Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

460
B Ionic strength corrections
j k ε(j,k) Comments
Table B-4: (continued)
2
Th(NO 3 ) + 2 Cl − —
ClO − 0.43 ± 0.18 Estimated in Section X.1.3.3 of [2008RAN/FUG], using ε(Th 4+ ,
4
NO − 0.43 ± 0.18 X) = (0.70 ± 0.10) kg·mol –1 for X = ClO − 4
and NO − 3
.
3
2
Th(H2PO 4) 2 Cl − —
ClO − 4
0.4 ± 0.1 Estimated in Section X.2.3.2 of [2008RAN/FUG].
NO − —
3
2
Th(SCN) + 2 Cl − —
ClO − 4
0.38 ± 0.20 See Section XI.1.3.6.1 of [2008RAN/FUG].
NO − 3
—
2
Mg + Cl − 0.19 ± 0.02
ClO − 4
0.33 ± 0.03 Reported by Ciavatta [1980CIA].
NO − 3
0.17 ± 0.01
2
Ca + Cl − 0.14 ± 0.01
ClO − 4
0.27 ± 0.03 Reported by Ciavatta [1980CIA].
NO − 3
0.02 ± 0.01
2
Ba + Cl − 0.07 ± 0.01
ClO − 4
0.15 ± 0.02 Reported by Ciavatta [1980CIA].
NO − 3
− 0.28 ± 0.03
3
Al + Cl − 0.33 ± 0.02 Reported by Ciavatta [1980CIA].
ClO − 4
—
NO − 3
—
3
Ni2
OH + Cl − —
ClO − 3+ −
3+ −
0.59 ± 0.15 By assuming ε (Ni
4
2OH ,ClO
4)
≈ ε (Be2OH ,ClO
4),
see
Section V.3.1.1 in [2005GAM/BUG].
NO − 3
—
3
Fe + Cl − —
ClO − 4
0.56 ± 0.03 Reported by Ciavatta [1980CIA].
NO − 3
0.42 ± 0.08
3
Cr + Cl − 0.30 ± 0.03 Reported by Ciavatta [1980CIA].
ClO − 4
—
NO − 3
0.27 ± 0.02 Reported by Ciavatta [1980CIA].
3
La + Cl − 0.22 ± 0.02
ClO − 4
0.47 ± 0.03
Reported by Ciavatta [1980CIA].
NO − 3
—
(Continued on next page)
CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012