Thesis - faculty.ait.ac.th - Asian Institute of Technology
Thesis - faculty.ait.ac.th - Asian Institute of Technology
Thesis - faculty.ait.ac.th - Asian Institute of Technology
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Where;<br />
J = ∆P Eq. 4.2<br />
µRt<br />
J = Permeate flux (L/m 2 .h)<br />
∆P = Applied pressure (kPa)<br />
µ = Dynamic viscosity (N.s/m 2 )<br />
Rt = Total resistance for filtration or Hydraulic resistance <strong>of</strong> clean<br />
membrane (m -1 )<br />
The membrane resistance (Rm) <strong>of</strong> <strong>th</strong>e YMBR was found to be 6.66 x 10 11 m -1 and<br />
<strong>th</strong>at <strong>of</strong> BMBR was found to be 6.29 x 10 11 m -1 . The membrane used in <strong>th</strong>e study had a<br />
surf<strong>ac</strong>e area <strong>of</strong> 0.42 m 2 and pore size <strong>of</strong> 0.1 µm. Bo<strong>th</strong> <strong>th</strong>e membranes had a similar pore<br />
size and almost <strong>th</strong>e same membrane resistance. The membrane resistant is important as<br />
wi<strong>th</strong> increasing membrane operation, <strong>th</strong>e membrane resistance tends to increase <strong>th</strong>e<br />
transmembrane pressure, which after a certain limit decreases <strong>th</strong>e flux to a great extent.<br />
During <strong>th</strong>is stage when <strong>th</strong>e transmembrane pressure re<strong>ac</strong>hes a maximum, <strong>th</strong>e membrane is<br />
said to be fouled. The effect <strong>of</strong> <strong>th</strong>e membrane resistance prior to and after fouling has also<br />
been studied which would be discussed in later part <strong>of</strong> <strong>th</strong>is chapter.<br />
4.3.2 Optimization <strong>of</strong> HRT in Terms <strong>of</strong> Membrane Biore<strong>ac</strong>tor Treatment Efficiency<br />
(1) COD Removal Efficiency<br />
The influent COD concentration was maintained around 7,000 to 9,000 mg/L, and<br />
<strong>th</strong>e volumetric loading rate was gradually increased from 6.7 to 17.9 kg COD/m 3 .d by<br />
decreasing HRT from 24 h to 12 h wi<strong>th</strong> 4 h decrement. A detailed tabulation <strong>of</strong> <strong>th</strong>e results<br />
is given in Table E-1 and E-2 <strong>of</strong> Appendix E for <strong>th</strong>e BMBR and YMBR systems,<br />
respectively. The increase in organic loading in terms <strong>of</strong> COD concentration and change in<br />
HRT is presented in Figure 4.13. As a real le<strong>ac</strong>hate from <strong>th</strong>e transfer station and sanitary<br />
landfill was used, fluctuations in <strong>th</strong>e feed could not be avoided. In all experimental runs,<br />
<strong>th</strong>e MLSS <strong>of</strong> bo<strong>th</strong> <strong>th</strong>e systems were maintained around 10,000 to 12,000 mg/L and DO<br />
concentration <strong>of</strong> above 2.0 mg/L. Figure 4.14 and 4.15 illustrates <strong>th</strong>e MLSS concentration<br />
and pH, respectively in bo<strong>th</strong> <strong>th</strong>e membrane biore<strong>ac</strong>tors. The fluctuations in <strong>th</strong>e pH <strong>of</strong> <strong>th</strong>e<br />
BMBR re<strong>ac</strong>tor could be due to <strong>th</strong>e products if <strong>th</strong>e degradation taking pl<strong>ac</strong>e wi<strong>th</strong>in <strong>th</strong>e<br />
system.<br />
While treating <strong>th</strong>e medium-aged landfill wi<strong>th</strong> membrane biore<strong>ac</strong>tors, <strong>th</strong>e effluent<br />
COD concentration fluctuated wi<strong>th</strong> <strong>th</strong>at <strong>of</strong> <strong>th</strong>e influent concentration. The influent and<br />
effluent COD concentration in <strong>th</strong>e BMBR and YMBR are presented in Figure 4.16. It was<br />
observed <strong>th</strong>at <strong>th</strong>e average COD removal efficiency <strong>of</strong> <strong>th</strong>e YMBR was slightly higher <strong>th</strong>an<br />
<strong>th</strong>at <strong>of</strong> <strong>th</strong>e BMBR for varied HRT, <strong>th</strong>ough <strong>th</strong>e difference was just marginal. The reason for<br />
<strong>th</strong>e increased run period at 16h HRT was <strong>th</strong>e absence <strong>of</strong> significant improvement in <strong>th</strong>e<br />
treatment performance in terms <strong>of</strong> COD removal. In a study conducted by Sun, et al., 2002<br />
found similar results. When an influent wastewater wi<strong>th</strong> 2,400 mg/L COD was treated<br />
using a submerged MBR, it was found <strong>th</strong>at a change in HRT from 3 to 6 days did not<br />
significantly affect <strong>th</strong>e performance. The removal efficiency just changed from 92 to 93%.<br />
A high COD removal <strong>of</strong> <strong>th</strong>e high streng<strong>th</strong> wastewater could be due to <strong>th</strong>e increased HRT<br />
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