Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

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362 A Discussion of selected references [1978KOS/SAM] The authors performed heat capacity measurements for SnO(tetragonal) at temperatures ranging fron 4.281 to 310.70 K (see Table A-38). Table A-38: Several series of heat capacity measurements of SnO(tetragonal) from [1978KOS/SAM]. T/K ο p,m C (SnO, cr, T )/ T/K –1 J·mol –1·K ο p,m C (SnO, cr, T )/ T/K –1 J·mol –1·K ο p,m C (SnO, cr, T )/ –1 J·mol –1·K 4.281 0.01179 10.056 0.1901 40.004 7.5341 4.325 0.01227 10.707 0.2315 43.593 8.6393 5.266 0.02396 11.809 0.3331 46.631 9.5768 5.4 0.02827 12.295 0.4244 50.231 10.6981 6.421 0.04820 New series 54.042 11.8775 7.024 0.06295 7.312 0.07243 57.140 12.9227 7.447 0.07706 8.468 0.1155 63.610 15.5285 7.646 0.08357 12.766 0.4512 69.244 17.0310 8.742 0.1277 13.389 0.5716 71.678 17.434 9.838 0.1826 13.941 0.5709 72.524 17.8565 10.619 0.2274 14.448 0.6809 74.684 18.4731 11.218 0.2684 14.883 0.8089 77.774 19.0753 12.066 0.3199 New series 81.986 20.2531 New series 13.060 0.4845 85.964 20.5727 5.043 0.2106 13.240 0.5004 90.031 21.9451 5.7 0.03459 14.103 0.5828 93.862 22.8806 6.155 0.04314 14.996 0.7163 97.547 23.7003 6.467 0.05047 15.883 0.8263 102.875 24.7726 6.876 0.06390 18.582 1.2347 108.005 25.8287 7.158 0.07312 20.927 1.9242 112.388 26.9378 7.837 0.08932 22.980 2.5326 116.880 27.5968 7.960 0.09696 24.474 2.8882 121.250 28.6186 8.738 0.1239 25.871 3.3384 125.345 19.1432 9.121 0.1410 27.803 3.7179 129.839 29.9470 9.831 0.1759 30.395 4.4857 133.720 30.5767 141.482 31.8992 36.529 6.4475 137.918 31.2700 145.542 32.6478 194.764 39.5183 249.700 44.5450 149.548 33.1850 198.778 39.5622 254.157 45.1311 (Continued on next page) CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
A Discussion of selected references 363 T/K ο p,m C (SnO, cr, T )/ T/K –1 J·mol –1·K Table A-38 (continued) ο p,m C (SnO, cr, T )/ T/K –1 J·mol –1·K ο p,m C (SnO, cr, T )/ –1 J·mol –1·K 150.487 33.4975 201.833 40.2179 258.568 45.7156 153.445 33.7506 206.248 40.2693 262.970 45.8173 154.618 33.8703 210.157 40.9835 267.330 46.1717 158.891 34.5569 212.739 41.4576 270.928 46.5365 163.663 35.1770 216.740 41.7885 275.995 46.7436 165.199 35.3586 218.064 41.7254 280.258 46.7909 168.878 35.9242 220.741 42.0032 284.513 47.0633 169.868 35.9050 222.758 42.2019 298.925 47.2888 174.008 36.6175 228.622 43.0354 294.190 47.4976 179.713 37.4284 232.511 43.3621 298.343 47.7294 183.489 37.7493 236.368 43.5969 302.467 48.0181 187.599 38.6028 236.556 43.6048 306.599 48.2005 191.262 38.9083 245.656 44.1805 310.707 48.3716 In this temperature range the coefficients of a) an exponential power function bx / y = ax (A.70) ο (SnO, cr, )/J·K −1 ·mol −1 77.816( /K) [ −25.295(K/ T )] Cp, m T = T and b) the Gompertz function y = aexp{ −exp[ b− cln( x)]} (A.71) o C p, m (SnO, cr, T )/J·K –1·mol –1 = 85.825 exp{− exp[3.5131 – 0.71245 ln(T/K)]} were fitted to the data of Table A-38. Approaches a) and b) led to C o p, m (SnO, cr) = 47.989 J·K –1·mol –1 and C o p, m (SnO, cr) = 48.093 J·K –1·mol –1 , respectively. A better agreement with Kostryukov et al.’s result was obtained from the linear regression of the data between 262.97 ≤ T/K ≤ 310.71, C (SnO, cr) = (47.756 ± 0.076) J·K –1·mol –1 . o p, m The entropy was calculated a) by nonlinear regression of C o / p, m T vs. T, o refitting the coefficients of ( ( Cp, m / T )/J·K –2·mol –1 = 78.528 (T/K) [− 25.519(K/T) − 1] ) and o integrating with respect to T and b) by integrating the Gompertz function of C p, m with respect to ln (T/K), resulting in ο a) S m (SnO, cr, 298.15 K) = (57.180 ± 0.223) J·K –1·mol –1 and ο b) S m (SnO, cr, 298.15 K) = (57.105 ± 0.260) J·K –1·mol –1 . CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
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CHEMICAL THERMODYNAMICS OF TIN Hein
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CHEMICAL THERMODYNAMICS Vol. 1. Che
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vi Preface of the successive drafts
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viii Acknowledgements for peer revi
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x How to contact the NEA TDB Projec
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xii Contents III Selected tin data
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xiv Contents VIII.3 Aqueous halide
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xvi Contents B.1.3.2 Estimations ba
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xviii List of figures Figure VII-12
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xx List of figures Figure IX-3: Hea
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xxii List of figures Figure A-35: S
