Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

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List of tables
Table A-77:
Table A-78:
4−
x
Formation constants β x of SnClx
complexes (units on the
molality basis) determined in HClO 4 background solutions at
different ionic strength (the estimated experimental errors (3σ)
are in parentheses) and extrapolated values to zero ionic
strength and to I m = 6.41 mol kg –1 by SIT. ....................................... 428
The formation constants used for the evaluation at different
ionic strength and the calculated standard potentials. ...................... 430
Table B-1: Water activities aHO for the most common ionic media at
2
various concentrations applying Pitzer’s ion interaction
approach and the interaction parameters given in [1991PIT]........... 441
Table B-2:
Table B-3:
Value of the Debye-Hückel constant A as a function of
temperature at a pressure of 1 bar below 100 °C and at the
steam saturated pressure for t ≥ 100 °C. ................................... 443
The preparation of the experimental equilibrium constants for
the extrapolation to I = 0 with the specific ion interaction
method at 25 °C and 1 bar, according to Reaction (B.12). ............... 445
Table B-4: Ion interaction coefficients ε ( jk , ) (kg·mol −1 ) for cations j with
k = Cl − , ClO − 4
and NO − 3
. ................................................................. 449
Table B-5: Ion interaction coefficients, ε ( jk , ) (kg·mol –1 ), for anions j
with k = Li + , Na + and K + . ................................................................. 468
Table B 6: Ion interaction coefficients, ε 1 (j,k) and ε 2 (j,k), both in kg·mol –1 ,
for cations j with k = Cl − , ClO4
− and NO −
3
(first part), and for
anions j with k = Li + , Na + and K + (second part), according to
the relationship ε = ε 1 + ε 2 log 10 I m ...................................................... 480
Table B-7:
SIT interaction coefficients ε(j,k) (kg·mol –1 ) for neutral species,
j, with k, electroneutral combination of ions. ................................... 481
Table C-1:
Details of the calculation of the equilibrium constant for
Reaction (C.17) corrected to I = 0 using (C.19). .............................. 495
CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012