36. Cao, Y.W.; Banin, U. J. Am. Chem. Soc. 2000, 122, 9692.37. Kershaw, S.V.; Burt, M.; Harrison, M.; Rogach, A.; Weller, H.; Eychmuller, A.Appl. Phys. Lett. 1999, 75, 1694.38. Harrison, M.T.; Kershaw, S.V.; Rogach, A.L.; Kornowski, A.; Eychmuller, A.;Weller, H. Adv. Mater 2000, 12, 123.39. Peng, X.G.; Manna, L.; Yang, W.D.; Wickham, J.; Scher, E.; Kadavanich, A.;Alivisatos, A.P. Nature 2000, 404, 59.40. Manna, L.; Scher, E.C.; Alivisatos, A.P. J. Am. Chem. Soc. 2000, 122, 12,700.41. Peng, Z.A.; Peng, X. J. Am. Chem. Soc. 2001, 123, 1389.42. Hu, J.; Li, L.S.; Yang, W.; Manna, L.; Wang, L.W.; Alivisatos, A.P. Science2001, 292, 2060.43. Vahala, K.J.; Sercel, P.C. Phys. Rev. Lett. 1990, 65, 239.44. Norris, D.J.; Sacra, A.; Murray, C.B.; Bawendi, M.G. Phys. Rev. Lett. 1994,72, 2612.45. Norris, D.J.; Bawendi, M.G. Phys. Rev. B 1996, 53, 16,338.46. Bertram, D.; Micic, O.I.; Nozik, A.J. Phys. Rev. B 1998, 57, R4265.47. Banin, U.; Lee, J.C.; Guzelian, A.A.; Kadavanich, A.V.; Alivisatos, A.P.; Jaskolski,W.; Bryant, G.W.; Efros, Al.L.; Rosen, M. J. Chem. Phys. 1998, 109,2306.48. Banin, U.; Lee, J.C.; Guzelian, A.A.; Kadavanich, A.V.; Alivisatos, A.P. SuperlatticesMicrostruct. 1997, 22, 559.49. Ekimov, A.I.; Hache, F.; Schanne-Klein, M.C.; Ricard, D.; Flytzanis, C.;Kudryavtsev, I.A.; Yazeva, T.V.; Rodina, A.V.; Efros, A.L. J. Opt. Soc. Am. B1993, 10, 100.50. Fu, H.; Wang, L.W.; Zunger, A. Appl. Phys. Lett. 1997, 71, 3433.51. Williamson, A.J.; Zunger, A. Phys. Rev. B 2000, 61, 1978.52. Porath, D.; Levi, Y.; Tarabiah, M.; Millo, O. Phys. Rev. B 1997, 56, 9829.53. Porath, D.; Millo, O. J. Appl. Phys. 1997, 85, 2241.54. Kastner, M.A. Phys. Today, 1993, 46, 24.55. Kouwenhoven, L. Science 1997, 257, 1896; Service, R.F. Science 1997, 275, 303.56. Amman, M.; Mullen, K.; Ben-Jacob, E. J. Appl. Phys. 1989, 65, 339.57. Hanna, A.E.; Tinkham, M. Phys. Rev. B 1991, 44, 5919.58. Klein, D.L.; Roth, R.; Lim, A.K.L.; Alivisatos, A.P.; McEuen, P.L. Nature1997, 389, 699; Klein, D.L., et al., Appl. Phys. Lett. 1996, 68, 2574.59. Alperson, B.; Cohen, S.; Rubinstein, I.; Hodes, G. Phys. Rev. B 1995, 52,17,017.60. Bar-Sadeh, E.; Goldstein, Y.; Zhang, C.; Deng, H.; Abeles, B.; Millo, O. Phys.Rev. B 1994, 50, 8961.61. Bar-Sadeh, et al. J. Vac. Sci. Technol. B 1995, 13, 1084.62. Dubois, J.G.A.; Gerritsen, J.W.; Shafranjuk, S.E.; Boon, E.J.G.; Schmid, G.;van Kempen, H. Europhys. Lett. 1995, 33, 279.63. Schoenenberg, C.; van Houten, H.; Donkerlost, H.C. Europhys. Lett. 1992, 20,249.64. Bakkers, E.P.A.M.; Vanmaekelbergh, D. Phys. Rev. B 2000, 62, 7743.65. Katz, D.; Millo, O.; Kan, S.H.; Banin, U. Appl. Phys. Lett. 2001, 79, 117.<strong>Copyright</strong> <strong>2004</strong> <strong>by</strong> <strong>Marcel</strong> <strong>Dekker</strong>, <strong>Inc</strong>. <strong>All</strong> <strong>Rights</strong> <strong>Reserved</strong>.
