Thesis - faculty.ait.ac.th - Asian Institute of Technology
Thesis - faculty.ait.ac.th - Asian Institute of Technology
Thesis - faculty.ait.ac.th - Asian Institute of Technology
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influent re<strong>ac</strong>hed 200 mg/L. For <strong>th</strong>e wastewater polluted wi<strong>th</strong> phenol, phenol concentration<br />
range <strong>of</strong> 1,000-1,500 mg/L could inhibit <strong>th</strong>e respiration <strong>of</strong> <strong>th</strong>e sludge by 37%.<br />
Kim, et al. (1994) investigated <strong>th</strong>e toxicity by using respiration meter, <strong>th</strong>e data<br />
evaluation show <strong>th</strong>at <strong>th</strong>e respiration rate decreased about 20% at Cobalt (Co) concentration<br />
<strong>of</strong> 28 mg/L. It was reported <strong>th</strong>at <strong>th</strong>e grow<strong>th</strong> microorganisms was inhibited even at a<br />
concentration lower <strong>th</strong>an 0.08 mg/L. In addition, <strong>th</strong>e toxicity test was conducted in high<br />
and low pH conditions and it was found <strong>th</strong>at respiration rate decreased in bo<strong>th</strong>.<br />
Madoni, et al. (1996, 1999) investigated <strong>th</strong>e effect <strong>of</strong> lead toxicity on <strong>ac</strong>tivated<br />
sludge process. The respiration rate was inhibited 67% at <strong>th</strong>e soluble lead concentration <strong>of</strong><br />
16.9 mg/L after one hour exposure. The <strong>ac</strong>ute toxicity <strong>of</strong> lead to organisms has been<br />
reported at concentration ranging from 2 to 6 mg/L.<br />
The concentrations <strong>of</strong> various toxicants and <strong>th</strong>eir inhibitory on b<strong>ac</strong>terial respiration<br />
are summarized in Table 2.17.<br />
Table 2.17 Inhibitory Effect <strong>of</strong> Various Toxicants<br />
Toxicants Concentration Inhibition <strong>of</strong> Respiration Reference<br />
(mg/L)<br />
(%)<br />
Co 28 20 Kim, et al., 1994<br />
Cu 50 30 Temmink, et al., 1993<br />
Cd 40 50 Talinli and Tokta, 1994<br />
Ni 9 50 Talinli and Tokta, 1994<br />
Pb 16.9 67 Madoni, et al., 1999<br />
Phenol 1,000-1,500<br />
37<br />
Temmink, et al., 1993<br />
1,600<br />
50<br />
Talinli and Tokta, 1994<br />
2.11 Membrane Biore<strong>ac</strong>tors<br />
Biore<strong>ac</strong>tors are re<strong>ac</strong>tors <strong>th</strong>at convert or produce materials using functions naturally<br />
endowed to living creatures. Re<strong>ac</strong>tors using immobilized enzymes, microorganisms,<br />
animal, or plant cells and <strong>th</strong>ose applying new me<strong>th</strong>odologies such as genetic manipulation<br />
or cell fusion are typical biore<strong>ac</strong>tors (Belfort, 1989). Therefore, biore<strong>ac</strong>tors are re<strong>ac</strong>tors<br />
used to produce material wi<strong>th</strong> new or advanced technology by <strong>th</strong>e application <strong>of</strong> biological<br />
functions.<br />
The combination <strong>of</strong> membranes to biological processes for treatment has led to <strong>th</strong>e<br />
emergence <strong>of</strong> membrane biore<strong>ac</strong>tors (MBR) for separation and retention <strong>of</strong> solids; for<br />
bubble-less aeration wi<strong>th</strong>in <strong>th</strong>e biore<strong>ac</strong>tor; and for extr<strong>ac</strong>tion <strong>of</strong> priority organic pollutants<br />
from industrial contaminated water (Stephenson, et al., 2000). The membrane unit can be<br />
configured external to or immersed in <strong>th</strong>e biore<strong>ac</strong>tor (Figure 2.10).<br />
In an external circuit, <strong>th</strong>e membranes can be ei<strong>th</strong>er internally or externally skinned<br />
whilst submerged membrane re<strong>ac</strong>tors should contain membranes <strong>th</strong>at are externally<br />
skinned. The incorporating <strong>of</strong> membranes into <strong>th</strong>e biological re<strong>ac</strong>tor has eliminated <strong>th</strong>e<br />
sedimentation tank from biological treatment step associated wi<strong>th</strong> conventional wastewater<br />
treatment pr<strong>ac</strong>tices.<br />
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