Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

V.1 Tin crystal 85
Table V-4: Comparison of experimental enthalpy differences of white tin with selected
reference data [1991GUR/VEY2].
T/K
H m (Sn, β, T ) − H m (Sn, β, 471 K)/J·mol –1
[1960GEN/HAG]
[1991GUR/VEY2]
481 289 303
491 573 609
T fus 1004 1044
T/K
H m (Sn, β, T ) − H m (Sn, β, 291 K)/J·mol –1
[1926AWB/GRI]
[1991GUR/VEY2]
366 2210 2075
421 3623 3664
453 4594 4614
T fus 6094 6201
Table V-5 lists compilations/evaluations which present data as a function of
temperature. The compilations [1952ROS/WAG], [1968WAG/EVA] and
[1982WAG/EVA] include data only at 298.15 K. Some references in Table V-5 contain
fitting equations, the parameters of which are found in Table V-6. The equation of
Jaeger and Bottema [1932JAE/BOT] is a fitting equation for the authors’ own
experimental measurements only, and is given here for comparison.
Table V-5: Survey of compilations/evaluations of the heat capacity of white tin
ο
(Sn, β, T ).
C p,m
Reference T/K Discussion Data source given
[1956STU/SIN] 298 − 505 N Y
[1960KEL] 350 − 505 N Y
[1963HUL/ORR], [1973HUL/DES] 298 − 505 Y Y
[1973BAR/KNA]
[1973HUL/DES2], [1982PAN], [1993BAR], [1991DIN] 298 − 505 Y Y
[1978ROB/HEM] 298 − 505 N Y
[1991GUR/VEY], [1993MCB/GOR], [1995ROB/HEM] 100 − 505 Y Y
[1999BIN/MIL] 298 − 505 N N
CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012