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Pierre River Mine Project

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AIR AENV SIRS 6 – 14<br />

Section 11.1<br />

Risk management requires that the criticality of the failure be considered. This<br />

requires that both the probability and the consequence of failure be considered<br />

jointly. A piece of equipment that fails frequently but whose failure carries little<br />

consequence poses a low risk. On the other hand, equipment that has a low<br />

frequency of failure but whose failure has serious consequences is a high risk<br />

management issue. In the response to this SIR 250d, Shell acknowledges that<br />

there is a potential to create concentrations sufficient to cause acute injury to<br />

vegetation.<br />

13a Discuss potential human health effects as a result of accidental releases of SO2.<br />

Provide quantitative evidence in support of the discussion.<br />

Response 13a The health assessment for this upset scenario was included in EIA, Volume 3,<br />

Appendix 3-8, Section 4.3.3.<br />

Question No. 14<br />

As part of the health assessment, maximum predicted ground-level air<br />

concentrations of SO2 were compared to varying concentrations at which health<br />

effects are known to occur. As discussed, the aim of the health assessment was to<br />

establish the nature and severity of the health effects related to the predicted air<br />

concentrations associated with the described upset events.<br />

The findings of the health assessment indicated that some of the predicted SO2<br />

concentrations were high enough to potentially cause adverse health effects.<br />

However, Shell has committed to redundant SO2 pollution control equipment that<br />

will switch to natural gas within 15 minutes and, consequently, decrease the<br />

exposure time.<br />

Request Volume 2, SIR 235a, Page 20-2.<br />

Shell indicates The typical odour threshold for each compound was determined<br />

by calculating the geometric mean of the available odour thresholds. It is<br />

common practice in sensory evaluation to use geometric means as they account<br />

for the wide range of responses over several orders if magnitude. The SIR<br />

response then demonstrates the calculation of an H2S threshold using the<br />

maximum and minimum values from the 9 pieces of cited literature. The<br />

calculation assumes that all of the reported H2S odour thresholds in the cited<br />

references are equally valid in calculating the geometric mean. Many of the<br />

references Shell cites for odour thresholds are outdated and not appropriate for<br />

the objective of assessing the effects of odour. More recent sources of<br />

information provide confirmation of much lower odour thresholds for H2S (e.g.,<br />

Harvard University 2005 1 ; Iowa State University 2004 2 ; Lenntech 2006 3 ). All of<br />

these sources confirm an odour threshold of 1 ppb for H 2 S. The use of the<br />

geometric mean concentration value of 14 µg/m 3 underestimates H2S odour<br />

impacts due to the proposed development knowing that there are observation<br />

data to demonstrate that H2S is detectable at instantaneous odour concentrations<br />

April 2010 Shell Canada Limited 11-13<br />

CR029

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