Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

Appendix A
Discussion of selected references
A
This appendix comprises discussions relating to a number of key publications which
contain experimental information cited in this review. These discussions are
fundamental in explaining the accuracy of the data concerned and the interpretation of
the experiments, but they are too lengthy or are related to too many different sections to
be included in the main text. The notation used in this appendix is consistent with that
used in the present book, and not necessarily consistent with that used in the publication
under discussion.
[1813BER]
In this paper among other things the preparation and analysis of black tin(II) oxide was
reported. The first stage was to precipitate white, hydrous tin(II) oxide from tin(II)
chloride solutions with potassium carbonate.
[1844SCH]
On pages 174 and 175 preparations and analyses of tin(II) oxide hydrate and tin(IV)
oxide hydrate are reported.
Tin(II) oxide hydrate was obtained by precipitating tin(II) chloride solutions
with potassium carbonate solutions. After drying at 80 °C in a stream of carbon dioxide
the substance contained 93.54% SnO and 6.46% H 2 O apparently conforming to
2SnO·H 2 O (theor. 93.73% SnO and 6.27% H 2 O).
[1882DIT]
This is a short communication reporting the syntheses of basic tin(II) chlorides:
SnCl 2·4SnO·6H 2 O, 2SnCl 2·3SnO·6H 2 O, and SnCl 2·SnO·4H 2 O. Detailed analyses of
these products are given in [1882DIT2].
[1882DIT2]
In this paper the syntheses and analyses of two tin(II) oxide hydrates, three basic tin(II)
chlorides and two basic tin(II) sulfates were reported.
CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012