66. Su, B.; Goldman, V.J.; Cunningham, J.E. Phys. Rev. B 1992, 46, 7664.67. Vdovin, E.E., et al. Science 2000, 290, 122.68. Crommie, M.F.; Lutz, C.P.; Eigler, D.M. Science 1993, 262, 218.69. Venema, L.C., et al. Science 1999, 283, 52.70. Pan, S.H.; Hudson, E.W.; Lang, K.M.; Eisaki, H.; Uchida, S.; Davis, J.C.Nature 2000, 403, 746.71. Grandidier, B., et al. Phys. Rev. Lett. 2000, 85, 1068.72. Millo, O.; Katz, D.; Cao, Y-W.; Banin, U. Phys. Rev. Lett. 2001, 86, 5751.73. Wolf, E.L. Principles of Electron Tunneling Spectroscopy; Oxford UniversityPress: Oxford, 1989.74. Wiesendanger, R. Scanning Probe Microscopy and Spectroscopy; CambridgeUniversity Press: London, 1994.75. Colvin, V.L.; Goldstein, A.N.; Alivisatos, A.P. J. Am. Chem. Soc. 1992, 114,5221.76. Efros, A.L.; Rosen, M. Annu. Rev. Phys. Chem. 2000, 30, 475.77. Rabani, E.; Hetenyi, B.; Berne, B.J.; Brus, L.E. J. Chem. Phys. 1999, 110, 5355.78. Franceschetti, A.; Fu, H.; Wang, L.W.; Zunger, A. Phys. Rev. B 1999, 60, 1819.79. Zunger, A. MRS Bull. 1998, 23, 35.80. Franceschetti, A.; Zunger, A. Phys. Rev. B 2000, 62, 2614.81. Franceschetti, A.; Zunger, A. Appl. Phys. Lett. 2000, 76, 1731.82. Niquet, Y.M.; Delerue, C.; Lannoo, M.; <strong>All</strong>an, G. Phys. Rev. B 2001, 64, 3305.83. Lifshitz, E.; Glozman, A.; Litvin, I.D.; Porteanu, H. J. Phys. Chem. B 2000,104, 10,449.84. Millo, O.; Katz, D.; Cao, Y.W.; Banin, U. J. Low Temp. Phys. 2000, 118, 365.85. Alperson, B.; Hodes, G.; Rubinstein, I.; Porath, D.; Millo, O. Appl. Phys. Lett.1999, 75, 1751.86. Terrill, R.H.; Postlethwaite, T.A.; Chen, C-H.; Poon, C-D.; Terzis, A.; Chen,A.; Hutchison, J.E.; Clark, M.R.; Wignall, G.; Londono, J.D.; Superfine, R.;Falvo, M.; Johnson, C.S.; Samulski, E.T.; Murray, R.W. J. Am. Chem. Soc.1995, 117, 12,537.87. Schlamp, M.C.; Peng, X.G.; Alivisatos, A.P. J. Appl. Phys. 1997, 82, 5837.88. Mattoussi, H.; Radzilowski, L.H.; Dabbousi, B.O.; Thomas, E.L.; Bawendi,M.G.; Rubner, M.F. J. Appl. Phys. 1998, 83, 7965.89. Kuno, M.; Lee, J.K.; Dabbousi, B.O.; Mikulec, F.V.; Bawendi, M.G. J. Chem.Phys. 1997, 106, 9869.90. Schooss, D., et al. Phys. Rev. B 1994, 49, 17,072.<strong>Copyright</strong> <strong>2004</strong> <strong>by</strong> <strong>Marcel</strong> <strong>Dekker</strong>, <strong>Inc</strong>. <strong>All</strong> <strong>Rights</strong> <strong>Reserved</strong>.
