Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

Contents
xv
IX.1.1.2.6 Sn 4 S 5 (cr) .................................................................................. 221
IX.1.1.2.7 Ternary tin sulfides.................................................................. 221
IX.1.1.3 Solubility of tin sulfides ................................................................... 222
IX.1.1.3.1 Solubility of SnS(cr) ................................................................ 223
IX.1.1.3.2 Solubility of SnS 2 (cr) .............................................................. 224
IX.1.2 Tin sulfates ............................................................................................... 225
IX.1.2.1 Aqueous sulfato complexes of tin(II) ............................................... 225
IX.1.2.2 Aqueous sulfato complexes of tin(IV) ............................................. 227
IX.1.2.3 Solid tin sulfates ............................................................................... 227
IX.1.2.4 Basic tin(II) sulfate ........................................................................... 228
IX.1.2.4.1 Composition of basic tin(II) sulfate ......................................... 228
IX.1.2.4.2 Solubility of Sn 3 (OH) 2 OSO 4 ................................................... 228
X Group 15 compounds and complexes 231
X.1 Nitrogen compounds and complexes .......................................................... 231
X.1.1 Aqueous tin(II) nitrato complexes ............................................................ 231
X.2 Phosphorus compounds and complexes ..................................................... 234
X.2.1 Solid tin phosphide ................................................................................... 234
X.2.2 Aqueous tin phosphato complexes ........................................................... 236
X.2.2.1 Aqueous tin(II) phosphato complexes .............................................. 236
X.2.2.2 Aqueous tin(II) pyrophosphato complexes ...................................... 238
X.2.2.3 Aqueous tin(IV) pyrophosphato complexes ..................................... 240
X.3 Arsenic compounds and complexes ............................................................ 241
X.3.1 Tin arsenides ............................................................................................. 241
X.3.1.1 SnAs(cr) ........................................................................................... 241
X.3.1.2 Sn 4 As 3 (cr)......................................................................................... 244
XI Group 14 compounds and complexes 249
XI.1 Aqueous tin thiocyanato complexes ............................................................ 249
XI.1.1 Aqueous Sn(II) thiocyanates ..................................................................... 249
Appendix A: Discussion of selected references 255
Appendix B: Ionic strength corrections 435
B.1 The specific ion interaction equations ........................................................ 436
B.1.1 Background ............................................................................................... 436
B.1.2 Ionic strength corrections at temperatures other than 25 °C
(298.15 K) ............................................................................................................... 443
B.1.3 Estimation of ion interaction coefficients ................................................. 444
B.1.3.1 Estimation from mean activity coefficient data ................................ 444
CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012