Thesis - faculty.ait.ac.th - Asian Institute of Technology

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3.1 Introduction Chapter 3 Methodology The present study on landfill leachate treatment comprises of four experimental stages, namely: toxicity study, ammonia stripping, membrane bioreactor study and sludge characterization. The different experimental stages of this study are shown in the Figure 3.1. MBR process HRT Sludge characteristics Figure 3.1 Flowchart Showing Different Stages of Experimental Study 3.2 Leachate Characterization Acclimatized yeast and bacteria sludges Toxicity study Ammonia stripping study Membrane bioreactor study MWCO The leachate used for the treatment was obtained from Pathumthani Landfill Site and Ram-Indra Transfer Station, which were initially characterized. After characterization these leachates were mixed in an appropriate proportion to simulate a medium-aged leachate composition. The characteristic of the simulated leachate used for the study is shown in Table 3.1. 54 Ammonia nitrogen Lead pH Gradient velocity Contact time Coupling ammonia stripping with MBR process Sludge characteristics MWCO
Table 3.1 Composition of Simulated Leachate Parameters Concentration pH 7.8-8.2 COD (mg/L) 8,000±1,000 BOD/COD 0.40±0.05 NH4-N (mg/L) 1,700±100 TKN (mg/L) 1,900±100 TDS (mg/L) 12,000±1,000 Note: Pb concentration is below 0.3 mg/L, which has no effect on microbial toxicity. 3.3 Seed Study 3.3.1 Yeast and Bacterial Sludge a) Yeast Sludge The mixed yeast sludge comprises of a mixture of wild yeast varieties that exist in the raw wastewater and which quantitatively propagate under normal enrichment conditions. The procedure for enrichment of yeasts was carried out according to the Standard Methods for the examination of water and wastewater (APHA, et al., 1998). The yeast strains were selected based on competition among different organisms present in wastewater (Nishihara Ltd., 2001) by the enrichment culture technique. Figure 3.2 illustrates the procedure for enrichment of yeast. Seed Seed yeast yeast sludge sludge (from (from sediments sediments) ) Filling Aeration Aeration 24 24 h h MLSS Completion Enriched Completion Enriched culture > 3,000 mg/L Figure 3.2 Diagram Illustrating the Enrichment Procedure 55 < 3,000 mg/L Drawing Settling
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APPLICATION OF MEMBRANE BIOREACTOR
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Abstract Landfill leachate is a com
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Table of Contents Chapter Title Pag
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4.5.6 Cost Analysis for Operation 1
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4.4 Effect of Free Ammonia Concentr
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4.16 COD Concentration in the Influ
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MWCO Molecular Weight Cut-off MWW M
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1.1 Background Chapter 1 Introducti
Page 17 and 18: generally unsuccessful in removal o
Page 19 and 20: 2.1 Introduction Chapter 2 Literatu
Page 21 and 22: In the municipal solid waste landfi
Page 23 and 24: COD/TOC, VS/FS and VFA/TOC ratios o
Page 25 and 26: Table 2.3 presents the general leac
Page 27 and 28: Ground water 2.7.1 Seasonal Variati
Page 29 and 30: Table 2.5 Variation of COD, BOD & B
Page 31 and 32: entails the re-circulation of leach
Page 33 and 34: Table 2.8 Summary of Biokinetic Coe
Page 35 and 36: that extensive loss of nitrogen (up
Page 37 and 38: ammonia could only be achieved when
Page 39 and 40: Table 2.10 Treatment Efficiencies o
Page 41 and 42: Activated Carbon Adsorption Granula
Page 43 and 44: Colloidal material as well as metal
Page 45 and 46: iologically, physical-chemical proc
Page 47 and 48: Ammonia Stripping Air stripping of
Page 49 and 50: These systems are land intensive wh
Page 51 and 52: the biological treatment can be rep
Page 53 and 54: Table 2.16 Typical Leachate Composi
Page 55 and 56: influent reached 200 mg/L. For the
Page 57 and 58: Table 2.18 Advantages and Disadvant
Page 59 and 60: through the effluent. Different ope
Page 61 and 62: Mixed Liquor Suspended Solids and D
Page 63 and 64: 2.12 Yeasts 2.12.1 Introduction The
Page 65 and 66: Nishihara ESRC Ltd. (2001) studied
Page 67: nitrification-denitrification proce
Page 71 and 72: 3.4.1 Ammonia Toxicity The experime
Page 73 and 74: Figure 3.4 Experiments Conducted to
Page 75 and 76: Leachate Option Ammonia Stripping R
Page 77 and 78: MW larger than 50 kDa, (2) MW betwe
Page 79 and 80: Figure 3.7 Flowchart Showing Ammoni
Page 81 and 82: Chapter 4 Results and Discussion 4.
