Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

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250 XI Group 14 compounds and complexes For reasons mentioned in Appendix A, the constants reported in [1976SAM/LYA] were not considered in this review. The re-evaluation of the potentiometric data of [1961GOL/OGN] determined at 293.15 K indicated that the consideration of two species (SnSCN + and Sn(SCN) 2 (aq)) is sufficient to describe the experimental data up to 20% replacement of the background electrolyte (at higher thiocyanate concentrations a notable medium effect may arise). The temperature correction to 298.15 K is assumed to be negligible. The constants for Reaction ((XI.1), q = 2 and 3) reported in [1980FED/BOL] were not considered, since these reactions take place in a region where an important medium effect can be expected. Similarly, the value of log 10 β 1 reported in [1980FED/BOL] for I = 0.5 M was rejected, as the amount of SnSCN + formed up to [SCN – ] tot = 0.1 M (20% replacement of the background electrolyte) is probably too small to produce a reliable value. The SIT analysis of the remaining 3 values (Figure XI-1) resulted in the following selected constant ο log10 β 1 ((XI.1), q = 1, 298.15 K) = (1.5 ± 0.7). The corresponding ion interaction coefficient is Δε((XI.1), q = 1) = − (0.07 ± 0.29) kg·mol –1 . Figure XI-1: Extrapolation to I = 0 of the experimental data for reaction Sn 2+ + SCN – SnSCN + in NaClO 4 media. Experimental data from [1961GOL/OGN] and [1980FED/BOL]. 3.0 2.5 Sn 2+ + SCN – SnSCN + 2.0 log 10 β 1 + 4D 1.5 1.0 0.5 0.0 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 I / kg·mol –1 CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
XI-1 Aqueous tin thiocyanato complexes 251 The selected thermodynamic formation constant corresponds to ο m Δ rG ((XI.1), q = 1, 298.15 K) = − (8.6 ± 4.0) kJ·mol –1 . The Gibbs energy of formation is calculated using the selected values for Sn 2+ and SCN – : Δ (SnSCN+ , 298.15 K) = (56.7 ± 5.7) kJ·mol –1 . G ο f m CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
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CHEMICAL THERMODYNAMICS OF TIN Hein
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CHEMICAL THERMODYNAMICS Vol. 1. Che
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vi Preface of the successive drafts
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viii Acknowledgements for peer revi
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x How to contact the NEA TDB Projec
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xii Contents III Selected tin data
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xiv Contents VIII.3 Aqueous halide
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xvi Contents B.1.3.2 Estimations ba
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xviii List of figures Figure VII-12
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xx List of figures Figure IX-3: Hea
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xxii List of figures Figure A-35: S
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List of tables Table II-1: Abbrevia
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List of tables xxvii Table VIII-1:
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List of tables xxix Table IX-4: Tab
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List of tables xxxi Table A-21: Sta
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List of tables xxxiii Table A-64: T
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Part 1 Introductory material
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4 I Introduction and Ti. In 1976, t
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6 I Introduction The present review
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8 I Introduction subjective choice
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10 II Standards, conventions and co
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30 II.3 II Standards, conventions a
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Part 2 Tables of selected data
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44 III Selected tin data Table III-
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50 III Selected tin data Species Re
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Chapter IV Selected auxiliary data
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IV Selected auxiliary data 57 Table
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IV Selected auxiliary data 75 Speci
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IV Selected auxiliary data 77 Speci
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Part 3 Discussion of data selection
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82 V Elemental tin transition, call
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84 V Elemental tin ο Table V-3: Co
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86 V Elemental tin Table V-6: Param
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Chapter VI VI Simple tin aqua ionsE
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VI.2 Sn 2+ 91 at 24.5 °C in aqueou
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VI.2 Sn 2+ 93 Reference Table VI-1:
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VI.2 Sn 2+ 95 As only three data pa
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VI.2 Sn 2+ 97 Figures A-37 to A-40.
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VI.3 Sn 4+ 99 Sn 4+ + H 2 (g) Sn 2
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VI.3 Sn 4+ 101 (NH 4 ) 2 SnCl 6 see
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VI.3 Sn 4+ 103 Sn 4+ + H 2 (g) Sn
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VI.3 Sn 4+ 105 Figure VI-3: Modifie
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108 VII Tin oxygen and hydrogen com
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138 VIII Group 17 (halogen) compoun
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Page 293 and 294: A Discussion of selected references
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A Discussion of selected references
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B Appendix B Ionic strength correct
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B.1 2BThe specific ion interaction
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B.3 4BTables of ion interaction coe
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484 C Assigned uncertainties The mi
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486 C Assigned uncertainties discus
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488 C Assigned uncertainties In cas
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490 C Assigned uncertainties The un
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492 C Assigned uncertainties In thi
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494 C Assigned uncertainties bit fu
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496 C Assigned uncertainties that t
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498 C Assigned uncertainties Eq. (C
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Bibliography [1813BER] [1831NEU] [1
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