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Examination of Firearms Review: 2007 to 2010 - Interpol

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found between the fingermark donation status and the DNA shedder status. The level<br />

<strong>of</strong> ridge details on a fingermark is consequently not correlated with the subsequent<br />

DNA pr<strong>of</strong>iling tests.<br />

2.2.14 CBRNE-related evidence (Chemical, Biological, Radiological, Nuclear, and<br />

Explosive)<br />

Research on CBRNE-contaminated evidence has seriously increased<br />

during these last three years. Most <strong>of</strong> the researches were dedicated <strong>to</strong><br />

the effect <strong>of</strong> the contaminant, and <strong>of</strong> the decontamination procedures, on<br />

the subsequent detection <strong>of</strong> latent fingermarks. In the case <strong>of</strong> chemical<br />

contamination, if items were contaminated with acid chemical vapours, the<br />

use <strong>of</strong> volatile organic bases could help in improving the cyanoacrylate<br />

fuming process (314). In the case <strong>of</strong> biological contamination, the use <strong>of</strong><br />

formaldehyde vapours during the decontamination procedure could be<br />

detrimental for some amino-acid reagents (315). No adverse effects were<br />

however observed if irradiation is used <strong>to</strong> decontaminate the items (316).<br />

Finally, bacterial activity showed almost no detrimental effect on the latent<br />

and blood fingermarks left on porous and non-porous substrates<br />

(variations were however obtained for adhesives) (317). In the case <strong>of</strong><br />

irradiation, fingermarks could still be detected on glass and aluminium<br />

after high doses <strong>of</strong> irradiation (even if glass could become optically<br />

degraded) (318). However, detrimental effects induced <strong>to</strong> the substrate<br />

itself (especially for plastic and paper items) could hamper the fingermark<br />

detection processing. Nevertheless, up <strong>to</strong> 100 kGy, it has been shown that<br />

the processing <strong>of</strong> latent fingermarks using common detection techniques<br />

is still possible. In another study, some chemical and physical<br />

decontamination procedures were shown <strong>to</strong> be highly detrimental on the<br />

subsequent recovery <strong>of</strong> latent fingermarks on documents (319). In such<br />

cases, it is either recommended not <strong>to</strong> decontaminate the documents<br />

(even after the recovery <strong>of</strong> fingermarks), or <strong>to</strong> proceed <strong>to</strong> the<br />

decontamination after the recovery <strong>of</strong> fingermarks. Explosive<br />

contaminations could be located and identified on latent fingermarks using<br />

analytical <strong>to</strong>ols such as Raman chemical imaging (320), or Fourier<br />

transform infrared spectroscopy (321, 322). Fingermarks on post-blast<br />

devices could still be detected using either cyanoacrylate fuming (323), or<br />

reflected UV imaging (RUVIS) (324).<br />

Chemical contamination<br />

The exposure <strong>of</strong> evidence <strong>to</strong> hydrochloric acid (HCl) vapours or chlorine (from a<br />

chemical weapon or from methamphetamine labora<strong>to</strong>ries) could result in an<br />

acidification <strong>of</strong> the secretion residue, causing detrimental effects on some fingermark<br />

detection mechanisms (such as cyanoacrylate polymerization or ninhydrin).<br />

McDonald et al. assessed the efficiency <strong>of</strong> a basic pretreatment (using volatile bases)<br />

prior <strong>to</strong> the application <strong>of</strong> detection techniques (314). Fingermarks on glass slides<br />

and standard pho<strong>to</strong>copy paper were considered. They observed that exposure <strong>to</strong><br />

high level <strong>of</strong> acid vapors could indeed lead <strong>to</strong> an inhibition <strong>of</strong> the cyanoacrylate<br />

polymerization and <strong>to</strong> a modification <strong>of</strong> the ninhydrin reaction mechanism (leading <strong>to</strong><br />

light pink-red marks instead <strong>of</strong> dark purple). Exposure <strong>of</strong> the evidence <strong>to</strong><br />

270

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