Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

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List of figures
Figure IX-3: Heat capacity function of SnS 2 (cr)................................................... 218
Figure IX-4: Solubility of SnS in aqueous HCl. .................................................... 224
Figure IX-5: Extrapolation to I = 0 of the experimental data for reaction Sn 2+
+ SO 2−
SnSO 4 (aq) in NaClO 4 media at 25 °C. .......................... 226
4
Figure X-1:
Figure X-2:
Extrapolation to I = 0 of the experimental data for reaction
Sn 2+ + NO − 3
SnNO + 3
in NaClO 4 media. ..................................... 233
Extrapolation to I = 0 of the experimental data for reaction
Sn 2+ + 2NO −
3
Sn(NO 3 ) 2 (aq) in NaClO 4 media. .......................... 234
Figure X-3: Speciation diagram for the tin(II)-orthophosphate system at I =
3 M (NaClO 4 ) with total concentrations [Sn 2+ ] T = 10 –4 M and
[ PO 3−
] T = 10 –3 M. ............................................................................ 237
Figure X-4:
Figure X-5:
4
Heat capacity data of SnAs(cr) as measured by Koshchenko et
al. [1980KOS/PAS2]. ....................................................................... 243
Two sets of measured heat capacity data for Sn 4 As 3 with
w(Sn) = 0.58 and 0.59 [1980KOS/PAS].. ........................................ 247
Figure XI-1:
Extrapolation to I = 0 of the experimental data for reaction
Sn 2+ + SCN – SnSCN + in NaClO 4 media. .................................... 250
Figure A-1: Solubility of SnI 2 (s) in water at different temperatures. ................... 257
Figure A-2: Solubility of “Sn(OH) 2 (s)” in NaOH solutions. ............................... 259
Figure A-3: log10 K
s,3
(A.9) vs. m(Na + )................................................................ 261
ο
Figure A-4: E of Sn(IV)/Sn(II) vs. c − .................................................. 264
app,HCl
(Cl )tot
Figure A-5: Correction term connecting log 10 {m Sn(IV) /m Sn(II) } and
log 10 { m 4 / m 2 depends on m − ................................................. 264
+
Sn Sn
+}
Cl
Figure A-6: Variation of (RT ln (10)/2F)·log 10 { m 2
Sn
/ m } vs. + 2
Pb
m + ClO 4 − .............. 266
Figure A-7: Variation of { ο ' + 4D RT ln(10)/2F}/mV vs.
E
ClO4
m − . .................... 269
Figure A-8: Equilibrium concentration of Sn 2+ as a function of pH. ................... 271
Figure A-9:
Figure A-10:
E of Sn 4+ /Sn 2+ vs. m (Sn)tot . ....................................................... 275
o
m
'(HCl)
E ' of Sn 4+ /Sn 2+ vs. m HCl . Extrapolation to m HCl = 0 by
E = E + b·m 0.5 HCl . .......................................................... 276
o
m (HCl)
o
m
'(HCl)
o
m(HCl)
CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012