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Thesis - faculty.ait.ac.th - Asian Institute of Technology

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2.1 Introduction<br />

Chapter 2<br />

Literature Review<br />

A landfill is any form <strong>of</strong> waste land, ranging from an uncontrolled rubbish "dump" to<br />

a full "containment" site engineered wi<strong>th</strong> high standards to protect <strong>th</strong>e environment. The<br />

landfill is <strong>th</strong>e most economical form <strong>of</strong> solid waste disposal as adverse environmental<br />

effects and o<strong>th</strong>er risks and inconveniences are minimized, <strong>th</strong>ereby allowing waste to<br />

decompose under controlled conditions until it eventually transforms into relatively inert,<br />

stabilized material (Robinson and Maris, 1983). Most landfills can be operated<br />

satisf<strong>ac</strong>torily for at least some period in <strong>th</strong>eir lifetime in <strong>th</strong>is manner and in absence <strong>of</strong> any<br />

significant negative environmental imp<strong>ac</strong>t.<br />

Unfortunately, in warmer climates, <strong>th</strong>e increase in le<strong>ac</strong>hate production after<br />

precipitation is rapid (Lema, et al., 1988) due to rainfall exceeding <strong>th</strong>e amount which can<br />

be effectively evaporated during winter or rainy seasons. Hence, le<strong>ac</strong>hate generation needs<br />

to be controlled and effective le<strong>ac</strong>hate treatment options have to be identified in order to<br />

avoid negative imp<strong>ac</strong>ts caused by <strong>th</strong>e le<strong>ac</strong>hate.<br />

A common pr<strong>ac</strong>tice in controlling le<strong>ac</strong>hate generation is to control <strong>th</strong>e water<br />

infiltration in <strong>th</strong>e landfill by waste comp<strong>ac</strong>tion as it reduces <strong>th</strong>e infiltration rate. Fur<strong>th</strong>er, by<br />

designing water pro<strong>of</strong> covers and growing plants on <strong>th</strong>e soil covers <strong>of</strong> <strong>th</strong>e waste,<br />

infiltration can be minimized. Figure 2.1 presents a typical engineered landfill. The landfill<br />

le<strong>ac</strong>hate char<strong>ac</strong>teristic is controlled by solid waste char<strong>ac</strong>teristics, moisture content, pH,<br />

redox potential, temperature, etc. The presence <strong>of</strong> moisture is necessary for <strong>th</strong>e biological<br />

conversions wi<strong>th</strong>in <strong>th</strong>e landfill and for landfill stabilisation, which occurs when <strong>th</strong>ere is<br />

insufficient moisture. Degradation processes wi<strong>th</strong>in <strong>th</strong>e landfill are also temperature<br />

dependent. The pH and redox potential set <strong>th</strong>e conditions for <strong>th</strong>e different phases <strong>of</strong><br />

degradation and biological processes wi<strong>th</strong>in <strong>th</strong>e landfill. Thus, <strong>th</strong>e microbial composition<br />

wi<strong>th</strong>in <strong>th</strong>e landfill effectively contributes to <strong>th</strong>e landfill stabilization.<br />

After <strong>th</strong>e initial period <strong>of</strong> waste pl<strong>ac</strong>ement in a landfill, microbial processes proceed<br />

under anoxic conditions. Hydrolytic and fermentative microbial processes solubilize <strong>th</strong>e<br />

waste components during <strong>th</strong>e <strong>ac</strong>id fermentation phase producing organic <strong>ac</strong>ids, alcohols,<br />

ammonia, carbon dioxide and o<strong>th</strong>er low molecular weight compounds as major products.<br />

This process occurs at a low pH (typically around 5) and is enhanced by <strong>th</strong>e presence <strong>of</strong><br />

moisture wi<strong>th</strong>in <strong>th</strong>e landfill. After several mon<strong>th</strong>s, <strong>th</strong>e me<strong>th</strong>ane fermentation stage occurs.<br />

Me<strong>th</strong>anogenic le<strong>ac</strong>hate is neutral in pH and possesses moderate organic compounds which<br />

are not easily degradable and are fermented to yield me<strong>th</strong>ane, carbon dioxide and o<strong>th</strong>er<br />

gaseous end products (Harmsen, 1983; Farquhar, 1989).<br />

5

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