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Examination of Firearms Review: 2007 to 2010 - Interpol

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26. Infusion Mass Spectrometry<br />

A final mass spectrometry technique investigated was infusion mass<br />

spectrometry.[331] This technique involves simple hydrolysis and extraction as a<br />

sample preparation technique that does not involve a derivatization step,<br />

followed by direct introduction <strong>to</strong> the MS. In this artwork application, drying oils,<br />

used as binding media and varnishes, were characterized.<br />

27. Imaging (Tomography)<br />

Optical Coherence Tomography (OCT) is a technique for obtaining sub-surface<br />

images <strong>of</strong> translucent or opaque materials at a resolution equivalent <strong>to</strong> a lowpower<br />

microscope. It is similar <strong>to</strong> ultrasound and can penetrate up <strong>to</strong> several<br />

millimeters <strong>to</strong> provide cross-sectional images. Targowski et al. provide an<br />

overview <strong>of</strong> the technique and describes an instrument especially designed for<br />

art diagnostics.[332] Liang and coauthors report progress on optimizing and<br />

designing an OCT instrument for in situ use in museums.[333] Adler et al.<br />

discuss the technique further and claim that it is well suited for analyzing artwork<br />

where a surface layer obscures details <strong>of</strong> interest.[334] In two separate papers,<br />

La<strong>to</strong>ur and coauthors use the technique <strong>to</strong> obtain pigment information and<br />

demonstrate how the technique can be applied <strong>to</strong> wood varnishes.[335;336]<br />

Computed Tomography (CT), another imaging technique traditionally used in<br />

medical diagnostics, was shown <strong>to</strong> be applicable <strong>to</strong> artwork analysis by providing<br />

morphological and physical information on the inner structure <strong>of</strong> artworks.[337]<br />

Its use with radiography was discussed.<br />

28. Determination <strong>of</strong> Materials and Artistic Techniques<br />

A variety <strong>of</strong> the techniques described thus far were used <strong>to</strong> evaluate the<br />

materials and/or techniques <strong>of</strong> various artists, collections, or geographic<br />

locations.[338-344] Furthermore, a variety <strong>of</strong> substrates were analyzed,<br />

including alabaster[345], archaeological pastes[346], drawings and illuminated<br />

manuscripts [347;348], pottery or s<strong>to</strong>neware[349-352], religious items[353;354],<br />

rocks[355], tiles [356], and walls[357-364].<br />

29. Conservation, Degradation and Forgery Detection<br />

A range <strong>of</strong> the aforementioned techniques were also used in various<br />

combinations in order <strong>to</strong> study degradation/aging processes in painting<br />

materials.[297;365-369] Since this has little practical application for forensic<br />

paint analyses, the appropriate references are merely listed. For a thorough<br />

discussion on the various techniques available for materials conservation,<br />

including paints, consult Analytical Techniques in Materials Conservation.[370]<br />

Further, Applied Physics A published a special issue entitled “Science and<br />

Technology <strong>of</strong> Cultural Heritage Materials: Art Conservation and Res<strong>to</strong>ration,”<br />

Volume 92, number 1, July 2008 that may be <strong>of</strong> interest.<br />

150

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