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Advances in Fingerprint Technology.pdf

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Coll<strong>in</strong> and Thomas (U.K., 1972). Accord<strong>in</strong>g to Goode and Morris, 13 Coll<strong>in</strong><br />

and Thomas <strong>in</strong>vestigated the use of one of the classical silver physical<br />

developers to enhance pr<strong>in</strong>ts developed by the vacuum metal deposition<br />

process. The idea was sound. These authors knew that silver physical developers<br />

detect very low levels of silver metal and other metals. It is, for example,<br />

one of the most sensitive methods that Feigl 11 cites for detect<strong>in</strong>g silver (his<br />

book was first published <strong>in</strong> English <strong>in</strong> 1937). Thus, they reasoned that because<br />

the vacuum metal deposition process, after the <strong>in</strong>itial deposition of gold,<br />

deposits z<strong>in</strong>c or cadmium all over the surface and <strong>in</strong> the f<strong>in</strong>gerpr<strong>in</strong>t furrows,<br />

but not on the f<strong>in</strong>gerpr<strong>in</strong>t ridges, then an Ag-PD should enhance the furrow<br />

regions. They noted the potential of its use but were limited by the <strong>in</strong>stability<br />

of the classical Ag-PD they used.<br />

Fuller and Thomas 14 (U.K., 1974). These authors also <strong>in</strong>vestigated a classical<br />

Ag-PD for visualiz<strong>in</strong>g latent pr<strong>in</strong>ts on fabrics and paper. They used the<br />

Metol/citric acid reduc<strong>in</strong>g agent <strong>in</strong> their Ag-PD. The <strong>in</strong>terest<strong>in</strong>g part of their<br />

work lies <strong>in</strong> their Appendix 1 (process modifications). It is surpris<strong>in</strong>g that<br />

many of the ideas they had are now be<strong>in</strong>g further <strong>in</strong>vestigated. For example,<br />

regard<strong>in</strong>g their suggestion to use metals other than silver, Dr. Kev<strong>in</strong> Kyle of<br />

the Special Technologies Laboratory (a Department of Energy [DOE] Laboratory<br />

located <strong>in</strong> Santa Barbara, CA) has <strong>in</strong>vestigated a copper-based physical<br />

developer. The DOE funded this project dur<strong>in</strong>g 1998–1999 and the U.S.<br />

Secret Service managed the research. Other ideas of Fuller and Thomas<br />

<strong>in</strong>clude sequential treatment with Ag-PD components and film-transfer<br />

methods.<br />

Morris 15 (U.K., 1975). Morris was the first to document the use of the<br />

“Philips Physical Developer” (a name given by Morris to the “FC-1” silver<br />

physical developer formulated by Jonker, Molenaar, and Dipple <strong>in</strong> The Netherlands)<br />

for visualiz<strong>in</strong>g latent pr<strong>in</strong>ts on paper. It uses the reversible ferrous/ferric<br />

redox couple with citric acid for the reduc<strong>in</strong>g agent. The FC <strong>in</strong><br />

the Philips formulation FC-1 stands for ferrous/ferric citric. In our op<strong>in</strong>ion,<br />

this is Morris’ Ag-PD pioneer<strong>in</strong>g work. It <strong>in</strong>troduced the currently used Ag-<br />

PD. Morris clearly saw the potential of the Ag-PD for visualiz<strong>in</strong>g latent pr<strong>in</strong>ts<br />

on water-soaked paper (he obta<strong>in</strong>ed pr<strong>in</strong>ts even after 12 days of immersion).<br />

He saw it as a post-n<strong>in</strong>hydr<strong>in</strong> reagent. He also provided a hypothesis for how<br />

the developer works, propos<strong>in</strong>g that “trigger” materials exist on the latent<br />

pr<strong>in</strong>t residue that act as catalytic nuclei and <strong>in</strong>itiate the physical development<br />

process (similar to the silver and silver sulfide specks on the photo-exposed<br />

silver halide crystals <strong>in</strong> photography). These “trigger” materials <strong>in</strong>clude: (1)<br />

wax esters (lipids) because these can strip away the surfactant shell from<br />

(spontaneously formed) silver nuclei formed <strong>in</strong> solution, and (2) chloride

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