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Copyright 2004 by Marcel Dekker, In
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Copyright 2004 by Marcel Dekker, In
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Copyright 2004 by Marcel Dekker, In
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This book covers several topics of
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esult, some exciting topics were no
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3. Fine Structure and Polarization
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9. III-V Quantum Dots and Quantum D
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ContributorsUri BaninThe Hebrew Uni
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1‘‘Soft’’ Chemical Synthesi
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structure of energy states leads to
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growth can proceed by Ostwald ripen
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Figure 3 Transmission electron micr
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Figure 4 Temporal evolution of the
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No. 26, are f85% (Fig. 6) [21]. Alt
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tion spectra and broad PL spectra.
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ing surface-to-volume ratio with di
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Figure 8 Photoluminescence spectra
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lattice mismatch. Such a large latt
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match between InAs and ZnS of f11%.
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successfully repeated for up to thr
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Under a different growth regime, on
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Figure 14 Atomic model of the CdSe
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‘‘Teardrop-shaped’’ particl
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Figure 17 High-resolution TEMs of C
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allows isolation of tetrapods in f8
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ligand concentrations yield a reduc
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een determined and quantitatively c
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tion volumes were also shown to be
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synthesis temperatures of z400jC ar
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Figure 23 (a) Photoluminescence spe
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levels (fV1 Mn per NQD). Despite in
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Figure 25 X-ray diffraction pattern
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Figure 27 Transmission electron mic
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An additional factor that strongly
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Figure 30 (a,b) Schematics illustra
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Slow, controlled precipitation of h
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Figure 34 Schematic illustrating th
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Figure 36 Transmission electron mic
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achieving biological compatibility
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47. Yu H.; Gibbons P.C.; Kelton K.F
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2Electronic Structure inSemiconduct
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Figure 2 (a) Simple model of a nano
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electron and hole to be treated as
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independently, Eq. (13) is commonly
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a better description of the bulk ba
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investigated. For optical experimen
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Figure 4 (a) Absorption (solid line
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Figure 6 Normalized PLE scans for s
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Figure 8 A simplistic model for des
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Figure 10 Theoretically predicted p
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Figure 12 Schematics depicting the
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Figure 14 Calculated band-edge exci
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Figure 15 Absorption (solid line) a
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Figure 18 (a) Calculated band-edge
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IV.BEYOND CdSeA. Indium Arsenide Na
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the six-band Luttinger Hamiltonian.
