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Scientific and Technical Aerospace Reports Volume 38 July 28, 2000

Scientific and Technical Aerospace Reports Volume 38 July 28, 2000

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<strong>2000</strong>0067648 NASA Marshall Space Flight Center, Huntsville, AL USA<br />

Mechanisms for the Crystallization of ZBLAN<br />

Ethridge, Edwin C., NASA Marshall Space Flight Center, USA; Tucker, Dennis S., NASA Marshall Space Flight Center, USA;<br />

[<strong>2000</strong>]; 1p; In English; Microgravity Materials, 8 Jun. <strong>2000</strong>, Huntsville, AL, USA; Sponsored by NASA, USA; No Copyright;<br />

Avail: Issuing Activity; Abstract Only<br />

A number of research teams have observed that glass forming melts that are solidified in low-g exhibit enhanced glass formation.<br />

This project will examine one of these glasses, the heavy metal fluoride glass ZBLAN. A four year ground based research<br />

program has been approved to examine the crystallization of ZBLAN glasses with the purpose of testing a theory for the crystallization<br />

of ZBLAN glass. The theory could explain the general observations of enhanced glass formation of other glasses melted<br />

<strong>and</strong> solidified in low-g. Fluid flow in 1-g results from buoyancy forces <strong>and</strong> surface tension driven convection. This fluid flow can<br />

introduce shear in undercooled liquids in 1-g. In low-g it is known that fluid flows are greatly reduced so that the shear rate in<br />

fluids in low-g are extremely low. It is believed that fluids may have some weak structure in the absence of flow. Even very small<br />

shear rates could cause this structure to collapse in response to the shear. A general result would be shear thinning of the fluid.<br />

The hypothesis of this research is that: Shear thinning in undercooled liquids increases the rate of nucleation <strong>and</strong> crystallization<br />

of glass forming melts. Shear of the melt can be reduced in low-g enhancing undercooling <strong>and</strong> glass formation. Samples will be<br />

melted <strong>and</strong> quenched in 1-g under quiescent conditions at a number of controlled cooling rates to determine times <strong>and</strong> temperatures<br />

of crystallization <strong>and</strong> heated at controlled heating rates to determine kinetic crystallization parameters. Experiments will also be<br />

performed on the materials while under controlled vibration conditions <strong>and</strong> compared with the quiescent experiments in order<br />

to evaluate the effect of shear in the liquid on crystallization kinetics. After the experimental parameters are well known, experiments<br />

will be repeated under low-g (<strong>and</strong> 2-g) conditions on the KC-135 aircraft during low-g parabolic maneuvers. The results<br />

will determine the effects of shear on crystallization. Our experimental setups will be designed with low-g experiments in mind<br />

<strong>and</strong> will be tested as breadboard low-g experiments. It is very likely that the thermal analysis instrumentation can be adapted to<br />

be run in the microgravity glovebox facilities. Critical space experiments may result to test the theory at longer low-g time experiments<br />

in space.<br />

Author<br />

Crystallization; Glass; Metal Fluorides; Melts (Crystal Growth)<br />

77<br />

PHYSICS OF ELEMENTARY PARTICLES AND FIELDS<br />

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<strong>2000</strong>0062449 Forschungszentrum Rossendorf e.V., Dresden, Germany<br />

Kaons in nuclear matter<br />

Kolomeitsev, E. E.; Feb. <strong>28</strong>, 1997; 170p; In German; In English<br />

Report No.(s): DE99-715823; FZR-167; No Copyright; Avail: Department of Energy Information Bridge<br />

The subject of the doctoral thesis is examination of the properties of kaons in nuclear matter. A specific method is explained<br />

that has been developed for the scientific objectives of the thesis <strong>and</strong> permits description of the kaon- nucleon interactions <strong>and</strong><br />

kaon-nucleon scattering in a vacuum. The main challenge involved was to find approaches that would enable application of the<br />

derived relations out of the kaon mass shell, connected with the second objective, namely to possibly find methods which are independent<br />

of models. The way chosen to achieve this goal relied on application of reduction formulas as well as current algebra<br />

relations <strong>and</strong> the PCAC hypothesis.<br />

NTIS<br />

Kaons; Matter (Physics); Nucleons<br />

<strong>2000</strong>0062715 Joint Inst. for Nuclear Research, Bogolyubov Lab. of Theoretical Physics, Dubna, USSR<br />

Is the Casimir effect relevant to sonoluminescence<br />

Nesterenko, V. V.; Pirozhenko, I.; Dec. 31, 1998; 12p; In English<br />

Report No.(s): DE99-607974; JINR-E-2-98-40; No Copyright; Avail: Department of Energy Information Bridge<br />

The Casimir energy of a solid ball (or cavity in an infinite medium) is calculated by a direct frequency summation using the<br />

contour integration. The dispersion is taken into account, <strong>and</strong> the divergences are removed by making use of the zeta function<br />

technique. The Casimir energy of a dielectric ball (or cavity) turns out to be positive, it being increased when the radius of the<br />

ball decreases. The latter eliminates completely the possibility of explaining, via the Casimir effect, the sonoluminescence for<br />

207

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