Page 83 and 84: COD Removal Effeciency (%) COD Remo
Page 85 and 86: MLSS (mg/L) 14000 12000 10000 8000
Page 87 and 88: Specific Growth Rate ( d -1 ) 0.50
Page 89 and 90: change in the predominant species w
Page 91 and 92: Table 4.4 Effect of Free Ammonia Co
Page 93 and 94: Table 4.5 Substrate Utilization by
Page 95 and 96: 4.3.1 Initial Membrane Resistance P
Page 97 and 98: when compared with the present stud
Page 99 and 100: COD Removal Efficiency (%) 90 80 70
Page 101 and 102: (2) TKN Removal Efficiency Prior to
Page 103 and 104: As there was no significant improve
Page 105 and 106: The probable reason for frequent fo
Page 107 and 108: Ammonia Concentration (mg/L) Ammoni
Page 109 and 110: concentration after treatment. Othe
Page 111 and 112: After the chemical cleaning of the
Page 113 and 114: emoval of 38%. A higher removal in
Page 115 and 116: Influent BOD (mg/L) Influent BOD (m
Page 117 and 118: (3) TKN Removal Efficiency The TKN
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Figure 4.34 gives the overall TKN r
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fraction and slowly biodegradable C
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BOD (mg/L) BOD (mg/L) 6000 5000 400
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Figure 4.39 Molecular Weight Cut-of
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COD (mg/L) 8000 6000 4000 2000 COD
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Though, the obtained COD removal ef
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cake used on the top of the membran
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Chapter 5 Conclusions and Recommend
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0.02, respectively. This can be con
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References Abeling, U., and Seyfrie
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Brown, M.J., and Lester, J.N., 1980
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Diamadopoulos, E., 1994. Characteri
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Grady, C.P.L., Daigger, G.T., and L
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Keenan, J.D., Steiner, R.L., and Fu
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Martin, G.M.A., Auzmenti, A.I., and
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Pohland, F.G., and Harper, S.R., 19
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Shin, H.S., An, H., Kang, S.T., Cho
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Visvanathan, C., Ben Aim, R., and P
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Appendix A Pictures of Experiments
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Raw Leachate YMBR Effluent BMBR Eff
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Appendix B Leachate Characteristics
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Table B-2 Acclimation of Mixed Yeas
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Appendix C Experimental Data of Bio
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y: Where: OUR at line g: This is th
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Table C-3 Experimental Results for
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Appendix D Membrane Resistance Stud
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Table D-3 Experimental Data for Det
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Table D-4 Experimental Data for Det
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Pressure (kPa) Pressure (kPa) 25 20
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Appendix E MBR without Ammonia Stri
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Day HRT (h) pH COD (mg/L) Feed Reac
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Day HRT (h) pH COD (mg/L) Feed Reac
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Table E-3 Variation in TMP with Tim
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Appendix F Ammonia Stripping Studie
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Table F-5 Pilot Scale Study on Ammo
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Table G-1 Feed, Reactor and Effluen
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Table G-3 Feed, Reactor and Effluen
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Appendix H Other Studies 179
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Table H-2 Membrane Resistance of th
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Table H-6 Chemical Cost for the Yea
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Thesis - faculty.ait.ac.th - Asian Institute of Technology

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