Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

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282 A Discussion of selected references was evaluated assuming ε(Sn(OH) 2 ,NaOH) = 0. Using the NEA TDB value of (0.04 ± 0.01) kg˙mol –1 for ε(Na + , OH – ), ε(Na + , Sn(OH) − 3 ) = (0.20 ± 0.04) kg˙mol –1 can be obtained. Table A-7: Solubility of SnO(cr) in NaOH solutions. 10 3·m NaOH /mol·kg –1 10 5·m Sn(II) /mol·kg –1 log 10 a(H 2 O) log 10 ( * K s3 /a(H 2 O) 5.0000 67.9000 − 0.0001 − 0.8036 5.0000 70.5000 − 0.0001 − 0.7847 5.0000 69.6000 − 0.0001 − 0.7912 7.6400 95.7000 − 0.0001 − 0.8439 7.6400 94.1000 − 0.0001 − 0.8523 10.2300 134.0000 − 0.0002 − 0.8216 18.7400 238.0000 − 0.0003 − 0.8369 18.7400 254.0000 − 0.0003 − 0.8044 36.9700 440.0000 − 0.0006 − 0.8688 36.9700 460.0000 − 0.0006 − 0.8468 55.4000 700.0000 − 0.0008 − 0.8389 55.4000 700.0000 − 0.0008 − 0.8389 73.4000 880.0000 − 0.0011 − 0.8647 73.4000 850.0000 − 0.0011 − 0.8817 93.1000 1100.0000 − 0.0014 − 0.8716 93.1000 1100.0000 − 0.0014 − 0.8716 187.9000 1800.0000 − 0.0028 − 0.9721 187.9000 2000.0000 − 0.0028 − 0.9212 375.8000 4200.0000 − 0.0056 − 0.8946 375.8000 4400.0000 − 0.0056 − 0.8718 563.1000 6000.0000 − 0.0084 − 0.9151 563.1000 5600.0000 − 0.0084 − 0.9485 751.0000 7300.0000 − 0.0112 − 0.9567 751.0000 7100.0000 − 0.0112 − 0.9700 1131.0000 9700.0000 − 0.0169 − 1.0109 1131.0000 9800.0000 − 0.0169 − 1.0060 CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
A Discussion of selected references 283 Figure A-14: Solubility of SnO(cr) in NaOH solutions (: experimental data; solid line: * linear fit ( log10 K s31= − (0.840 ± 0.016), Δε = (0.190 ± 0.038) kg·mol –1 ); dashed lines: confidence limits; dotted lines: prediction limits). -0.75 -0.80 SnO(cr) + OH – + H 2 O Sn(OH) – 3 -0.85 log 10 {K s 3,1 / a(H 2 O)} -0.90 -0.95 -1.00 -1.05 0.0 0.2 0.4 0.6 0.8 1.0 1.2 m (Na + ) / mol·kg –1 [1941MOO/PAU] Powder photographic X-ray data are used to show that the tetragonal crystals SnO and PbO have similar structures: D 7 4h – P4/nmm SnO: a 0 = (3.796 ± 0.006), c 0 = (4.816 ± 0.008) Å, Z = 2 PbO: a 0 = (3.947 ± 0.006), c 0 = (4.988 ± 0.008) Å, Z = 2. The density of SnO(tetr.) calculated from the unit cell data amounts to ρ = (6447 ± 31) kg·m –3 . [1942GOR/LEI] Data on the solubility of SnO(s) in aqueous solutions of 0.0113 to 0.1125 M HClO 4 are presented at 25 °C. The solubilities in HClO 4 and HCl (according to [1941GAR/HEI]) are identical within the experimental error up to [Sn(II)] = 0.05 M. The authors took this as evidence for the absence of significant chloride complexing by Sn 2+ in this concentration range. CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
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CHEMICAL THERMODYNAMICS OF TIN Hein
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CHEMICAL THERMODYNAMICS Vol. 1. Che
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vi Preface of the successive drafts
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viii Acknowledgements for peer revi
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x How to contact the NEA TDB Projec
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xii Contents III Selected tin data
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xiv Contents VIII.3 Aqueous halide
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xvi Contents B.1.3.2 Estimations ba
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xviii List of figures Figure VII-12
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xx List of figures Figure IX-3: Hea
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xxii List of figures Figure A-35: S
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List of tables Table II-1: Abbrevia
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List of tables xxvii Table VIII-1:
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List of tables xxix Table IX-4: Tab
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List of tables xxxi Table A-21: Sta
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List of tables xxxiii Table A-64: T
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Part 1 Introductory material
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4 I Introduction and Ti. In 1976, t
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6 I Introduction The present review
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8 I Introduction subjective choice
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10 II Standards, conventions and co
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30 II.3 II Standards, conventions a
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Part 2 Tables of selected data
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44 III Selected tin data Table III-
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50 III Selected tin data Species Re
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Chapter IV Selected auxiliary data
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IV Selected auxiliary data 57 Table
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IV Selected auxiliary data 75 Speci
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IV Selected auxiliary data 77 Speci
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Part 3 Discussion of data selection
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82 V Elemental tin transition, call
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84 V Elemental tin ο Table V-3: Co
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86 V Elemental tin Table V-6: Param
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Chapter VI VI Simple tin aqua ionsE
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VI.2 Sn 2+ 91 at 24.5 °C in aqueou
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VI.2 Sn 2+ 93 Reference Table VI-1:
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VI.2 Sn 2+ 95 As only three data pa
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VI.2 Sn 2+ 97 Figures A-37 to A-40.
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VI.3 Sn 4+ 99 Sn 4+ + H 2 (g) Sn 2
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VI.3 Sn 4+ 101 (NH 4 ) 2 SnCl 6 see
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VI.3 Sn 4+ 103 Sn 4+ + H 2 (g) Sn
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VI.3 Sn 4+ 105 Figure VI-3: Modifie
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108 VII Tin oxygen and hydrogen com
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138 VIII Group 17 (halogen) compoun
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Chapter IX IX Group 16 compounds an
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IX.1 Sulfur compounds and complexes
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A Discussion of selected references
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B Appendix B Ionic strength correct
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B.1 2BThe specific ion interaction
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B.3 4BTables of ion interaction coe
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484 C Assigned uncertainties The mi
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486 C Assigned uncertainties discus
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488 C Assigned uncertainties In cas
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490 C Assigned uncertainties The un
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492 C Assigned uncertainties In thi
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494 C Assigned uncertainties bit fu
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496 C Assigned uncertainties that t
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498 C Assigned uncertainties Eq. (C
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