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Scientific and Technical Aerospace Reports Volume 38 July 28, 2000

Scientific and Technical Aerospace Reports Volume 38 July 28, 2000

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<strong>2000</strong>0064533 Austin State Univ., Dept. of Geology, Nacogdoches, TX USA<br />

X-Ray Diffraction Verification of AVIRIS Clay Mineral Identification, Summitville Ares, Soutwestern Colorado<br />

Duncan, W. S., Austin State Univ., USA; Ledger, E. B., Austin State Univ., USA; Whitehead, V. S., Austin State Univ., USA;<br />

Summaries of the Seventh JPL Airborne Earth Science Workshop January 12-16, 1998; Dec. 19, 1998; <strong>Volume</strong> 1, pp. 85-95; In<br />

English; See also <strong>2000</strong>0064520; No Copyright; Avail: CASI; A03, Hardcopy; A04, Microfiche<br />

The eastern San Juan Mountains of southwestern Colorado are the site of mid- <strong>and</strong> late-Tertiary volcanic activity. The volcanic<br />

activity had two effects on the state of Colorado. Some of the eruptions were extremely large, <strong>and</strong> magmas formed thick<br />

geologic rock units that contributed to the scenic nature of the area. The other effect was that magmas brought precious metals<br />

to the earth’s near surface that could be exploited by mining. In the last ten or twenty million years after most of the activity ended,<br />

the volcanic bedrock underwent extensive erosion due to the high relief, <strong>and</strong> chemical weathering of the volcanic rock produced<br />

clay minerals in the soil. The original mineralization also emplaced sulfide minerals (mostly non-ore minerals called gangue) that<br />

reacted to form very acidic conditions due to sulfide-to-sulfate reactions. The clay minerals that form in such an environment<br />

depend on time (duration) of chemical reactions forming the clays, the parent volcanic rock composition <strong>and</strong> texture, <strong>and</strong> the present<br />

weathering conditions, including pH. Clay minerals are natural aluminosilicates that form at the earth’s surface in response<br />

to chemical alteration of higher temperature minerals such as feldspars <strong>and</strong> mica. Feldspars <strong>and</strong> mica are K, Na, <strong>and</strong> Ca aluminosilicates<br />

that can form from magmas. They do not form at ambient temperatures, but rather alter to clay. Analysis of clay minerals<br />

is not easy, because they are layer aluminosilicates that can change their structures (d-spacings) in response to their chemical environment,<br />

sometimes in a matter of seconds. St<strong>and</strong>ard techniques have been developed over the last eighty or so years to identify<br />

various clay minerals using X-ray diffraction (XRD). Even with diagnostic chemical preparation in the controlled environment<br />

of the laboratory, clay minerals sometimes require elaborate means to get an unambiguous identification using XRD. A non-laboratory<br />

method of clay mineral identification is claimed by a group at the USA Geological Survey (USGS) that uses analysis of<br />

visible <strong>and</strong> near-infrared (NIR) spectra reflected from the ground, <strong>and</strong> detected from an airplane flying over the area of interest.<br />

The purpose of this study is to analyze by traditional means claims regarding clay mineral identification using the AVIRIS system.<br />

A specific study of clay mineral interpretations was conducted on an image of the Summitville mine site in southwestern Colorado.<br />

This study centers on verifying clay mineral identifications made by Clark et al. (1995). Most clay mineral structures were originally<br />

determined in the 1930s using XRD. This method was developed <strong>and</strong> applied to minerals by Nobel laureate Linus Pauling.<br />

We used XRD to analyze the mineral constituents in the area interpreted by Clark et al. (1995). The characterization of clay minerals<br />

as distinct crystalline materials as opposed to amorphous material was not proven until XRD was used to verify this in the<br />

1930s. Since then XRD has remained the st<strong>and</strong>ard method of clay mineral identification. The objective of this study was to use<br />

XRD to attempt to verify a new method, imaging spectroscopy.<br />

Derived from text<br />

Clays; Mineral Deposits; Mineral Exploration; Remote Sensing; X Ray Diffraction; Infrared Spectroscopy<br />

<strong>2000</strong>0064536 California State Univ., Dept. of Biology <strong>and</strong> Microbiology, Los Angeles, CA USA<br />

A Multi-Scale Sampling Strategy for Detecting Physiologically Significant Signals in AVIRIS Imagery<br />

Gamon, John A., California State Univ., USA; Lee, Lai-Fun, California State Univ., USA; Qiu, Hong-Lie, California State Univ.,<br />

USA; Davis, Stephen, Pepperdine Univ., USA; Roberts, Dar A., California Univ., USA; Ustin, Susan L., California Univ., USA;<br />

Summaries of the Seventh JPL Airborne Earth Science Workshop January 12-16, 1998; Dec. 19, 1998; <strong>Volume</strong> 1, pp. 111-120;<br />

In English; See also <strong>2000</strong>0064520; No Copyright; Avail: CASI; A02, Hardcopy; A04, Microfiche<br />

Models of photosynthetic production at ecosystem <strong>and</strong> global scales require multiple input parameters specifying physical<br />

<strong>and</strong> physiological surface features. While certain physical parameters (e.g., absorbed photosynthetically active radiation) can be<br />

derived from current satellite sensors, other physiologically relevant measures (e.g., vegetation type, water status, carboxylation<br />

capacity, or photosynthetic light-use efficiency), are not generally directly available from current satellite sensors at the appropriate<br />

geographic scale. Consequently, many model parameters must be assumed or derived from independent sources, often at an<br />

inappropriate scale. An abundance of ecophysiological studies at the leaf <strong>and</strong> canopy scales suggests strong physiological control<br />

of vegetation-atmosphere CO2 <strong>and</strong> water vapor fluxes, particularly in evergreen vegetation subjected to diurnal or seasonal<br />

stresses. For example hot, dry conditions can lead to stomatal closure, <strong>and</strong> associated ”downregulation” of photosynthetic<br />

biochemical processes, a phenomenon often manifested as a ”midday photosynthetic depression”. A recent study with the revised<br />

simple biosphere (SiB2) model demonstrated that photosynthetic downregulation can significantly impact global climate. However,<br />

at the global scale, the exact significance of downregulation remains unclear, largely because appropriate physiological measures<br />

are generally unavailable at this scale. Clearly, there is a need to develop reliable ways of extracting physiologically relevant<br />

information from remote sensing. Narrow-b<strong>and</strong> spectrometers offer many opportunities for deriving physiological parameters<br />

needed for ecosystem <strong>and</strong> global scale photosynthetic models. Experimental studies on the ground at the leaf- to st<strong>and</strong>-scale have<br />

indicated that several narrow-b<strong>and</strong> features can be used to detect plant physiological status. One physiological signal is caused<br />

105

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