Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

180
VIII Group 17 (halogen) compounds and complexes
Figure VIII-22: Extrapolation to I = 0 of the experimental enthalpy data for reaction
Sn 2+ + Cl – SnCl + in HClO 4 media. DL = ¾ AL Im/(1+
1.5 Im)
see
[2005HUM/AND] Eq. (V.58 pp. 99-100). Experimental data are recalculated from
[1973VAS/VAS].
16
Sn 2+ + Cl – SnCl +
12
Δ
r
H
m
+ 4D
L
8
4
0
0 1 2 3 4 5
I / mol·kg –1
Figure VIII-23: Extrapolation to I = 0 of the experimental enthalpy data for reaction
Sn 2+ + 2 Cl – SnCl 2 (aq) in HClO 4 media. Experimental data are recalculated from
[1973VAS/VAS].
25
20
Sn 2+ + 2Cl – SnCl 2
(aq)
Δ r
H m
+ 6D L
15
10
5
0
0 1 2 3 4 5
I / mol·kg –1
CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012