Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

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Contents
III Selected tin data 43
IV Selected auxiliary data 55
V Elemental tin 81
V.1 Tin crystal ....................................................................................................... 81
V.1.1 General considerations ................................................................................ 81
V.1.2 Properties of grey tin .................................................................................. 82
V.1.3 Properties of white tin ................................................................................. 83
VI Simple tin aqua ions 89
VI.1 Preliminary remarks ...................................................................................... 89
VI.2 Sn 2+ .................................................................................................................. 90
VI.2.1 Gibbs energy of formation of Sn 2+ .............................................................. 90
VI.2.2 Enthalpy of formation of Sn 2+ ..................................................................... 94
VI.2.3 Partial molar entropy of Sn 2+ ...................................................................... 98
VI.3 Sn 4+ .................................................................................................................. 98
VI.3.1 Redox reaction Sn 4+ /Sn 2+ ............................................................................ 99
VI.3.2 Entropy estimation methods for aqueous tin(IV) ion ................................ 104
VII Tin oxygen and hydrogen compounds and complexes 107
VII.1 Aqueous tin hydroxido complexes .............................................................. 107
VII.1.1 Tin(II) hydroxido complexes .................................................................... 107
VII.1.2 Tin(IV) hydroxido complexes .................................................................. 113
VII.1.3 Mixed hydroxido complexes of tin(II) ...................................................... 116
VII.1.4 Mixed hydroxido complexes of tin(IV) .................................................... 117
VII.2 Solid tin oxides and hydroxides ................................................................... 117
VII.2.1 Introduction .............................................................................................. 117
VII.2.2 SnO(cr) ..................................................................................................... 118
VII.2.2.1 Enthalpy of formation of SnO(cr) .................................................... 118
VII.2.2.2 Heat capacity of SnO(cr) .................................................................. 120
VII.2.2.3 Solubility of SnO(cr) ........................................................................ 121
VII.2.2.4 Selected data..................................................................................... 126
VII.2.3 SnO 2 (cr).................................................................................................... 127
VII.2.3.1 Enthalpy of formation of SnO 2 (cr)................................................... 127
VII.2.3.2 Heat capacity of SnO 2 (cr) ................................................................ 128
VII.3 Gaseous tin hydrides .................................................................................... 134
VII.3.1 SnH 4 (g) ..................................................................................................... 134
CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012