Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

A Discussion of selected references
339
Figure A-34: SIT analysis of the data of [1973VAS/GLA] at 25 °C (: experimental
data, error bars (± 0.5 mV) estimated by the reviewer; solid line: linear fit; dotted lines:
95% confidence limits).
{E m
°' + [RT·ln(10)/2F ] 2D}/mV
-145
-150
-155
-160
Sn 2+ + H 2
(g) Sn(s) + 2H +
E°(Sn 2+ /Sn) = –(145.14 ± 0.60) mV
Δε = (0.094 ± 0.006) kg·mol –1
0 1 2 3 4 5
m(ClO – )/mo l·kg–1
4
Figure A-35: SIT analysis of the data of [1973VAS/GLA] at 35 °C (: experimental
data, error bars (± 0.5 mV) estimated by the reviewer; solid line: linear fit; dotted lines:
95% confidence limits).
-145
Sn 2+ + H 2
(g) Sn(s) + 2H +
{E m
°' + [RT·ln(10)/2F ] 2D}/mV
-150
-155
-160
E°(Sn 2+ /Sn) = –(146.85 ± 0.78) mV
Δε = (0.078 ± 0.007) kg·mol –1
0 1 2 3 4 5
m(ClO – 4 )/mol·kg–1
CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012