Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

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430 A Discussion of selected references Table A-78: The formation constants used for the evaluation at different ionic strength and the calculated standard potentials. I m (I c ) Applied formation constants 2−n (molar values) for SnCl 4.73 (3 M HclO 4 + 1 M HCl) 6.22 (4 M HclO 4 + 1 M HCl) 7.88 (5 M HclO 4 + 1 M HCl) log10 β 1 = 1.26, log10 β 2 = 1.98, log10 β 3 = 1.97, log10 β 4 = 2.46, log10 β 1 = 1.47, log10 β 2 = 2.36, log10 β 3 = 2.35, log10 β 4 = 2.88, log10 β 1 = 1.74, log10 β 2 = 2.83, log10 β 3 = 2.84, log10 β 4 = 3.41, n Applied formation constants 4−n (molar values) for SnCl log10 β 1 = 2.43, log10 β 2 = 4.59, log10 β 4 = 7.69, log10 β 5 = 8.91, log10 β 6 = 8.74, log10 β 1 = 2.78, log10 β 2 = 5.18, log10 β 4 = 8.56, log10 β 5 = 9.73, log10 β 6 = 9.71, log10 β 1 = 3.22, log10 β 2 = 5.94, log10 β 4 = 9.67, log10 β 5 = 10.79, log10 β 6 = 10.94, n E ο ' (Sn 4+ /Sn 2+ )/V 0.2797 ± 0.0123 0.2732 ± 0.0066 0.2627 ± 0.0087 Figure A-51: The observed E values of cell III as a function of log 10 ([Sn 4+ free]/[Sn 2+ free]) at I m = 4.73 (A), 6.22 (B) and 7.88 (C) (see also Table A-78). 0.14 0.13 A exp. data, error bars: ± 0.005 V linear fit, fixed slope: k/2 = 0.02958 V / decade E° = (0.2797 ± 0.0123) V 0.12 E / V 0.11 0.10 0.09 298.15 K (3M HClO 4 + 1M HCl) -6.2 -6.0 -5.8 -5.6 -5.4 -5.2 -5.0 log 10 ([Sn 4+ free ]/[Sn2+ free ]) (Continued on next page) CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
A Discussion of selected references 431 Figure A-51 (continued) 0.12 0.11 B exp. data, error bars: ± 0.004 V linear fit, fixed slope: k/2 = 0.02958 V / decade E° = (0.2732 ± 0.0066) V 0.10 E / V 0.09 0.08 298.15 K (4M HClO 4 + 1M HCl) -6.6 -6.4 -6.2 -6.0 -5.8 -5.6 -5.4 log 10 ([Sn 4+ free ]/[Sn2+ free ]) 0.09 0.08 C exp. data, error bars: ± 0.004 V linear fit, fixed slope: k/2 = 0.02958 V / decade E° = (0.2627 ± 0.0087) V 0.07 E / V 0.06 0.05 0.04 298.15 K (5M HClO 4 + 1M HCl) -7.2 -7.0 -6.8 -6.6 -6.4 -6.2 -6.0 log 10 ([Sn 4+ free ]/[Sn2+ free ]) CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
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CHEMICAL THERMODYNAMICS OF TIN Hein
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CHEMICAL THERMODYNAMICS Vol. 1. Che
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vi Preface of the successive drafts
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viii Acknowledgements for peer revi
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x How to contact the NEA TDB Projec
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xii Contents III Selected tin data
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xiv Contents VIII.3 Aqueous halide
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xvi Contents B.1.3.2 Estimations ba
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xviii List of figures Figure VII-12
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xx List of figures Figure IX-3: Hea
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xxii List of figures Figure A-35: S
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List of tables Table II-1: Abbrevia
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List of tables xxvii Table VIII-1:
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List of tables xxix Table IX-4: Tab
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List of tables xxxi Table A-21: Sta
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List of tables xxxiii Table A-64: T
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Part 1 Introductory material
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4 I Introduction and Ti. In 1976, t
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6 I Introduction The present review
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8 I Introduction subjective choice
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10 II Standards, conventions and co
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30 II.3 II Standards, conventions a
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Part 2 Tables of selected data
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44 III Selected tin data Table III-
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50 III Selected tin data Species Re
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Chapter IV Selected auxiliary data
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IV Selected auxiliary data 57 Table
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IV Selected auxiliary data 75 Speci
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IV Selected auxiliary data 77 Speci
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Part 3 Discussion of data selection
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82 V Elemental tin transition, call
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84 V Elemental tin ο Table V-3: Co
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86 V Elemental tin Table V-6: Param
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Chapter VI VI Simple tin aqua ionsE
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VI.2 Sn 2+ 91 at 24.5 °C in aqueou
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VI.2 Sn 2+ 93 Reference Table VI-1:
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VI.2 Sn 2+ 95 As only three data pa
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VI.2 Sn 2+ 97 Figures A-37 to A-40.
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VI.3 Sn 4+ 99 Sn 4+ + H 2 (g) Sn 2
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VI.3 Sn 4+ 101 (NH 4 ) 2 SnCl 6 see
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VI.3 Sn 4+ 103 Sn 4+ + H 2 (g) Sn
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VI.3 Sn 4+ 105 Figure VI-3: Modifie
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108 VII Tin oxygen and hydrogen com
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138 VIII Group 17 (halogen) compoun
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Chapter IX IX Group 16 compounds an
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IX.1 Sulfur compounds and complexes
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232 X Group 15 compounds and comple
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Chapter XI XI Group 14 compounds an
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XI-1 Aqueous tin thiocyanato comple
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Appendix A Discussion of selected r
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A Discussion of selected references
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Page 415 and 416: A Discussion of selected references
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Page 471 and 472: B Appendix B Ionic strength correct
Page 473 and 474: B.1 2BThe specific ion interaction
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B.3 4BTables of ion interaction coe
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484 C Assigned uncertainties The mi
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486 C Assigned uncertainties discus
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488 C Assigned uncertainties In cas
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490 C Assigned uncertainties The un
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492 C Assigned uncertainties In thi
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494 C Assigned uncertainties bit fu
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496 C Assigned uncertainties that t
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498 C Assigned uncertainties Eq. (C
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