Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

464
B Ionic strength corrections
j k ε(j,k) Comments
Table B-4: (continued)
3
Th(NO 3 ) + Cl − —
ClO − 4
0.56 ± 0.14 Calculated in Section X.1.3.3 of [2008RAN/FUG] using
4+
NO − 0.56 ± 0.14 ε (Th ,X) = (0.70 ± 0.10) kg·mol −1 , for X = ClO −
and
3
4
NO − .
3
3
Th(H2PO 4) Cl − —
ClO − 4
0.5 ± 0.1 Estimated in Section X.2.3.2 of [2008RAN/FUG].
NO − 3
—
2 4 3 4
3
Th(H PO )(H PO ) + Cl − —
3
Th(SCN) + Cl − —
2
3
Be OH + Cl − —
ClO −
4
0.5 ± 0.1 Estimated in Section X.2.3.2 of [2008RAN/FUG].
NO − 3
—
ClO −
4
0.50 ± 0.10 See Section XI.1.3.6.1 of [2008RAN/FUG].
NO − 3
—
ClO −
4
NO − —
3
0.50 ± 0.05 Taken from [1986BRU], where the following assump-
2+ −
tions were made: ε (Be ,ClO ) = 0.30 kg·mol −1 as for
2 2
other ε(M + ,ClO − ); ε(Be + ,Cl − ) = 0.17 kg·mol −1 as for
other
2+ −
ε (M ,Cl ) and
2+ −
for other ε (M , NO ) .
4
3
4
2+ −
ε (Be , NO
3
)
= 0.17 kg·mol −1 as
3
Be 3(OH) 3
Cl − 0.30 ± 0.05 Taken from [1986BRU], where the following assumptions
were made: ε (Be ,ClO
2+ −
4
) = 0.30 kg·mol −1 as for
2 2
other ε(M ,ClO 4
); ε(Be ,Cl ) = 0.17 kg·mol −1 as for
2+ −
2+ −
other ε (M ,Cl ) and ε (Be , NO
3
) = 0.17 kg·mol −1 as
2+ −
for other ε (M , NO
3
) .
ClO −
4
NO −
3
Sn 4+ Cl − —
0.51 ± 0.05 Evaluated in [1992GRE/FUG] using
(0.76 ± 0.06) kg·mol −1 .
4+
ε (U ,X) =
0.29 ± 0.05 Taken from [1986BRU], where the following assump-
2+ −
tions were made: ε (Be ,ClO ) = 0.30 kg·mol −1 as for
2 2
other ε(M + ,ClO − ); ε(Be + ,Cl − ) = 0.17 kg·mol −1 as for
other
2+ −
ε (M ,Cl ) and
2+ −
for other ε (M , NO )
4
3
4
2+ −
ε (Be , NO
3
)
ClO −
4
0.7 ± 0.2 See Section VI.3.1 of this review.
NO − —
3
= 0.17 kg·mol −1 as
(Continued on next page)
CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012