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Advances in Fingerprint Technology.pdf

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laser<br />

Figure 6.6 Block diagram of phase-shift/demodulation apparatus for time-resolved<br />

imag<strong>in</strong>g.<br />

F<strong>in</strong>gerpr<strong>in</strong>t Treatments<br />

F<strong>in</strong>gerpr<strong>in</strong>t treatments suitable for time-resolved imag<strong>in</strong>g began to be<br />

explored <strong>in</strong> the late 1980s. At first, transition metal complexes that yield<br />

charge-transfer phosphorescences were successfully exam<strong>in</strong>ed and applied to<br />

f<strong>in</strong>gerpr<strong>in</strong>t development by dust<strong>in</strong>g or sta<strong>in</strong><strong>in</strong>g. 15 However, such complexes<br />

could not be utilized for chemical f<strong>in</strong>gerpr<strong>in</strong>t development, thus limit<strong>in</strong>g the<br />

approach primarily to smooth surfaces. Next, lanthanide-based procedures<br />

were explored. These have the potential of form<strong>in</strong>g a universal photolum<strong>in</strong>escence<br />

approach to f<strong>in</strong>gerpr<strong>in</strong>t detection, be<strong>in</strong>g applicable, <strong>in</strong> pr<strong>in</strong>ciple, to<br />

all types of surface and to f<strong>in</strong>gerpr<strong>in</strong>ts of any age. They have by now reached<br />

a reasonable level of maturity. However, problems persist with the lanthanide<br />

(rare earth) approaches, thus prompt<strong>in</strong>g more recent <strong>in</strong>vestigation of photolum<strong>in</strong>escent<br />

semiconductor nanocomposites.<br />

Lanthanide-Based Procedures<br />

modulator<br />

delay<br />

s<strong>in</strong>e<br />

wave<br />

generator<br />

MCP<br />

CCD<br />

f<strong>in</strong>gerpr<strong>in</strong>t<br />

sample<br />

computer<br />

The concept of time-resolved f<strong>in</strong>gerpr<strong>in</strong>t detection for purposes of background<br />

fluorescence suppression actually dates back to 1979. 16 Its feasibility<br />

then was explored us<strong>in</strong>g a rotat<strong>in</strong>g cyl<strong>in</strong>der with slots cut <strong>in</strong>to it to turn the<br />

laser illum<strong>in</strong>ation on and off. The photographic camera was placed such that<br />

the sample would come <strong>in</strong>to its view at a time after laser cut-off, as shown<br />

<strong>in</strong> Figure 6.7. The arrangement resembles a phosphoroscope, a device that<br />

dates back to the 19th century. The sample was a f<strong>in</strong>gerpr<strong>in</strong>t dusted with a<br />

powder that conta<strong>in</strong>ed a Tb 3+ complex, yield<strong>in</strong>g a green lum<strong>in</strong>escence of<br />

millisecond-order lifetime. The f<strong>in</strong>gerpr<strong>in</strong>t was located on yellow notepad

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