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List of tables Table II-1: Abbrevia
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List of tables xxvii Table VIII-1:
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List of tables xxix Table IX-4: Tab
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List of tables xxxi Table A-21: Sta
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List of tables xxxiii Table A-64: T
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Part 1 Introductory material
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4 I Introduction and Ti. In 1976, t
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6 I Introduction The present review
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8 I Introduction subjective choice
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10 II Standards, conventions and co
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30 II.3 II Standards, conventions a
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Part 2 Tables of selected data
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44 III Selected tin data Table III-
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50 III Selected tin data Species Re
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Chapter IV Selected auxiliary data
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IV Selected auxiliary data 57 Table
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IV Selected auxiliary data 75 Speci
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IV Selected auxiliary data 77 Speci
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Part 3 Discussion of data selection
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82 V Elemental tin transition, call
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84 V Elemental tin ο Table V-3: Co
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86 V Elemental tin Table V-6: Param
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Chapter VI VI Simple tin aqua ionsE
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VI.2 Sn 2+ 91 at 24.5 °C in aqueou
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VI.2 Sn 2+ 93 Reference Table VI-1:
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VI.2 Sn 2+ 95 As only three data pa
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VI.2 Sn 2+ 97 Figures A-37 to A-40.
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VI.3 Sn 4+ 99 Sn 4+ + H 2 (g) Sn 2
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VI.3 Sn 4+ 101 (NH 4 ) 2 SnCl 6 see
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VI.3 Sn 4+ 103 Sn 4+ + H 2 (g) Sn
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VI.3 Sn 4+ 105 Figure VI-3: Modifie
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108 VII Tin oxygen and hydrogen com
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138 VIII Group 17 (halogen) compoun
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Chapter IX IX Group 16 compounds an
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IX.1 Sulfur compounds and complexes
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232 X Group 15 compounds and comple
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Chapter XI XI Group 14 compounds an
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XI-1 Aqueous tin thiocyanato comple
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Appendix A Discussion of selected r
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A Discussion of selected references
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Page 347 and 348: A Discussion of selected references
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B Appendix B Ionic strength correct
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B.1 2BThe specific ion interaction
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B.3 4BTables of ion interaction coe
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484 C Assigned uncertainties The mi
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486 C Assigned uncertainties discus
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488 C Assigned uncertainties In cas
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490 C Assigned uncertainties The un
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492 C Assigned uncertainties In thi
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494 C Assigned uncertainties bit fu
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496 C Assigned uncertainties that t
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498 C Assigned uncertainties Eq. (C
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Bibliography [1813BER] [1831NEU] [1
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