coyle et al [37] investigated the use <strong>of</strong> Raman spectroscopy in the subclassification<br />

<strong>of</strong> cellulosic fibres. Whilst it was possible <strong>to</strong> distinguish the<br />

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