Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

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364 A Discussion of selected references These entropy values overlap, but result a) was selected for this review, because integration of smoothed T, C data yielded also 57.18 J·K −1·mol −1 . [1978VAS/YAS] o p, m An equation for recalculating thermal effects to zero ionic strength is derived from the Debye-Hückel relation. Numerical values of the coefficients over a wide range of temperatures and ionic strengths are given. The enthalpy of reaction measured at finite ionic strength can be extrapolated 2 ο to I → 0 by linear regression: Δ H − Δ z Ψ = Δ H + bI . r The following table compares the different ionic strength extrapolation functions used in [1967VAS], [1978VAS/YAS] and [1996PLY/GRE]. The agreement between [1967VAS] and [1978VAS/YAS] is not as good as expected. r Table A-39: Molarity to molality conversion. I/M (HClO 4 ) I/mol·kg –1 (HClO 4 ) F(I) M basis/kJ·mol –1 [1967VAS] F(I) M basis/kJ·mol –1 [1978VAS/YAS] F(I) m basis/kJ·mol –1 [1996PLY/GRE] 0.1000 0.10077 0.1798 0.2096 0.3203 0.5000 0.51330 0.2588 0.3617 0.5144 1.0000 1.05080 0.2874 0.4353 0.6017 2.0000 2.20380 0.3107 0.5085 0.6853 3.0000 3.47130 0.3218 0.5498 0.7313 4.0000 4.86840 0.3286 0.5779 0.7626 6.0000 8.12820 0.3369 0.6154 0.8048 [1979PAU/STE] Paukov et al. [1979PAU/STE] measured the heat capacity of SnCl 2 (cr) in the temperature range of 5 to 304.70 K. The values measured for a sample of high purity (99.5%) in a rhombic phase (PbCl 2 ) are shown in Table A-40 and Table A-41 . They estimated the accuracy of the measurements as 0.2% at T > 25 K and about 0.5% at T < 25 K. CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
A Discussion of selected references 365 Table A-40: Experimental data on heat capacity of SnCl 2 (cr) from [1979PAU/STE]. T/K ο C p,m T/K (SnCl 2 , cr, T )/ –1 J·mol –1·K ο C p,m T/K (SnCl 2 , cr, T )/ –1 J·mol –1·K ο C p,m T/K (SnCl 2 , cr, T )/ –1 J·mol –1·K ο C p,m (SnCl 2 , cr, T )/ –1 J·mol –1·K 5.00 0.3868 28.30 17.97 82.51 52.46 180.16 70.98 5.46 0.5543 29.90 19.28 82.73 52.57 188.08 71.76 5.73 0.6521 33.94 22.66 87.23 54.33 193.56 72.21 6.58 1.018 35.56 23.99 89.35 55.11 200.85 72.89 7.68 1.522 40.08 27.41 95.10 56.69 206.01 73.24 8.68 2.176 41.64 28.72 97.40 57.77 211.62 73.44 9.63 2.768 43.24 29.94 103.32 59.47 218.68 73.84 10.60 3.366 48.20 33.53 105.85 60.10 226.92 74.32 11.54 4.054 49.92 34.88 112.12 61.56 235.08 74.87 12.49 4.752 51.57 36.07 114.91 62.15 243.16 75.28 13.60 5.687 53.14 37.18 121.55 63.58 251.18 75.71 14.67 6.621 57.02 39.70 124.47 64.14 259.45 76.23 15.65 7.376 59.07 40.90 132.29 65.44 267.97 76.67 16.63 8.225 64.27 43.94 138.40 66.27 275.71 77.00 17.55 8.977 66.81 45.38 145.74 67.41 281.67 77.47 18.51 9.749 69.24 46.56 150.70 68.08 289.03 77.67 19.68 10.73 74.66 49.25 155.84 68.66 296.90 77.96 20.86 11.70 77.10 50.14 161.39 69.20 299.12 77.97 21.91 12.59 79.80 51.36 169.08 69.99 303.01 78.23 22.92 13.40 80.61 51.74 174.52 70.52 304.70 78.33 Table A-41: Heat capacity, entropy and enthalpy of SnCl 2 (cr) from [1979PAU/STE]. ο C p,m S m ο ο 0K 0K T/K ( HT − H ) T/K ( HT − H ) (SnCl 2 , cr, T )/ (SnCl 2 , cr, T )/ (SnCl 2 , cr, T )/ (SnCl 2 , cr, T )/ (SnCl 2 , cr, T )/ (SnCl 2 , cr, T )/ –1 J·mol –1·K –1 J·mol –1·K J·mol –1 –1 J·mol –1·K –1 J·mol –1·K J·mol –1 5 0.4172 0.2206 0.8378 70 46.98 39.09 1602 7 1.226 0.4745 2.390 80 51.47 45.65 2096 9 2.349 0.9139 5.935 90 55.31 51.94 2630 12 4.384 1.859 15.94 100 58.50 57.68 3199 15 6.866 3.101 32.77 150 67.96 83.69 6392 20 10.99 5.640 77.41 200 72.75 104.0 9917 30 19.36 11.67 229.0 250 75.69 120.5 13630 40 27.44 18.36 463.5 273.15 76.94 127.3 15400 50 34.89 25.30 775.7 298.15 78.05 134.1 17330 60 41.49 32.27 1159 300 78.12 134.6 17475 ο C p,m S m CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
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CHEMICAL THERMODYNAMICS OF TIN Hein
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CHEMICAL THERMODYNAMICS Vol. 1. Che
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vi Preface of the successive drafts
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viii Acknowledgements for peer revi
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x How to contact the NEA TDB Projec
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xii Contents III Selected tin data
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xiv Contents VIII.3 Aqueous halide
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xvi Contents B.1.3.2 Estimations ba
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xviii List of figures Figure VII-12
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xx List of figures Figure IX-3: Hea
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xxii List of figures Figure A-35: S
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List of tables Table II-1: Abbrevia