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11. Norris, D.J.; Efros, Al.L.; Ros
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69. Gaponenko, S.V.; Woggon, U.; Sa
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formation of a long-lived dark exci
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where the constant A is determined
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In crystals for which the function
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The respective wave functions areC
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passive, as was shown in Ref. 12. T
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square of the matrix element of the
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where e F = e F ieV and e F F = e x
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see that for all nanocrystal shapes
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optical recombination of the excito
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B. Recombination of the Dark Excito
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where x = cos h and f = l B g e H/3
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The theory of the polarization memo
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Figure 7 The size dependence of the
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state would have an infinite lifeti
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crystal axis [see Eq. (40)]. As a r
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time of the exciton momentum relaxa
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One must also account for the influ
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observed in one of the first studie
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REFERENCES1. Bawendi, M.G.; Wilson,
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4Intraband Spectroscopyand Dynamics
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The solid line in Fig. 1 shows the
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Figure 2 FTIR spectra of n-type CdS
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of the center frequency. The experi
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limit given by radiative relaxation
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from a long lifetime due to the pho
- Page 171 and 172:
are two natural approaches to study
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32. Inoshita, T.; Sakaki, H. Physic
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continuous spectral tunability over
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function and envelope function mome
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ottleneck’’ [14,28]. Further re
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in NQDs is dominated by nonphonon e
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Figure 4 Dynamics of the IR postpum
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Figure 5 (a) Time-resolved PL spect
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Figure 6 (a) The time delay of the
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and due to Auger-type e-h interacti
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Figure 9 Dynamics of the 1S bleachi
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significantly greater than the fast
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Figure 11 (a) Pump-intensity-depend
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NQD size. For small NQD sizes (R =
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Figure 14 Nonlinear absorption/gain
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sorption change associated with a s
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where n h em is the hole ‘‘emit
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ultrafast (subpicosecond to picosec
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Figure 18 Schematic of transitions
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Figure 19 Dynamics of pump-induced
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where n i (i=1, 2 . . . , N ) is th
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Figure 21 (a) Two-e-h-pair (biexcit
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the volume fraction (filling factor
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intensity dependence of this peak (
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Copyright 2004 by Marcel Dekker, In
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can contribute to the saturation of
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Copyright 2004 by Marcel Dekker, In
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coupling between ‘‘volume’’
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numerous discussions on the photoph
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53. Kang, K.; Kepner, A.; Gaponenko
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the ‘‘on-off ’’ emission in
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parallel form of data acquisition i
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Figure 3 (a) Spectral time trace of
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transition energies. In fact, these
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distribution (dark line) does not d
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exposure to only room light. In our
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statistics for the off times are in
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230Shimizu and BawendiCopyright 200
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Figure 10 (a) Time trace of a CdSe(
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and excited QD core states to fluct
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arrows indicate the on-time truncat
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W. K. Woo and V. C. Sundar for assi
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size allows the electron affinity a
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II.THEORY OF ELECTRON TRANSFER BETW
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For the specific case of charge tra
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dominates, the mobility is often fi
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where the constant A and the temper
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components of modulation which are
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nanocrystals [41], understanding ph
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and ionization potential through tw
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quantum dots. Furthermore, because
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For many applications, a host mater
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form blends with morphologies that
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Figure 11 Photoluminescence efficie
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Figure 12 (a) Room-temperature PIA
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discussed briefly in Section IV. Ch
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dithiolates to thiol-terminated DNA
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Films of passivated CdSe nanocrysta
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Figure 16 Photocurrent action spect
- Page 289 and 290: decay with stretched exponential ki
- Page 291 and 292: siderably larger than might be esti
- Page 293 and 294: dispersing CdSe nanocrystal chromop
- Page 295 and 296: memory and charge storage effects [
- Page 297 and 298: all) of the optically excited elect
- Page 299 and 300: composites of nanocrystals and conj
- Page 301 and 302: 55. Asbury, J.B.; Hao, E.C.; Wang,
- Page 303 and 304: 108. Morgan, N.Y.; Leatherdale, C.A
- Page 305 and 306: The approaches to fabrication of se
- Page 307 and 308: Figure 1 Experimental realization o
- Page 309 and 310: Due to this voltage division, the m
- Page 311 and 312: Figure 3 Simulated tunneling spectr
- Page 313 and 314: electron charging. In both positive
- Page 315 and 316: Figure 5 shows the typical features
- Page 317 and 318: Figure 7 Map of levels for InAs nan
- Page 319 and 320: Figure 8 Scanning electron microsco
- Page 321 and 322: D CB = 0.31 eV is thus obtained. On
- Page 323 and 324: Figure 11 Correlation of optical an
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- Page 327 and 328: charging indicated that the tunneli
- Page 329 and 330: capacitance values were also kept t
- Page 331 and 332: could not be detected in the QD/DT/
- Page 333 and 334: Figure 18 Tunneling conductanceF sp
- Page 335 and 336: data in the inset of Fig. 19 repres
- Page 337 and 338: corresponding to the s-like wave fu
- Page 339: 7. Grabert, H.; Devoret, M.H., Eds.
