Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

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50 III Selected tin data Species Reaction Table III-2 (Continued) log K 10 ο G H ο ο Δ r m Δ r m Δ S ο r m (kJ·mol –1 ) (kJ·mol –1 ) (J·K –1·mol –1 ) Sn 21 Cl 16 (OH) 14 O 6 (cr) 16Cl – + 20H 2 O(l) + 21Sn 2+ 26H + + Sn 21 Cl 16 (OH) 14 O 6 (cr) 34.020 ±3.360 − 194.188 ±19.179 SnBr + Br – + Sn 2+ SnBr + 1.330 ±0.180 − 7.592 ±1.027 SnBr 2 (aq) 2Br – + Sn 2+ SnBr 2 (aq) 1.970 ±0.210 − 11.245 ±1.199 SnBr 2 (g) SnBr 4 (g) SnBr 2 (cr) SnBr 2 (g) SnBr 4 (cr) SnBr 4 (g) 134.600 ±2.000 63.800 ±1.500 SnBr 3 – 3Br – + Sn 2+ SnBr 3 – 1.930 ±0.270 − 11.017 ±1.541 SnI 2 (g) SnI 4 (g) SnI 2 (cr) SnI 2 (g) SnI 4 (cr) SnI 4 (g) 144.900 ±2.500 88.600 ±2.600 SnSCN + SCN – + Sn 2+ SnSCN + 1.500 ±0.700 SnSO 4 (aq) SO 4 2– + Sn 2+ SnSO 4 (aq) 3.430 ±0.250 − 8.562 ±3.996 − 19.579 ±1.427 SnNO 3 + NO 3 – + Sn 2+ SnNO 3 + 1.270 ±0.310 − 7.249 ±1.769 (Continued on next page) CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
III Selected tin data 51 Species Reaction Table III-2 (Continued) log K Sn(NO 3 ) 2 (aq) 2NO 3 – + Sn 2+ Sn(NO 3 ) 2 (aq) 10 ο 1.390 ±0.530 G H ο ο Δ r m Δ r m Δ S ο r m (kJ·mol –1 ) (kJ·mol –1 ) (J·K –1·mol –1 ) − 7.934 ±3.025 ο ο ο (a) Value calculated internally using Δ rGm =ΔrHm −T Δ rSm. (b) Value of log10 K ο calculated internally from Δ r m G ο CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
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CHEMICAL THERMODYNAMICS OF TIN Hein
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CHEMICAL THERMODYNAMICS Vol. 1. Che
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vi Preface of the successive drafts
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viii Acknowledgements for peer revi
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x How to contact the NEA TDB Projec
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xii Contents III Selected tin data
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xiv Contents VIII.3 Aqueous halide
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xvi Contents B.1.3.2 Estimations ba
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xviii List of figures Figure VII-12
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xx List of figures Figure IX-3: Hea
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xxii List of figures Figure A-35: S
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List of tables Table II-1: Abbrevia
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List of tables xxvii Table VIII-1:
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List of tables xxix Table IX-4: Tab
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List of tables xxxi Table A-21: Sta
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Page 37: Part 1 Introductory material
Page 40 and 41: 4 I Introduction and Ti. In 1976, t
Page 42 and 43: 6 I Introduction The present review
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Page 46 and 47: 10 II Standards, conventions and co
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Page 77: Part 2 Tables of selected data
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Page 91 and 92: Chapter IV Selected auxiliary data
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Page 115: Part 3 Discussion of data selection
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Page 125 and 126: Chapter VI VI Simple tin aqua ionsE
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VI.3 Sn 4+ 101 (NH 4 ) 2 SnCl 6 see
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VI.3 Sn 4+ 103 Sn 4+ + H 2 (g) Sn
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VI.3 Sn 4+ 105 Figure VI-3: Modifie
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108 VII Tin oxygen and hydrogen com
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138 VIII Group 17 (halogen) compoun
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Chapter IX IX Group 16 compounds an
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IX.1 Sulfur compounds and complexes
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232 X Group 15 compounds and comple
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Chapter XI XI Group 14 compounds an
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XI-1 Aqueous tin thiocyanato comple
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Appendix A Discussion of selected r
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A Discussion of selected references
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B Appendix B Ionic strength correct
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B.1 2BThe specific ion interaction
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B.3 4BTables of ion interaction coe
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484 C Assigned uncertainties The mi
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486 C Assigned uncertainties discus
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488 C Assigned uncertainties In cas
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490 C Assigned uncertainties The un
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492 C Assigned uncertainties In thi
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494 C Assigned uncertainties bit fu
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498 C Assigned uncertainties Eq. (C
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Bibliography [1813BER] [1831NEU] [1
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