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List of tables xxvii Table VIII-1:
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List of tables xxix Table IX-4: Tab
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List of tables xxxi Table A-21: Sta
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List of tables xxxiii Table A-64: T
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Part 1 Introductory material
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4 I Introduction and Ti. In 1976, t
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6 I Introduction The present review
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8 I Introduction subjective choice
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10 II Standards, conventions and co
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30 II.3 II Standards, conventions a
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Part 2 Tables of selected data
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44 III Selected tin data Table III-
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50 III Selected tin data Species Re
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Chapter IV Selected auxiliary data
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IV Selected auxiliary data 57 Table
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IV Selected auxiliary data 75 Speci
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IV Selected auxiliary data 77 Speci
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Part 3 Discussion of data selection
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82 V Elemental tin transition, call
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84 V Elemental tin ο Table V-3: Co
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86 V Elemental tin Table V-6: Param
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Chapter VI VI Simple tin aqua ionsE
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VI.2 Sn 2+ 91 at 24.5 °C in aqueou
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VI.2 Sn 2+ 93 Reference Table VI-1:
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VI.2 Sn 2+ 95 As only three data pa
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VI.2 Sn 2+ 97 Figures A-37 to A-40.
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VI.3 Sn 4+ 99 Sn 4+ + H 2 (g) Sn 2
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VI.3 Sn 4+ 101 (NH 4 ) 2 SnCl 6 see
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VI.3 Sn 4+ 103 Sn 4+ + H 2 (g) Sn
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VI.3 Sn 4+ 105 Figure VI-3: Modifie
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108 VII Tin oxygen and hydrogen com
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138 VIII Group 17 (halogen) compoun
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Chapter IX IX Group 16 compounds an
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IX.1 Sulfur compounds and complexes
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232 X Group 15 compounds and comple
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Chapter XI XI Group 14 compounds an
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XI-1 Aqueous tin thiocyanato comple
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Appendix A Discussion of selected r
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A Discussion of selected references
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Page 349 and 350: A Discussion of selected references
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B Appendix B Ionic strength correct
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B.1 2BThe specific ion interaction
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B.3 4BTables of ion interaction coe
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484 C Assigned uncertainties The mi
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486 C Assigned uncertainties discus
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488 C Assigned uncertainties In cas
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490 C Assigned uncertainties The un
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492 C Assigned uncertainties In thi
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494 C Assigned uncertainties bit fu
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496 C Assigned uncertainties that t
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498 C Assigned uncertainties Eq. (C
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Bibliography [1813BER] [1831NEU] [1
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Bibliography 503 [1906GOL/ECK] [190
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Bibliography 505 [1924LAN] [1925BRI
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