- Page 343 and 344: dimensional confinement are created
- Page 345 and 346: Figure 1 Transmission electron micr
- Page 347 and 348: The room-temperature absorption and
- Page 349 and 350: narrower in samples with larger mea
- Page 351 and 352: GaInP 2 QDs from a plot of the squa
- Page 353 and 354: crystal, indicating lattice-matched
- Page 355 and 356: Figure 5 Evolution of Stranski-Kras
- Page 357 and 358: Figure 7 Photoluminescence spectra
- Page 359 and 360: Figure 8 Photoluminescence spectra
- Page 361 and 362: C. Efficient Anti-Stokes Photolumin
- Page 363 and 364: Because HF treatment has been shown
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- Page 367 and 368: intensity of the PL when it is on a
- Page 369 and 370: eV stems from recombining carriers
- Page 371 and 372: Figure 16 Model to explain two-colo
- Page 373 and 374: although this term is not rigorousl
- Page 375 and 376: 10 ps (about an order of magnitude
- Page 377 and 378: electron relaxation is inhibited an
- Page 379 and 380: Figure 18 Transmission electron mic
- Page 381 and 382: QDs, the nature of the QD capping s
- Page 383 and 384: QD solution. For an interdot distan
- Page 385 and 386: emission spectra of the two individ
- Page 387 and 388: Figure 23 Change of the PL intensit
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Figure 25Impact ionization in QDs.m
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prevent electron-hole recombination
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36. Miller, R.D.J.; McLendon, G.; N
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91. Vurgaftman, I.; Singh, J. Appl.
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139. Mićić, O.I.; Ahrenkiel, S.P.
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10Synthesis and Fabrication of Meta
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Figure 2 (A-C) Progression of HR-TE
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Figure 3 Schematic for gold nanocry
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Nanocrystal growth can occur by two
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on the other hand, provide an ensem
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Figure 6 (a) SAXS patterns for disp
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Figure 8 The gold nanocrystal film
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of the stabilizing ligand, and the
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successfully modeled the 2D island
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2. Steric Stabilization and a Soft
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are fully extended. Moving away fro
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Figure 11 High-resolution SEM image
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Figure 13 (A) Transmission electron
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function of the density of localize
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Figure 15 High-resolution SEM image
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thiol-capped nanocrystals [2]. The
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41. Ackerson, B.J. Nature 1993, 365
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with the effect of the particle com
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Figure 1a shows the surface plasmon
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Figure 2 (a) Ultraviolet-visible ab
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agents [34]. The short-wavelength b
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Figure 4 (a) Plot of the plasmon ab
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the framework of traditional Mie’
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show that effects due to the surrou
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is located at the position of the g
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Copyright 2004 by Marcel Dekker, In
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Figure 8 Ultraviolet-visible absorp
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laser pulses while being mixed in t
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Figure 10 shows HR-TEM images of go
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Figure 11 Transmission electron mic
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final irradiation product. At the s
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following the laser excitation appe
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36. Papavassiliou, G.C. Prog. Solid
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particles to expand. Because the he
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was frequency doubled in a 1-mm B-
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Figure 2 Frequency of the acoustic
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Figure 3 Change in radius (DR/R) ve
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In this model, the electrons couple
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Figure 5 Transient bleach data for
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Figure 7 (a) Transient bleach data
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that the particles with >80% Au hav
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3. Del Fatti, N.; Valle´e, F.; Fly